PRODUCTION OF SUBSTITUTED INDANONE

    公开(公告)号:JPH10139715A

    公开(公告)日:1998-05-26

    申请号:JP24497697

    申请日:1997-09-10

    Applicant: BASF AG

    Abstract: PROBLEM TO BE SOLVED: To easily and safely produce the subject compound useful as a production intermediate for a metallocence complex known as a polymerization catalyst in one step by reacting two specific kinds of compounds in the presence of a Friedel-Crafts catalyst. SOLUTION: The objective substituted indanone of the formula IV or the formula V is produced by reacting a compound of the formula I or the formula II [R , R , R and R are each H, a 1-4C (fluoro)alkyl, a (1-4C alkyl)silyl, phenyl, benzyl or R and R form a benzene ring together with the bonded C atom] with a compound of the formula III [R so a 1-10C alkyl or a (1-4C alkyl- substituted)phenyl; X is Cl, Br or I] in the presence of a Friedel-Crafts catalyst (e.g. AlCl3 ) in a Friedel-Crafts solvent (e.g. methylene chloride) at -80 to 0 deg.C.

    MULTIMODAL POLYAMIDES, POLYESTERS AND POLYESTER AMIDES

    公开(公告)号:HU0600301A2

    公开(公告)日:2006-07-28

    申请号:HU0600301

    申请日:2002-06-13

    Applicant: BASF AG

    Abstract: A thermoplastic polymer mixture comprising m polymers Pn, where m is a natural number greater than 1 and n is a natural number from 1 to m, where n is a natural number from 1 to m, where each of the polymers has one or more functional groups of the structure -(R )x-C(O)-(R )y- present as repeat units in the main chain of polymer Pn where x and y, independently of one another, are 0 or 1, and x+y=1 R and R , independently of one another, are oxygen or nitrogen bonded into the main polymer chain, where in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent the polymer mixture has at least two maxima of the relative frequency W, and after aging of the polymer mixture at the melting point of the polymer mixture determined to ISO 11357-1 and 11357-3 for 5 minutes, the polymer mixture has in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent at least 2 maxima of the relative frequency W, and the position of the maxima here after aging of the polymer mixture at the melting point of the polymer mixture is within three times the recurrent standard deviation sigma(r) of MP in percentage of the value measured to DIN 55672-2, based on the position of the maxima prior to aging of the polymer mixture at the melting point of the polymer mixture.

    6.
    发明专利
    未知

    公开(公告)号:DE10129522A1

    公开(公告)日:2003-01-09

    申请号:DE10129522

    申请日:2001-06-21

    Applicant: BASF AG

    Abstract: The invention relates to a thermoplastic polymer mixture containing m, m representing a natural number higher than 1, polymers Pn wherein n represents a natural number between 1 and m, and at least one recurring functional group contained in the Pn polymer chain, said group(s) having the structure -(R )x-C(O)-(R )y- wherein x and y independently represent 0 or 1, and x + y = 1, and R , R independently represent oxygen or nitrogen linked into the main polymer chain. The polymers Pn differ in terms of at least one characteristic related to molecular weight. The polymer mixture has a number average molecular weight Mn(P)1, a weight average molecular weight Mw(P)1, a Z average molecular weight Mz(P)1, a heterogeneity index Mw(P)1/Mn(P)1 and a molecular weight Mp(P)1 defined according to DIN 55672-2 in hexafluoroisopropanol as an elution agent. After maintaining the polymer mixture at the melting point of the same, defined according to ISO 11357-1 and 11357-3, for five minutes, the polymer mixture has a number average molecular weight Mn(P)2, a weight average molecular weight Mw(P)2, a Z average molecular weight Mz(P)2, a heterogeneity index Mw(P)2/Mn(P)2, and a molecular weight Mp(P)2 defined according to DIN 55672-2 in hexafluoroisopropanol as an elution agent. The values Mn(P)2, Mw(P)2, Mz(P)2, Mw(P)2/Mn(P)2 and Mp(P)2 lie within the triple replication standard deviation sigma (r) in relation to Mn(P)1, Mw(P)1, Mz(P)1, Mw(P)1/Mn(P)1 and Mp(P)1 according to DIN 55672-2 in hexafluoroisopropanol as an elution agent.

    7.
    发明专利
    未知

    公开(公告)号:DK260285A

    公开(公告)日:1985-12-13

    申请号:DK260285

    申请日:1985-06-11

    Applicant: BASF AG

    Abstract: Very pure riboflavin (I) is obtained by a process in which the riboflavin is dissolved in dilute aqueous alkali metal hydroxide solution, if necessary the alkaline solution is purified by treatment with active carbon or with a solvent which is insoluble or only slightly soluble in water, the resulting alkaline solution of I is introduced into water which is at 90 DEG -100 DEG C. and to which an acid has been added in an amount such that the reaction mixture is brought to a pH of from 6.5 to 0.8, the temperature being maintained at from 40 DEG to 100 DEG C., the reaction mixture is kept at from 90 DEG to 100 DEG C. for from 10 to 80 minutes and cooled, and I is then isolated.

    8.
    发明专利
    未知

    公开(公告)号:BR0210573A

    公开(公告)日:2004-08-03

    申请号:BR0210573

    申请日:2002-06-13

    Applicant: BASF AG

    Abstract: A thermoplastic polymer mixture comprising m polymers Pn, where m is a natural number greater than 1 and n is a natural number from 1 to m, where n is a natural number from 1 to m, where each of the polymers has one or more functional groups of the structure -(R )x-C(O)-(R )y- present as repeat units in the main chain of polymer Pn where x and y, independently of one another, are 0 or 1, and x+y=1 R and R , independently of one another, are oxygen or nitrogen bonded into the main polymer chain, where in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent the polymer mixture has at least two maxima of the relative frequency W, and after aging of the polymer mixture at the melting point of the polymer mixture determined to ISO 11357-1 and 11357-3 for 5 minutes, the polymer mixture has in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent at least 2 maxima of the relative frequency W, and the position of the maxima here after aging of the polymer mixture at the melting point of the polymer mixture is within three times the recurrent standard deviation sigma(r) of MP in percentage of the value measured to DIN 55672-2, based on the position of the maxima prior to aging of the polymer mixture at the melting point of the polymer mixture.

    Polymer mixture
    9.
    发明专利

    公开(公告)号:CZ20033514A3

    公开(公告)日:2004-05-12

    申请号:CZ20033514

    申请日:2002-06-14

    Applicant: BASF AG

    Abstract: The invention relates to a thermoplastic polymer mixture containing m, m representing a natural number higher than 1, polymers Pn wherein n represents a natural number between 1 and m, and at least one recurring functional group contained in the Pn polymer chain, said group(s) having the structure -(R )x-C(O)-(R )y- wherein x and y independently represent 0 or 1, and x+y=1, and R , R independently represent oxygen or nitrogen linked into the main polymer chain. The polymers Pn differ in terms of at least one characteristic related to molecular weight. The polymer mixture has a number average molecular weight Mn(P)1, a weight average molecular weight Mw(P)1, a Z average molecular weight Mz(P)1, a heterogeneity index Mw(P)1/Mn(P)1, and a molecular weight Mp(P)1 defined according to DIN 55672-2 in hexafluoroisopropanol as an elution agent. After maintaining the polymer mixture at the melting point of the same, defined according to ISO 11357-1 and 11357-3, for five minutes, the polymer mixture has a number average molecular weight Mn(P)2, a weight average molecular weight Mw(P)2, a Z average molecular weight Mz(P)2, a heterogeneity index Mw(P)2/Mn(P)2, and a molecular weight Mp(P)2 defined according to DIN 55672-2 in hexafluoroisopropanol as an elution agent. The values Mn(P)2, Mw(P)2, Mz(P)2, Mw(P)2/Mn(P)2 and Mp(P)2 lie within the triple replication standard deviation sigma (r) in relation to Mn(P)1, Mw(P)1, Mz(P)1, Mw(P)1/Mn(P)1 and Mp(P

    A thermoplastic polymer mixture useful for the production of fibers, e.g. carpets or flat structured textiles, contains polyamide

    公开(公告)号:DE10156293A1

    公开(公告)日:2003-05-28

    申请号:DE10156293

    申请日:2001-11-19

    Applicant: BASF AG

    Abstract: A thermoplastic polymer mixture (I) containing a polyamide (II) and a polymer (III), where the melt viscosity, as measured at 280 deg C is 100-20,000 s-1 is at most 75% of the melt viscosity measured in accordance with ISO 1443 of polyamide (II) at 280 deg C, and the boundary surface tension between a melt of polyamide (II) and a melt of polyamide (III) at 280 deg C, measured in accordance with US patent 5,50,607 by the Spinning-Drop-Method is in the region of 0-10 mN/m. A thermoplastic polymer mixture (I) containing (wt.%): (a) a polyamide (II)(50-99.9), (b) a polymer (III)( 0.1-50), where the melt viscosity, as measured in accordance with ISO 1443 of polyamide (II) at 280 deg C over the whole Scherraten (sic) region is 100-20,000 s-1 is at most 75% of the melt viscosity measured in accordance with ISO 1443 of polyamide (II) at 280 deg C, and the boundary surface tension between a melt of polyamide (II) and a melt of polyamide (III) at 280 deg C, measured in accordance with US patent 5,50,607 by the Spinning-Drop-Method is in the region of 0-10 mN/m. Independent claims are included for: (1) a process for preparation of a fiber by spinning a melt of a thermoplastic polymer, using the above polymer mixture (I) as the thermoplastic polymer; (2) a fiber obtained by the above process; (3) a carpet containing the above fiber; and (4) flat structure textiles containing the above fiber.

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