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公开(公告)号:DE10317929A1
公开(公告)日:2004-11-11
申请号:DE10317929
申请日:2003-04-17
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG , KUNSMANN-KEITEL DAGMAR PASCALE , BASLER PETER
Abstract: A process for dewatering hydrocyanic acid by distillation, which includes distilling crude hydrocyanic acid containing from 50 to 99.9% by weight of HCN, from 0.1 to 40% by weight of water, from 0 to 15% by weight of carbon oxides and optionally from 0.01 to 1% by weight of an involatile stabilizer, at a pressure of from 1 bar to 2.5 bar, a bottom temperature of from 100° C. to 130° C. and a top temperature of from 25° C. to 54° C., in the absence of a volatile stabilizer, in a distillation column to obtain a top draw stream containing purified, anhydrous hydrocyanic acid and carbon oxides and a bottom draw stream including water and, optionally, the involatile stabilizer.
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公开(公告)号:SA2124B1
公开(公告)日:2008-11-18
申请号:SA03230520
申请日:2003-01-22
Applicant: BASF AG
Inventor: MAASE MATHIAS , MASSONNE KLEMENS , HALBRITTER KLAUS , NOE RALF , BARTSCH MICHAEL , SIEGEL WOLFGANG , STEGMANN VEIT , FLORES MIGUEL , HUTTENLOCH OLIVER , BECKER MICHAEL
IPC: C07D233/58 , B01J31/24 , C07F9/22 , C07B61/00 , C07B63/00 , C07B63/02 , C07C1/30 , C07C7/10 , C07C13/23 , C07C45/50 , C07C67/14 , C07C67/58 , C07C69/14 , C07C69/78 , C07C403/12 , C07D233/60 , C07D403/12 , C07F7/18 , C07F9/02 , C07F9/12 , C07F9/142 , C07F9/145 , C07F9/46 , C07F9/48 , C07F9/50 , C07F9/52 , C07F9/572 , C07F9/6503 , C07F9/6574 , C07F9/6584
Abstract: الملخص: طريقةلإزالةالأحماض removal of acids منمخاليطالتفاعل reaction mixtures بإستخدامقاعدةمساعدة،وفيهاتقومالقاعدةالإضافية (ب) بالإتحادمعالحمض acid لتكوينملحيكونسائلعنددرجاتالحرارةالتيعندهالايتفككالناتجالذيلهقيمتهعلىنحومدهشأثناءإزالةالملح removal of the salt والسائل،و (ج) يكونالملحالخاصبالقاعدةالاضافيةمعالناتجالذيلهقيمتهأومحلولالناتجالذيلهقيمتهفيمذيبمناسبطورينسائلينغيرقابلينللامتزاج.
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公开(公告)号:PL383682A1
公开(公告)日:2008-04-14
申请号:PL38368204
申请日:2004-02-24
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG , BASSLER PETER
IPC: C07C253/10 , C07C253/34 , C07C255/04
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公开(公告)号:AR043883A1
公开(公告)日:2005-08-17
申请号:ARP040101309
申请日:2004-04-19
Applicant: BASF AG
Inventor: BAUMANN R , HADERLEIN G , FLORES MIGUEL , JUNGKAMP T , LUYKEN H , SCHEIDEL J , SIEGEL WOLFGANG , BARTSCH M , KUNSMANN-KEITEL D
IPC: C07C253/30 , C07C255/07
Abstract: Procedimiento para la isomerización de cis-2-pentenonitrilo en trans-3-pentenonitrilo en presencia de óxido de aluminio como catalizador, caracterizado porque el óxido de aluminio tiene una superficie BET de por lo menos 50m2/g.
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公开(公告)号:AR043727A1
公开(公告)日:2005-08-10
申请号:ARP040100698
申请日:2004-03-05
Applicant: BASF AG
Inventor: BAUMANN R , HADERLEIN G , FLORES MIGUEL , JUNGKAMP T , LUYKEN HERMANN , SCHEIDEL J , SIEGEL WOLFGANG , KUNSMANN-KEITEL D , BARTSCH MICHAEL
IPC: C07C255/07 , C07B35/08 , C07C253/30
Abstract: Procedimiento para la isomerización de 2-metil-3-butenonitrilo en un pentenonitrilo líneal en presencia de un sistema, que contiene: a)Ni(O), (a) un compuesto secuestrante de Ni(O) como ligando, que contiene fósforo de triple enlace y (c) un ácido lewis en donde durante la isomerización se toma de la mezcla de reacción un mezcla, que contiene 2_metil-3-butenonitrilo y pentenonitrilo lineal.
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公开(公告)号:NO20043512A
公开(公告)日:2004-08-23
申请号:NO20043512
申请日:2004-08-23
Applicant: BASF AG
Inventor: MAASE MATHIAS , MASONNE KLEMENS , HALBRITTER KLAUS , NOE RALF , BARTSCH MICHAEL , SIEGEL WOLFGANG , STEGMANN VEIT , FLORES MIGUEL , HUTTENLOCH OLIVER , BECKER MICHAEL
IPC: C07D233/58 , B01J31/24 , C07B61/00 , C07B63/00 , C07B63/02 , C07C1/30 , C07C7/10 , C07C13/23 , C07C45/50 , C07C67/14 , C07C67/58 , C07C69/14 , C07C69/78 , C07C403/12 , C07D233/60 , C07D403/12 , C07F7/18 , C07F9/02 , C07F9/12 , C07F9/142 , C07F9/145 , C07F9/22 , C07F9/46 , C07F9/48 , C07F9/50 , C07F9/52 , C07F9/572 , C07F9/6503 , C07F9/6574 , C07F9/6584
CPC classification number: C07C403/12 , C07C1/30 , C07C45/50 , C07C51/412 , C07C51/58 , C07C67/14 , C07C2531/02 , C07C2601/16 , C07D295/185 , C07D317/36 , C07F9/142 , C07F9/145 , C07F9/46 , C07F9/4841 , C07F9/52 , C07F9/5721 , C07F9/5728 , C07F9/65038 , C07F9/65746 , C07F9/65848 , C07C47/02 , C07C13/23 , C07C69/78 , C07C69/24 , C07C69/14 , C07C53/10
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17.
公开(公告)号:CA2473954A1
公开(公告)日:2003-07-31
申请号:CA2473954
申请日:2003-01-21
Applicant: BASF AG
Inventor: SEITZ VERENA , FLORES MIGUEL , STEGMANN VEIT , MAASE MATTHIAS , VOLLAND MARTIN , SIEGEL WOLFGANG , HALBRITTER KLAUS , BARTSCH MICHAEL , NOE RALF , PAPP RAINER , MASSONNE KLEMENS , BECKER MICHAEL , HUTTENLOCH OLIVER
IPC: C07D233/58 , B01J31/24 , C07B61/00 , C07B63/00 , C07B63/02 , C07C1/30 , C07C7/10 , C07C13/23 , C07C45/50 , C07C67/14 , C07C67/58 , C07C69/14 , C07C69/78 , C07C403/12 , C07D233/60 , C07D403/12 , C07F7/18 , C07F9/02 , C07F9/12 , C07F9/142 , C07F9/145 , C07F9/22 , C07F9/46 , C07F9/48 , C07F9/50 , C07F9/52 , C07F9/572 , C07F9/6503 , C07F9/6574 , C07F9/6584
Abstract: Disclosed is a method for producing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphite diamides, aminophosphines, diaminophosphines, phosphite amide halogenides, and aminophosphine halogenides by separating an acid in the presence of an auxiliary base. Said auxiliary base b) forms a salt with an acid, which is liquid at temperatures at which the valuable product is not significantly decomposed during separation of the liquid salt, and c) the salt of the auxiliary base and the valuable product or the solution of the valuable product form two immiscible phases in a suitable solvent.
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公开(公告)号:AT336464T
公开(公告)日:2006-09-15
申请号:AT04727522
申请日:2004-04-15
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG , KUNSMANN-KEITEL DAGMAR PASCALE , BASSLER PETER
IPC: C01C3/02 , C01C3/04 , C07C253/00
Abstract: A process for dewatering hydrocyanic acid by distillation, which includes distilling crude hydrocyanic acid containing from 50 to 99.9% by weight of HCN, from 0.1 to 40% by weight of water, from 0 to 15% by weight of carbon oxides and optionally from 0.01 to 1% by weight of an involatile stabilizer, at a pressure of from 1 bar to 2.5 bar, a bottom temperature of from 100° C. to 130° C. and a top temperature of from 25° C. to 54° C., in the absence of a volatile stabilizer, in a distillation column to obtain a top draw stream containing purified, anhydrous hydrocyanic acid and carbon oxides and a bottom draw stream including water and, optionally, the involatile stabilizer.
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公开(公告)号:BR0306886A
公开(公告)日:2004-12-28
申请号:BR0306886
申请日:2003-01-21
Applicant: BASF AG
Inventor: MAASE MATTHIAS , MASSONNE KLEMENS , HALBRITTER KLAUS , NOE RALF , BARTSCH MICHAEL , SIEGEL WOLFGANG , STEGMANN VEIT , FLORES MIGUEL , HUTTENLOCH OLIVER , BECKER MICHAEL
IPC: C07D233/58 , B01J31/24 , C07B61/00 , C07B63/00 , C07B63/02 , C07C1/30 , C07C7/10 , C07C13/23 , C07C45/50 , C07C67/14 , C07C67/58 , C07C69/14 , C07C69/78 , C07C403/12 , C07D233/60 , C07D403/12 , C07F7/18 , C07F9/02 , C07F9/12 , C07F9/142 , C07F9/145 , C07F9/22 , C07F9/46 , C07F9/48 , C07F9/50 , C07F9/52 , C07F9/572 , C07F9/6503 , C07F9/6574 , C07F9/6584
Abstract: Process for preparing aminodihalophosphines, diaminohalophosphines, triaminophosphines, phosphorous ester diamides, aminophosphines, diaminophosphines, phosphorous ester amide halides and aminophosphine halides with elimination of an acid in the presence of an auxiliary base, wherein the auxiliary base b) and the acid form a salt which is liquid at temperatures at which the desired product is not significantly decomposed during the process of separating off the liquid salt and c) the salt of the auxiliary base forms two immiscible liquid phases with the desired product or the solution of the desired product in a suitable solvent.
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公开(公告)号:DE10314761A1
公开(公告)日:2004-10-14
申请号:DE10314761
申请日:2003-03-31
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J23/755 , B01J31/02 , B01J31/14 , B01J31/18 , C07C253/10 , C07C255/04 , B01J31/12 , B01J31/24 , C07B43/08
Abstract: A system which is suitable as a catalyst for the hydrocyanation of olefinically unsaturated compounds and comprises a) Ni(0) b) a compound which complexes Ni(0) as a ligand and contains trivalent phosphorus, c) a Lewis acid and d) a compound of the formula M Rn where M: Al or Ti R: identical or different monovalent alkoxy radicals, in which case a plurality of alkoxy radicals may be bonded together, and additionally, in the case that M=Al, R may be identical or different monovalent alkyl radicals, in which case a plurality of alkyl radicals may be bonded together or one or more alkyl radicals may be bonded to one or more of the abovementioned alkoxy radicals, n: valency of M, and processes for hydrocyanating an olefinically unsaturated compound in the presence of such a system.
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