Pressure-feedable composition containing tricyclodecandimethylol
    1.
    发明专利
    Pressure-feedable composition containing tricyclodecandimethylol 审中-公开
    含有TRICYCLODECANDIMETHYLOL的压力可进料组合物

    公开(公告)号:JP2005325360A

    公开(公告)日:2005-11-24

    申请号:JP2005138911

    申请日:2005-05-11

    CPC classification number: C07D303/22 C07C43/1781 C08F220/00

    Abstract: PROBLEM TO BE SOLVED: To provide a composition which solves the problem of the commercial quality TCD-dimethylol that it is too viscous to pressure-feed and can be pressure-fed from a supplying vessel without melting it to enable the production of secondary products.
    SOLUTION: This composition contains (I) tricyclodecandimethylol and at least one polymerizable, preferably at least mono-unsaturated, compound in the weight ratio of 100:1-1:1, preferably 20:1-3:1. This composition was found possible to pressure-feed without melting it at room temperature.
    COPYRIGHT: (C)2006,JPO&NCIPI

    Abstract translation: 要解决的问题:提供一种解决商品质量TCD-二羟甲基问题的组合物,其过于粘稠而不能进行压力加料,并且可以从供应容器进行压力而不熔化,从而能够生产 二次产品。 解决方案:该组合物包含(I)三环癸二聚羟甲基和至少一种可聚合的,优选至少单不饱和的化合物,其重量比为100:1-1:1,优选为20:1-3:1。 发现这种组合物可能在室温下不进行熔融而进行加压进料。 版权所有(C)2006,JPO&NCIPI

    METHOD FOR THE PRODUCTION OF CYCLOHEXANOL FROM BENZOLE

    公开(公告)号:PL374274A1

    公开(公告)日:2005-10-03

    申请号:PL37427403

    申请日:2003-02-28

    Applicant: BASF AG

    Abstract: A process for preparing cyclohexanol from benzene by: a) preparing cyclohexene by hydrogenating benzene in the presence of a catalyst, and b) preparing cyclohexanol by hydrating the cyclohexene in the presence of a catalyst, comprises: carrying out steps a) and b) in a reaction facility which has a bottom region at the lower end, a top region at the upper end, and a reaction zone between the top region and the bottom region which contains the catalyst according to steps a) and b), evaporating a portion of the benzene using the heat of reaction in the reaction zone, condensing it in the top region and returning it to the reaction zone, and withdrawing a reaction mixture containing cyclohexanol in the bottom region.

    6.
    发明专利
    未知

    公开(公告)号:DE10209701A1

    公开(公告)日:2003-09-18

    申请号:DE10209701

    申请日:2002-03-06

    Applicant: BASF AG

    Abstract: A process for preparing cyclohexanol from benzene by: a) preparing cyclohexene by hydrogenating benzene in the presence of a catalyst, and b) preparing cyclohexanol by hydrating the cyclohexene in the presence of a catalyst, comprises: carrying out steps a) and b) in a reaction facility which has a bottom region at the lower end, a top region at the upper end, and a reaction zone between the top region and the bottom region which contains the catalyst according to steps a) and b), evaporating a portion of the benzene using the heat of reaction in the reaction zone, condensing it in the top region and returning it to the reaction zone, and withdrawing a reaction mixture containing cyclohexanol in the bottom region.

    9.
    发明专利
    未知

    公开(公告)号:DE502005002594D1

    公开(公告)日:2008-03-06

    申请号:DE502005002594

    申请日:2005-08-06

    Applicant: BASF AG

    Abstract: Processes for preparing a C5 aldehyde and propene are disclosed, the processes comprising: (a) providing a feedstream, the feedstream comprising butane, 1-butene, 2-butene and 1,3-butadiene, the 1,3-butadiene present in the feedstream in an amount up to 1000 ppm; (b) contacting the feedstream with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst to form a 2-butene-rich butane stream and a C5 aldehyde; (c) separating the 2-butene-rich butane stream and the C5 aldehyde; and (d) contacting the 2-butene-rich butane stream with ethene in the presence of a metathesis catalyst to form a propene-containing hydrocarbon stream.

    New phosphorous chelate compounds are useful as catalysts for asymmetrical synthesis (preferably as chiral components for the production of pharmaceuticals, plant protecting agents, cosmetics or flavor materials)

    公开(公告)号:DE102005061642A1

    公开(公告)日:2006-07-06

    申请号:DE102005061642

    申请日:2005-12-22

    Applicant: BASF AG

    Abstract: Phosphorous chelate compounds (I) are new. Phosphorous chelate compounds (I) of formula (R1>-P(R2>)-(X)a-Y1>-(O)b-P-((O)c-Rgamma )-(O)d-Rdelta ) are new. either R1>, R2>5-7 membered heterocyclic groups that are bonded over N atom to P atom; or PR1>R2>5-7 membered heterocycle additionally contains optionally substituted N atom and a further under oxygen and optionally substituted N atoms that are bonded directly to P atom; either Rgamma , Rdelta : akyl, cycloalkyl, heterocycloalkyl, aryl or hetaryl (all substituted with 1-5 of cycloalkyl, heterocycloalkyl, aryl, hetaryl, alkoxy, cycloalkoxy, heterocycloalkoxy, aryloxy, hetaryloxy, hydroxy, thiol, polyalkylenoxide, polyalkylenimine, COOH, carboxylate, SO3H, sulfonate, NE1>E2>, NE1>E2>E3>X-, halo, NO2, acyl or CN); or PRgamma Rdelta , ORgamma Rdelta : 5-8 membered heterocycle optionally annealed with 1-3 of cycloalkyl, heterocycloalkyl, aryl or hetaryl, where the heterocycle and optionally the annealed groups are substituted with 1-4 of alkyl, cycloalkyl, heterocycloalkyl, aryl, hetaryl, hydroxy, thiol, polyalkyleneoxide, polyalkylenimine, alkoxy, halo, COOH, carboxylate, SO3H, sulfonate, NE4>E5>, NE4>E5>E6>+>X->, NO2, alkoxycarbonyl, acyl or CN; E4>, E5>, E6>H, alkyl, cycloalkyl or aryl; X : O, S, SiReRf or NRg; Re, Rf, Rg : H, alkyl, cycloalkyl, heterocycloalkyl, aryl or hetaryl; X->anion; Y1>bivalent carbon containing bridge atoms; and a-d : 0-1 (where at least one of b, c or d is 1). Independent claims are also included for: (1) catalyst comprising at least one complex with a transition metal, as ligands of (I); (2) preparation of chiral compounds comprising reacting prochiral compounds containing at least ethylenic unsaturated double bond, with a substrate in the presence of a chiral catalyst; (3) a method for hydroformylation of compounds containing at least ethylenic unsaturated double bond comprising reacting with carbon monoxide and hydrogen in the presence of hydroformylating catalyst; (4) preparation of 2-propylheptanol comprising subjecting butene or butene containing C4-hydrocarbon mixture of hydroformylation to obtain n-valeraldehyde containing hydroformylating products, optionally isolating hydroformylating products under n-valeraldehyde enriched groups, subjecting the obtained hydroformylating products and n-valeraldehyde enriched groups to aldol condensation, hydrogenating the products of aldol condensation, catalytically with hydrogen to alcohols and optionally subjecting the hydrogenation products to isolate 2-propylheptanol enriched groups; and (5) a method of hydroformylation of alpha -olefine and olefine with inner double bonds containing a composition, comprising reacting with carbon monoxide and hydrogen in the presence of hydroformylating catalyst in two-stage reaction system (where the first step comprises feeding an inlet containing olefin, carbon monoxide and hydrogen and converting partly catalytically; feeding and converting the discharge from the above step; and feeding the discharge from the second step with a stream obtained from non-reacted olefine and saturated hydrocarbons).

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