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    15.
    发明专利
    未知

    公开(公告)号：ES2156358T3

    公开(公告)日：2001-06-16

    申请号：ES97903319

    申请日：1997-02-19

    Applicant: BASF AG

    Inventor： LYNCH JOHN ,  FISCHER DAVID ,  GORTZ HANS-HELMUT ,  SCHWEIER GUNTHER

    IPC: C08F4/12 ,  C08F4/44 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00 ,  C08F110/02

    Abstract: Supported catalyst systems are obtainable byA) reaction of an inorganic carrier with a metal compound of the general formula I whereM1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table,R1 is hydrogen, Ch1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,r is an integer from 1 to 4 ands, t and u are integers from 0 to 3 the sum r+s+t+u corresponding to the valency of M1,B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions andC) subsequent reaction with a metal compound of the general formula II whereM2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table,R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R6 and R7 are hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl or alkoxy each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,o is an integer from 1 to 3 andp and q are integers from 0 to 2 the sum o+p+q corresponding to the valency of M2.

    17.
    发明专利
    未知

    公开(公告)号：BR9707570A

    公开(公告)日：1999-07-27

    申请号：BR9707570

    申请日：1997-02-19

    Applicant: BASF AG

    Inventor： LYNCH JOHN ,  FISCHER DAVID ,  GORTZ HANS-HELMUT ,  SCHWEIER GUNTHER

    IPC: C08F4/12 ,  C08F4/44 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/646 ,  C08F4/68 ,  C08F10/00 ,  C08F110/02

    Abstract: Supported catalyst systems are obtainable byA) reaction of an inorganic carrier with a metal compound of the general formula I whereM1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table,R1 is hydrogen, Ch1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,r is an integer from 1 to 4 ands, t and u are integers from 0 to 3 the sum r+s+t+u corresponding to the valency of M1,B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions andC) subsequent reaction with a metal compound of the general formula II whereM2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table,R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R6 and R7 are hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl or alkoxy each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,o is an integer from 1 to 3 andp and q are integers from 0 to 2 the sum o+p+q corresponding to the valency of M2.

    18.
    发明专利
    未知

    公开(公告)号：BR9707565A

    公开(公告)日：1999-07-27

    申请号：BR9707565

    申请日：1997-02-19

    Applicant: BASF AG

    Inventor： LYNCH JOHN ,  FISCHER DAVID ,  GORTZ HANS-HELMUT ,  SCHWEIER GUNTHER

    IPC: C08F2/14 ,  C08F2/18 ,  C08F4/02 ,  C08F4/60 ,  C08F4/642 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/68 ,  C08F10/00 ,  C08F110/02

    Abstract: Polymers of alkenes are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are supported catalyst systems obtainable by A) reaction of an inorganic carrier with a metal compound of the general formula I M1(R1)r(R2)s(R3)t(R4)u I where M1 is an alkali metal, an alkaline earth metal or a metal of main group III or IV of the Periodic Table, R1 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R2 to R4 are each hydrogen, halogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl, arylalkyl, alkoxy or dialkylamino, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, r is an integer from 1 to 4 and s, t and u are integers from 0 to 3, the sum r+s+t+u corresponding to the valency of M1, B) reaction of the material obtained according to A) with a metallocene complex in its metal dihalide form and a compound forming metallocenium ions and C) subsequent reaction with a metal compound of the general formula II M2(R5)o(R6)p(R7)q IIin which M2 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table, R5 is hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R6 and R7 are each hydrogen, halogen, C1-C

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