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    11.
    发明专利
    未知

    公开(公告)号：DK0422493T3

    公开(公告)日：1994-01-24

    申请号：DK90118944

    申请日：1990-10-04

    Applicant: BASF AG

    Inventor： KAST JUERGEN DR ,  SCHUBERT JUERGEN DR ,  KACZMAREK REINHARD DR

    IPC: C07C327/24 ,  C07C327/28 ,  C07C327/58

    Abstract: Preparation of cyclohexanetrionecarboxylic acid thiol esters of the formula I in which R and R represent optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, benzyl or phenyl, and R additionally denotes hydrogen, by reacting a cyclohexanetrione compound II with hydroxylamine or hydroxylamine O-sulphonic acid in an inert solvent at temperatures from 0 to 150 DEG C to give cyclohexanetrione compounds III subsequently reacting the compounds III with a mercaptan IV R -SH IV in the presence of an anhydrous acid HX to give cyclohexanetrione imidothioester salts V where X represents the acid radical, and hydrolysing the compounds V to give the cyclohexanetrione carboxylic acid thiol esters I.

    13.
    发明专利
    未知

    公开(公告)号：DE58901178D1

    公开(公告)日：1992-05-21

    申请号：DE58901178

    申请日：1989-11-07

    Applicant: BASF AG

    Inventor： WILD JOCHEN DR ,  HARREUS ALBRECHT DR ,  SCHIRMER ULRICH DR ,  MEYER NORBERT DR ,  KAST JUERGEN DR ,  KOLASSA DIETER DR

    IPC: C07C239/20 ,  C07C323/19 ,  C07D209/48

    Abstract: Hydroxylamine derivatives have the general formula I Aryl-A-O-B I where Aryl is an unsubstituted or substituted, mononuclear or binuclear, isocyclic radical; A is a 1,4-butenylene group of the general formulae IIa or IIb IIa IIb where R1, R2, R3, R4 and R5 are each hydrogen, halogen, C1-C6-alkyl or C1-C6-alkenyl; B is NH2 or a dicarboximide group of the general formula III III where Z is unsubstituted or substituted phenylene, naphthylene, pyridinylene, cyclopentylene, cyclohexylene, cyclohexenylene, C2-C4-alkenylene or C2-C4-alkylene. The dicarboximides are intermediates for the compounds wherein B is NH2. The latter are used in synthesizing herbicidal compounds.

    Cyclohexenone-oxime-ester derivs.
    14.
    发明专利
    Cyclohexenone-oxime-ester derivs. 未知

    公开(公告)号：DE4033423A1

    公开(公告)日：1992-04-23

    申请号：DE4033423

    申请日：1990-10-20

    Applicant: BASF AG

    Inventor： MISSLITZ ULF DR ,  MEYER NORBERT DR ,  KAST JUERGEN DR ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR ,  WUERZER BRUNO DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR

    IPC: A01N35/10 ,  A01N43/14 ,  C07C239/20 ,  C07D309/06 ,  C07D335/02

    Abstract: Cyclohexenone oxime ether derivs. of formula (I) and their agriculturally useful salts and esters of 1-10C carboxylic acids and inorganic acids are new. R1 = 1-6C alkyl; A = oot. 1-3C alkyl-substd. 3-6C alkylene or 4-6C alkenyl in which one CH2 gp. is replaced by O, S, SO, SO2 or N(Ra); Ra = H, 1-4C alkyl, 3-6C alkenyl or 3-6C alkynyl; Z = Ph, 5-membered heteroaromatic contg. 1-3 heteroatoms chosen from 3N, O or S or 4-membered heteroaromatic contg. 1-4N; X = NRaRb, NO2 CN, halogen, 1-4C alkyl, partially or completely halogenated 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, partially or completely halogenated 1-4C alkoxv, carboxyl, 1-4C alkoxy carbonyl, benzyloxycarbonyl or KPh; n= 0-3 or 1-5 if Z = halogen; Rb = as Ra or is 1-6C aryl or R2 = 1-4C alkoxy(1-6C)alkyl, 1-4Calkylthio(1-6C)alkyl, 3-7C cycloalkyl, 5-7C cycloalkenyl, a 5-membered heterocycle (contg. 1 or 2 heteroatoms chosen from O and S), a 6- or 7-membered satd., singly or double unsatd. heterocycle (contg. or 2 heteroatoms chosen from O and S and opt. mono-, di or tri-substd. by O, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C di or tri-substd. by OH, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio or partially or completely halogenated 1-4C alkyl), a 5-membered heteroaromatic (contg. 1-3 heteroatoms chosen from O and S and opt. mono-, di or tri-substd. by halogen, CN, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, oartially or completely halogenated 1-4C alkyl, 2-6C alkenyl, 2-6C alkenyloxy, partially or completely halogenated 2-6C alkenyl or 1-4Calkoxy(1-4C)alkyll, Ph or pyridyl.

    New cyclohexenone oxime halo:phenyl-butyl ether(s) - useful as herbicides, esp. for control of weed grasses
    15.
    发明专利
    New cyclohexenone oxime halo:phenyl-butyl ether(s) - useful as herbicides, esp. for control of weed grasses 未知

    公开(公告)号：DE4018499A1

    公开(公告)日：1991-12-12

    申请号：DE4018499

    申请日：1990-06-09

    Applicant: BASF AG

    Inventor： KAST JUERGEN DR ,  MEYER NORBERT DR ,  MISSLITZ ULF DR ,  HARREUS ALBRECHT DR ,  WALTER HELMUT DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR

    IPC: A01N35/10 ,  A01N43/14 ,  C07D231/12 ,  C07D309/06

    Abstract: Cyclohexenone oxime ethers (I) and their salts and 1-10C carboxylic acid and inorganic acid esters are new: where R1 = 1-6C alkyl; R2 = 1-4C alkoxy-1-6C alkyl; 1-4C alkylthio-1-6C alkyl; 3-7C cycloalkyl or 5-7C cycloalkenyl opt. mono-, di- or tri-substd. by 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkyl, hydroxy and/or halogen; a 5-membered satd. heterocyclic gp. contg. 1 or 2 O and/or S atoms and opt. mono-, di- or tri-substd. by 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio and/or 1-4C haloalkyl; a 6-membered heterocyclic gp. contg. 1 or 2 O and/or S atoms and up to 2 double bonds and opt. mono-, di- or tri-substd. by hydroxy, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio and/or 1-4C haloalkyl; a 5-membered heteroaromatic gp. contg. 1 or 2 N atoms and/or 1 O or S atom and opt. mono-, di- or tri-substd. by halogen, cyano, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkyl, 2-6C alkenyl, 2-6C alkenyloxy, 2-6C haloalkenyl and/or 1-4C alkoxy-1-4C alkyl; or phenyl or pyridyl opt. mono-, di- or tri-substd. by halogen, nitro, cyano, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C alkoxy-1-4C alkyl, 1-4C alkylthio-1-4C alkyl, 1-4C haloalkyl, 3-6C alkenyloxy, 3-6C alkynyloxy and/or -NR3R4; R3 = H; 1-4C alkyl; 3-6C alkenyl; or 3-6C alkynyl; R4 = H; 1-4C alkyl; 3-6C alkenyl; 3-6C alkynyl; 1-6C acyl; or benzoyl opt. mono-, di- or tri-substd. in the ring by nitro, cyano, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio and/or 1-4C haloalkyl; X = halogen; n = 1-5.

    16.
    发明专利
    未知

    公开(公告)号：DE4014985A1

    公开(公告)日：1991-11-14

    申请号：DE4014985

    申请日：1990-05-09

    Applicant: BASF AG

    Inventor： SAUPE THOMAS DR ,  KAST JUERGEN DR ,  MISSLITZ ULF DR ,  HAGEN HELMUT DR ,  NILZ GERHARD DR ,  PFISTER JUERGEN DR ,  WALTER HELMUT DR ,  LANDES ANDREAS DR

    IPC: A01N25/32 ,  A01N35/10 ,  A01N37/34 ,  A01N37/44 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N43/28 ,  A01N43/653 ,  A01N43/80 ,  A01N43/836

    Abstract: Herbicidal agent containing a naphthalene derivative I (R = alkyl, alkylthio, haloalkyl, alkoxy, halogen, OH, NO2 and/or benzyl; m = 0, 1, 2 or 3; R = -CN, -C(NH2)NOH, -C(Z)TR , R = halogen, -NR R , -N=CH-R , -NR -SO2R , COOR , OH, Z = O, S; T = O, -NR ; R = H, optionally substituted alkyl, phenyl or benzyl; R = optionally substituted phenyl; R = H, optionally substituted alkyl or phenyl; R = H or optionally substituted alkyl; R = optionally substituted alkyl, phenyl or an optionally substituted heteroaromatic ring; R = optionally substituted alkyl or phenyl, or the R radicals together are an optionally substituted alkylene or alkenylene chain, or an optionally substituted fused benzene ring; R and R = alkyl or, together with the joint carbon atom, cycloalkyl; B = H, optionally substituted alkyl, alkoxycarbonyl, phenyl or -NR R -) as an antidote, and at least one herbicidal active substance from the group of the cyclohexenone derivatives.

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