公开(公告)号：DE58902234D1

公开(公告)日：1992-10-15

申请号：DE58902234

申请日：1989-06-01

Applicant: BASF AG

Inventor： SEELE RAINER DR ,  KOBER REINER DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: C07D405/00 ,  A01N43/50 ,  A01N43/653 ,  C07D405/06 ,  C07D405/14 ,  C07D521/00

公开(公告)号：DE4029197A1

公开(公告)日：1992-03-19

申请号：DE4029197

申请日：1990-09-14

Applicant: BASF AG

Inventor： SEELE RAINER DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR ,  KEIL MICHAEL DR ,  KOBER REINER DR ,  GOETZ NORBERT DR

IPC: A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08 ,  C07D303/04 ,  C07D303/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D405/08 ,  C07D407/04 ,  C07D407/06 ,  C07D493/10 ,  C07D521/00

Abstract: (A)Azolylmethyl-substd. cyclic alcohols of formula (I) and their acid-addn. salts and metal complexes are new. X= CH or N; T= (CH2)n, CR11R12, O or S; n= 1-5; R1 and R5= H or 1-4C alkyl, or CR1R5= C=CHR7 or CHZR'7; Z=CH2, O, SO, SO, SO2 or NR8; R7= (a) 1-8C alkyl, phenyl, biphenylyl, naphthyl, benzyl or 3-8C cycloalkyl, all opt. substd. by 1-3 of halogen, NO2, OPh, NH2, 1-4C alkyl, 1-4C alkoxy, or 1-4C haloalkyl, or (b) tetrahydropyranyl; R'7= H or R7; R2 and R3= H or 1-4C alkyl, or CR2R3 may be C=CHR7 when CR1R5 is C=CHR7; R4 and R8= H or 1-4C alkyl; or R3+R4 completes a satd. or unsatd. 5-6C carbocyclic ring; R6 and R9-R12= 1-8C alkyl, phenyl, biphenylyl, naphthyl, heteroaryl, benzyl, dioxolanyl or 3-8C cycloalkyl, all opt. substd. by 1-3 of halogen, NO2, OPh, NH2, 1-4C alkyl, 1-4C alkoxy or 1-4C haloalkyl; or R2+R3+R4+R9 completes an opt. halo-substd. benzene ring; etc.

公开(公告)号：DE4009594A1

公开(公告)日：1991-10-02

申请号：DE4009594

申请日：1990-03-26

Applicant: BASF AG

Inventor： SEELE RAINER DR ,  GOETZ NORBERT DR ,  BROX WOLFGANG DR ,  KOBER REINER DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D233/60 ,  C07D249/08 ,  C07D401/06 ,  C07D403/06 ,  C07D405/06 ,  C07D409/06 ,  C07D417/06 ,  C07D521/00

Abstract: Azolylethane derivatives of the formula I I where A and R1 are each alkyl, phenyl, biphenyl, naphthyl, benzyl, cycloalkyl, alkoxy, alkylthio, phenoxy, benzyloxy, phenylthio, methoxycarbonylethyl or hetaryl, these radicals being substituted or unsubstituted, D is halogen, alkoxy, alkylthio, phenylthio or phenoxy, these radicals being substituted or unsubstituted, X is CH or N, plant-tolerated acid addition salts and metal complex compounds thereof, and fungicides containing these compounds.

公开(公告)号：DE58900084D1

公开(公告)日：1991-05-16

申请号：DE58900084

申请日：1989-09-30

Applicant: BASF AG

Inventor： SEELE RAINER DR ,  KOBER REINER DR ,  KARBACH STEFAN DR ,  SAUTER HUBERT DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR ,  RADEMACHER WILHELM DR ,  JUNG JOHANN PROF DR

IPC: A01N43/50 ,  A01N43/653 ,  A01N43/836 ,  A61K31/41 ,  A61K31/415 ,  C07D233/56 ,  C07D233/60 ,  C07D233/61 ,  C07D249/08 ,  C07D401/10 ,  C07D405/10 ,  C07D521/00

Abstract: Azolylmethylcyclopropanes of the formula I where R is alkyl, cycloalkyl, cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenyl or phenyl, and these radicals are substituted or unsubstituted, A is H, F, Cl or Br, and X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides and growth-regulating agents containing these compounds.

公开(公告)号：DE3930166A1

公开(公告)日：1991-03-21

申请号：DE3930166

申请日：1989-09-09

Applicant: BASF AG

Inventor： SEELE RAINER DR ,  GOETZ NORBERT DR ,  KOBER REINER DR ,  ZIPPERER BERNHARD DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: A01N43/50 ,  A01N43/653 ,  C07D213/48 ,  C07D303/16 ,  C07D405/04 ,  C07D521/00

Abstract: Azolylmethyl-oxiranes (I) and their addn salts and metal complexes are new. A = 1-8C alkyl, phenyl, biphenyl, naphthyl, benzyl, tetrahydropyranyl or 3-8C cycloalkyl opt. mono-,di- or trisubstd. by halogen, nitro, phenoxy, amino or 1-4C alkyl, alkoxy or haloalkyl; X = CH or N. Starting materials (II) are also cl-aimed. L = nucleophilic leaving gp. USE/ADVANTAGE: Cpds (I) are broad spectrum fungicides used to treat plants, seeds, soil and materials, they are formulated conventionally and applied in amts. of 0.02-3 kg/ha. Cpds (I) have a better activity than the cpds. described in EP 94564 and EP 196038. 2 Cpds (I) i.e. 2-(1,2,4-triazol-1-ylmethyl) -2-(4-fluorophenyl)-3-)(2 -methylphenyl)-oxirane and the corrssp. 4-chlorophenyl cpd are claimed. In an example a) 2-methylbenzaldehyde was condensed with 4-fluorophenyl-acetaldehyde in the presence of NaOH and the prod was epoxidised (H2O2) and reduced (NaBH4) to give cis-2-hydroxymethyl-2) (4-fluorophenyl)-3-(2-methylphenyl) -oxirane which was converted (CH2SO2Cl) into cis-2-methanesulphonyl-methyl-2-)(4-fluorophenyl)-3-) (2-methylphenyl)-oxirane (II) b) 1,2,4-triazole (4.9g) in dimethylformamide (100 ml) was treated with K2CO3(16.4g), heated, cooled, treated with a soln of the prod from a) (20g) in dimethylformamide (50 ml) and stirred. The mixt was added to water, extracted and the extr-act was washed dired and concentrated to give (1,2,4-triazol-1-ylmethyl) -2-(4-fluorophenyl)-(3-(2-methyl-phenyl) -oxirane (I) (15g), m.pt 99-102 deg.C. (tert, butyl methyl ether/hexane). :(14pp Dwg.No. 0/0)

公开(公告)号：DE3913725A1

公开(公告)日：1990-10-31

申请号：DE3913725

申请日：1989-04-26

Applicant: BASF AG

Inventor： SEELE RAINER DR ,  KOBER REINER DR ,  GOETZ NORBERT DR ,  SAUPE THOMAS DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR ,  RADEMACHER WILHELM DR ,  JUNG JOHANN PROF DR

IPC: A01N43/50 ,  A01N43/54 ,  A01N43/653 ,  C07D233/60 ,  C07D233/61 ,  C07D233/64 ,  C07D249/08 ,  C07D303/32 ,  C07D401/06 ,  C07D401/14 ,  C07D405/06 ,  C07D405/14 ,  C07D521/00

Abstract: 1-Halovinylazoles of the general formula I I where A and R are each alkyl, cycloalkyl, cycloalkenyl, pyridyl, tetrahydropyranyl, naphthyl, biphenyl or phenyl, each of these radicals being substituted or unsubstituted, D is chlorine or bromine, and X is CH or N, acid addition salts and metal complexes thereof which are tolerated by plants, and fungicides and growth regulators containing these compounds.

公开(公告)号：DE3807951A1

公开(公告)日：1989-09-21

申请号：DE3807951

申请日：1988-03-10

Applicant: BASF AG

Inventor： SEELE RAINER DR ,  KARBACH STEFAN DR ,  JANSSEN BERND DR ,  KOBER REINER DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: C07D405/06 ,  A01N43/50 ,  C07D405/14 ,  C07D521/00

Abstract: Imidazolylmethyloxiranes of the general formula I I where R is phenyl, pyridyl, tetrahydropyranyl, norbornyl, C3-C12-cycloalkyl or C5-C8-cycloalkenyl, these radicals being unsubstituted or substituted, and their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.

公开(公告)号：DE3804990A1

公开(公告)日：1989-08-31

申请号：DE3804990

申请日：1988-02-18

Applicant: BASF AG

Inventor： SAUPE THOMAS DR ,  KLEBE GERHARD DR ,  SCHIRMER ULRICH DR ,  PAUL GERHARD DR ,  KOBER REINER DR ,  WUERZER BRUNO DR ,  BERGHAUS RAINER DR ,  MEYER NORBERT DR ,  WESTPHALEN KARL-OTTO DR

IPC: A01N43/90 ,  C07D471/04

Abstract: Sulfonamides of the general formula I I where A, n, R1, R2, R3, W, X, Y and Z have the meanings given in the disclosure and claims, salts and N-oxides thereof, and their use as herbicidal agents.

公开(公告)号：DE3609972A1

公开(公告)日：1986-10-30

申请号：DE3609972

申请日：1986-03-25

Applicant: BASF AG

Inventor： KOBER REINER DR ,  STEGLICH WOLFGANG PROF DR ,  MILZ WOLFGANG ,  SCHRADER THOMAS ,  ENDERS DIETER PROF DR ,  PAPADOPOULOS KYRIAKOS

IPC: C07D335/02 ,  C07D409/04 ,  C07F9/40 ,  C07C103/84

Abstract: Preparation of optically active alpha -acylamino- gamma -oxocarboxylates and alpha -acylamino- gamma -oxophosphonates I (where R and R are H, organic radicals C1-C12 or linked to give a 5- or 6-membered ring; R is an organic radical; R and R are optically active or non-active organic radicals, optionally linked to form a 5- or 6-membered ring; Y is C or P; n is 0 if Y is C; n is 1 if Y is P; C is the chiral centre which is critical for optical activity), by reacting an enamine II (where A is an optically active or inactive radical of a secondary amine) with a base and an alpha -halo- alpha -acylaminocarboxylate or -phosphonate III (where Hal is Cl or Br) and subsequently eliminating the amine AH, where at least one of the radicals A, R and R is derived from an optically active secondary amine or an optically active alcohol R -OH or R -OH.

公开(公告)号：ES2078279T3

公开(公告)日：1995-12-16

申请号：ES90116033

申请日：1990-08-22

Applicant: BASF AG

Inventor： KOBER REINER DR ,  SEELE RAINER DR ,  ZIERKE THOMAS DR ,  ISAK HEINZ DR ,  KARBACH STEFAN DR ,  WEGNER GUNTER DR

IPC: C07B49/00 ,  C07F3/02 ,  C07F7/08

Abstract: Preparation of ether solutions of arylmethylmagnesium halides… Ar-CH2-Mg-Hal I… (Aryl = unsubstituted or substituted aryl; Hal = Cl, Br) by the Grignard process from arylmethyl halides II… Ar-CH2-Hal II… with magnesium in an ether as a solvent, by using III… tert-butyl-O-R III… (R = C1-C3-alkyl) for this purpose.