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公开(公告)号:ZA976164B
公开(公告)日:1999-01-11
申请号:ZA976164
申请日:1997-07-11
Applicant: BASF AG
Inventor: GENZ MANFRED , MERGER ROLAND , BOLLMANN HEINZ , THAERIGEN RAINA , VOELKEL RUEDIGER , KRAUS RUPERT , POHL SIEGMUND
Abstract: Production of microcellular polyurethane elastomers is claimed by reacting (A) high mol. polyhydroxy compounds and optionally (B) low. mol. chain extenders and/or crosslinkers with (C) 3,3'-dimethoxy-4,4'- diisocyanato-diphenyl in presence or absence of (D) catalysts, foaming agents etc.. Preferably the polyhydroxy component (A) is of functionality 2-3 and mol. wt. 500-6,000 and is especially a difunctional polyester polyol, OH-containing polycarbonate or polyoxybutylene glycol of mol. wt. 800-3,500 while the chain extender is an alkane diol, dialkylene glycol or polyoxyalkylene glycol of mol. wt. up to 800 and the crosslinker is also of mol. wt. up to 800 and is a tri-or tetra-hydric alcohol or polyoxyalkylene polyol of functionality 3-4. Preparation of the elastomer is by: (1) first preparing a prepolymer of NCO content 2-20 wt.% by reacting (C) with (A) and optionally (B) and then reacting this prepolymer with water and optionally also (B); or (2) first reacting (C) with part of (A) and optionally also (B) and then reacting the prepolymer obtained with a mixture of water, the remainder of (A) and optionally also (B).
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公开(公告)号:AU3438997A
公开(公告)日:1998-02-09
申请号:AU3438997
申请日:1997-06-30
Applicant: BASF AG
Inventor: GENZ MANFRED , MERGER ROLAND , BOLLMANN HEINZ , THARIGEN RAINA , VOELKEL RUDIGER , KRAUS RUPERT , POHL SIEGMUND
IPC: C08G18/10 , C08G18/42 , C08G18/48 , C08G18/66 , C08G18/76 , C08G18/77 , C08G18/81 , C08J9/00 , C08J9/14
Abstract: A process is disclosed for preparing microcellular polyurethane elastomers by reacting: (a) high-molecular polyhydroxyl compounds, optionally (b) low-molecular chain-lengthening and/or cross-linking agents with (c) 3,3'-dimethoxy-4,4'-diisocyanato-diphenyl and/or 4,4'-stilbene-diisocyanate in the presence or absence of (d) catalysts; (e) foaming agents; and (f) additives. Also disclosed are isocyanate prepolymers suitable for preparing these elastomers.
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公开(公告)号:DE10145787A1
公开(公告)日:2003-04-10
申请号:DE10145787
申请日:2001-09-17
Applicant: BASF AG
Inventor: OCHSE MICHAEL , KRAUS RUPERT , DITTRICH CHRISTIAN , PLAUMANN HEINZ
IPC: C07C209/84 , C07C263/10 , C07C265/14
Abstract: Production of methylenedi(phenyl isocyanate) comprises reacting aniline with formaldehyde in the presence of an acid catalyst to form methylenedi(phenylamine), removing water and unreacted aniline without neutralizing the reaction mixture, and reacting the product with phosgene.
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公开(公告)号:AT201220T
公开(公告)日:2001-06-15
申请号:AT97930439
申请日:1997-06-30
Applicant: BASF AG
Inventor: GENZ MANFRED , MERGER ROLAND , BOLLMANN HEINZ , THAERIGEN RAINA , VOELKEL RUEDIGER , KRAUS RUPERT , POHL SIEGMUND
IPC: C08G18/10 , C08G18/42 , C08G18/48 , C08G18/66 , C08G18/76 , C08G18/77 , C08G18/81 , C08J9/00 , C08J9/14
Abstract: A process is disclosed for preparing microcellular polyurethane elastomers by reacting: (a) high-molecular polyhydroxyl compounds, optionally (b) low-molecular chain-lengthening and/or cross-linking agents with (c) 3,3'-dimethoxy-4,4'-diisocyanato-diphenyl and/or 4,4'-stilbene-diisocyanate in the presence or absence of (d) catalysts; (e) foaming agents; and (f) additives. Also disclosed are isocyanate prepolymers suitable for preparing these elastomers.
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公开(公告)号:MX9704810A
公开(公告)日:1998-07-31
申请号:MX9704810
申请日:1997-06-26
Applicant: BASF AG
Inventor: KRAUS RUPERT , TESCH HELMUT , BRUCHMANN BERND , SEYFERT WILFRIED , NEVEJANS FILIP , ABEEL PETER VAN DEN
IPC: C07C263/10 , C07C263/18 , C07C263/20 , C07C265/00 , C08G18/70 , C08G101/00 , C08G18/02
Abstract: Es un proceso para la preparacion de soluciones que contienen al menos isocianato, la solucion escribe definida se somete a un tratamiento con hidrogeno después de la fosgenacion y antes de la remocion completa del solvente y del fosgeno residual. Se ofrece un proceso para la preparacion de isocianatos o bien mezclas de isocianatos y los isocianatos preparados de esta forma pueden emplearse para la preparacion de poliuretanos, particularmente espumas de poliuretano.
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