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公开(公告)号:AU580816B2
公开(公告)日:1989-02-02
申请号:AU5059485
申请日:1985-11-29
Applicant: BASF AG
Inventor: MUELLER-MALL RUDOLF , WISTUBA ECKEHARDT , MATTHAEI LOTHAR , MELAN MICHAEL
IPC: C08F2/00 , C08F2/22 , C08F2/24 , C08F2/26 , C08F2/28 , C08F20/52 , C08F220/04 , C08F220/10 , C08F220/54 , C08F285/00 , C08F291/00 , C09D5/00 , C09D5/02 , C09D151/00 , C08F20/18 , C08F2/30 , C08F10/02 , C08F12/08 , C08F20/14 , C08F20/44 , C08J5/22 , C09D3/76
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公开(公告)号:DK555085D0
公开(公告)日:1985-11-29
申请号:DK555085
申请日:1985-11-29
Applicant: BASF AG
Inventor: MUELLER-MALL RUDOLF , MELAN MICHAEL , WISTUBA ECKEHARDT , MATTHAEI LOTHAR
IPC: C08F2/00 , C08F2/22 , C08F2/24 , C08F2/26 , C08F2/28 , C08F20/52 , C08F220/04 , C08F220/10 , C08F220/54 , C08F285/00 , C08F291/00 , C09D5/00 , C09D5/02 , C09D151/00 , C08F , C09D
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公开(公告)号:AU5116579A
公开(公告)日:1980-04-17
申请号:AU5116579
申请日:1979-09-25
Applicant: BASF AG
Inventor: MUELLER-MALL RUDOLF , WENDEL KURT , GEELHAAR HANS JOACHIM , MELAN MICHAEL
IPC: C08F2/00 , C08F2/22 , C08F2/24 , C08F2/30 , C08F2/38 , C08F20/12 , C08F20/14 , C08F20/18 , C08F220/14 , C08F220/18
Abstract: Aqueous polyacrylate dispersions having improved flow characteristics are prepared by polymerizing esters of acrylic acid and/or methacrylic acid and alkanols of 1 to 10 carbon atoms, with or without admixture of styrene and/or vinyl esters and/or water-soluble monoolefinically unsaturated comonomers (the monomer feed being in the form of an emulsion), in aqueous emulsion in the presence of a free radical polymerization initiator, a protective colloid, a nonionic emulsifier and a regulator, at least a part of the protective colloid being introduced into an aqueous initial charge, and a water-soluble regulator being employed in the initial charge and in the feed.
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公开(公告)号:DE50205227D1
公开(公告)日:2006-01-12
申请号:DE50205227
申请日:2002-10-29
Applicant: BASF AG
Inventor: LACH CHRISTIAN , MELAN MICHAEL
IPC: C08F220/12 , C08F257/02 , C08F265/04 , C08K5/00 , C08K5/132 , C08L51/00 , C09D151/00 , C09J151/00
Abstract: An aqueous synthetic resin formulation essentially comprising a synthetic resin A, a metallic cation with a charge number of from 2 to 4, dispersants, water, and finely divided fillers, and also, if desired, acetophenone derivatives or benzophenone derivatives, the resin A being prepared by free-radically initiated aqueous emulsion polymerization of monomers in the presence of from 0.01 to 3 parts by weight of an alien polymer seed per 100 parts by weight of the monomer mixture.
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公开(公告)号:DE10153932A1
公开(公告)日:2003-05-22
申请号:DE10153932
申请日:2001-11-06
Applicant: BASF AG
Inventor: LACH CHRISTIAN , MELAN MICHAEL
IPC: C08F220/12 , C08F257/02 , C08F265/04 , C08K5/00 , C08K5/132 , C08L51/00 , C09D151/00 , C09J151/00 , C09D5/02 , C09D5/12 , C09D133/12 , C08F220/18
Abstract: The invention relates to an aqueous synthetic resin preparation, which essentially contains a synthetic resin A, a metal cation with a charge number of 2 to 4, dispersing agents, water and fine-particle fillers as well as optionally acetophenone or benzophenone derivatives, whereby said synthetic resin A is produced by radically initiated aqueous emulsion polymerisation of monomers in the presence of 0.01 to 3 parts by weight of an external polymerisation initiator, based on 100 parts by weight of the monomer mixture.
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公开(公告)号:AU5349200A
公开(公告)日:2001-02-22
申请号:AU5349200
申请日:2000-08-18
Applicant: BASF AG
Inventor: BAUMSTARK ROLAND , KIRSCH STEFAN , DERSCH ROLF , DOBBELAAR JOHANNES , MELAN MICHAEL
IPC: C08L33/06 , C08F2/24 , C08F212/02 , C08F212/04 , C08F220/12 , C08K5/00 , C08L25/00 , C09D5/02 , C09D125/02 , C09D133/06 , E04C2/04 , C09D133/08 , C09D133/10 , C09D125/14 , C08L33/08 , C08L33/10 , C08L25/14
Abstract: Binder preparation with a minimum film-forming temperature below 10 degrees C, based on a dispersion containing anionic and non-ionic emulsifiers and a copolymer of 20-50 wt% vinyl-aromatic monomer, 45-70 wt% 1-18C alkyl acrylate or 5-18C alkyl methacrylate which forms a homopolymer with a Tg below 10 degrees C, 2-4 wt% methacrylic acid and optionally other comonomers. A binder preparation with a minimum film-forming temperature (MFT) below 10 degrees C, based on a binder polymer (P) in the form of an aqueous dispersion containing anionic emulsifier(s) and non-ionic emulsifier(s), in which (P) is a copolymer of (A1) 20-50 wt% vinyl-aromatic monomer(s), (A2) 0-15 wt% 1-4C alkyl (meth)acrylate(s), (A3) 0-30 wt% (meth)acrylonitrile, (B) 45-70 wt% monomer(s) which form a homopolymer with a glass transition point (Tg) below 10 degrees C, selected from 1-18C alkyl acrylates and 5-18C alkyl methacrylates, (C) 2-4 wt% methacrylic acid, (D) 0-3 wt% monomer(s) selected from amides, 1-4C hydroxyalkyl esters and 1-4C alkyl-polyalkyleneoxide-esters of 3-6C mono-unsaturated monocarboxylic acids and (E) 0-5 wt% other monomer(s), where the total amount of monomers (A1)-(A3) does not exceed 55 wt% of the total monomer content and the content of (A2) is at least 5 wt% if the content of (A3) is less than 0.5 wt%. An Independent claim is also included for emulsion paint containing binder preparation(s) as described.
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公开(公告)号:CA1226998A
公开(公告)日:1987-09-15
申请号:CA436433
申请日:1983-09-09
Applicant: BASF AG
Inventor: GELLERT ROLAND , MATTHAEI LOTHAR , MELAN MICHAEL , KERCKOW ALBRECHT , PETERS KARL-CLEMENS , WISTUBA ECKEHARDT , WULGARIS SAVAS
IPC: C08F18/00 , C08F2/22 , C08F18/02 , C08F218/10 , C09D5/34 , C09J131/02 , C09J131/04 , C09J3/14
Abstract: Binders for building adhesives, troweling compounds and plasters are based on emulsion copolymers comprising predominant amounts of vinyl propionate, as well as tert.-butyl acrylate and minor amounts of acrylic acid, with or without other monomers, and are used for bonding tiles and heat-insulating sheets.
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公开(公告)号:AU562637B2
公开(公告)日:1987-06-18
申请号:AU1899183
申请日:1983-09-09
Applicant: BASF AG
Inventor: GELLERT ROLAND , MELAN MICHAEL , KERCKOW ALBRECHT , PETERS KARL-CLEMENS , WISTUBA ECKEHARDT , WULGARIS SAVAS , MATTHAEI LOTHAR
IPC: C08F18/00 , C08F2/22 , C08F18/02 , C08F218/10 , C09D5/34 , C09J131/02 , C09J131/04 , C08F2/24
Abstract: 1. A binder for building adhesives, troweling mixes and plasters which is based on a halogen-free emulsion copolymer of monoolefinically unsaturated carboxylates, wherein the emulsion copolymer comprises (a) from 55 to 72 % by weight of vinyl propionate, (b) from 44,9 to 27,5 % by weight of tert.-butyl acrylate, (c) from 0.1 to 0.5 % by weight of acrylic acid or methacrylic acid, and (d) from 0 to 17.5 % by weight of a monoolefinically unsaturated carboxylate from the group comprising vinyl acetate, methyl acrylate and methacrylate, n- and isobutyl acrylate and methacrylate and dibutyl maleate, the percentages being based on the total amount of the monomers.
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公开(公告)号:AU4945385A
公开(公告)日:1986-05-15
申请号:AU4945385
申请日:1985-11-07
Applicant: BASF AG
Inventor: PENZEL ERICH , PRANGE WALTER , MELAN MICHAEL , WISTUBA ECKEHARDT , MUELLER ALFRED
IPC: C08L27/08 , C08F214/08 , C08F220/00 , C08F220/10 , C08F220/12 , C08L1/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L33/06 , C09D127/04 , C09D127/08 , C09D133/06 , C09D3/81
Abstract: Paints and renders contain, as binders, aqueous dispersions of copolymers which have a minimum film-forming temperature of from -15 DEG to 20 DEG C. and consist of (a) from 10 to 50% by weight of vinylidene chloride, up to half of which may be replaced with vinyl chloride, (b) from 44 to 88% by weight of esters of acrylic and/or methacrylic acid with alkanols of 1 to 18 carbon atoms and, if required, styrene, vinyl acetate, vinyl propionate or a mixture of these monomers and (c) from 2 to 6% by weight of alpha , beta -monoolefinically unsaturated mono- and/or dicarboxylic acids of 3 to 5 carbon atoms and/or their amides.
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公开(公告)号:AU7488181A
公开(公告)日:1982-03-11
申请号:AU7488181
申请日:1981-09-02
Applicant: BASF AG
Inventor: DISTLER DIETER , MELAN MICHAEL
IPC: C08L7/00 , C08F236/10 , C08K5/41 , C08K5/42 , C08L9/08 , C08L21/00 , C08L21/02 , C08L25/00 , C08L25/10 , C09D5/08 , C09D121/00 , C09D125/00 , C09D125/10 , C08F2/26 , C08F212/08 , C09D3/76 , C09D5/02
Abstract: Aqueous low-emulsifier dispersions of emulsion copolymers which contain, as copolymerized units, (a) from 35 to 55% by weight of butadiene, (b) from 35 to 60% by weight of styrene, (c) from 1 to 3% by weight of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 6 carbon atoms, (d) from 1 to 3% by weight of amides of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms, (e) from 1 to 4% by weight of N-methylolamides of alpha , beta -monoolefinically unsaturated monocarboxylic acids and/or dicarboxylic acids of 3 to 5 carbon atoms, or their alkyl ethers, and (f) from 1 to 3% by weight of acrylic acid and/or methacrylic acid monoesters of alkanediols of 2 to 6 carbon atoms, the emulsion containing, as emulsifier, from 0.1 to 0.8% by weight, based on emulsion copolymers, of fatty alcohol-sulfonates and/or alkylbenzenesulfonates, where alkyl is of 12 to 16 carbon atoms, are of particular value as binders for aqueous anti-corrosion paints.
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