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    13.
    发明专利
    未知

    公开(公告)号：DE59609156D1

    公开(公告)日：2002-06-06

    申请号：DE59609156

    申请日：1996-01-20

    Applicant: BASF AG

    Inventor： BALKENHOHL FRIEDHELM ,  DITRICH KLAUS ,  NUEBLING CHRISTOPH

    IPC: C12P13/02 ,  C12P41/00

    Abstract: A process for preparing optically active primary and secondary heteroatom-substituted amines from the corresponding racemates is characterised in that (a) a racemic heteroatom-substituted amine is enantioselectively acylated in the presence of a hydrolase with an ester whose acid component bear a fluorine, nitrogen, phosphorus, oxygen or sulphur atom next to the carbonyl carbon atom; (b) the mixture of optically active heteroatom-substituted amine and optically active acylated heteroatom-substituted amine is separated in order to produce an enantiomer of the heteroatom-substituted amine; (c) the other enantiomer of the heteroatom-substituted amine is optionally extracted from the acylated heteroatom-substituted amine by amide cleavage.

    14.
    发明专利
    未知

    公开(公告)号：DE59508928D1

    公开(公告)日：2001-02-01

    申请号：DE59508928

    申请日：1995-07-27

    Applicant: BASF AG

    Inventor： PLATH PETER ,  VON DEYN WOLFGANG ,  ENGEL STEFAN ,  KARDORFF UWE ,  NUEBLING CHRISTOPH ,  KOENIG HARTMANN ,  RANG HARALD ,  GERBER MATTHIAS ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO

    IPC: C07D275/04 ,  A01N43/80 ,  C07D275/06

    Abstract: PCT No. PCT/EP95/02977 Sec. 371 Date Feb. 3, 1997 Sec. 102(e) Date Feb. 3, 1997 PCT Filed Jul. 27, 1995 PCT Pub. No. WO96/05183 PCT Pub. Date Feb. 22, 1996Saccharin derivatives of the formula I I where the substituents have the following meanings: L and M are hydrogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, chlorine, cyano, methylsulfonyl, nitro or trifluoromethyl; Z is hydrogen, C1-C4-alkyl, C3-C8-cycloalkyl, C3-C6-alkenyl, C3-C5-alkynyl, C1-C4-acyl, benzyl or phenyl, the phenyl rings being unsubstituted or substituted by halogen or C1-C4-alkyl; R1 is cyclopropyl, 1-methylcyclopropyl, 1-methylthiocyclopropyl or tert-butyl; and agriculturally customary salts of the compounds I are described.

    15.
    发明专利
    未知

    公开(公告)号：AT198330T

    公开(公告)日：2001-01-15

    申请号：AT95929016

    申请日：1995-07-27

    Applicant: BASF AG

    Inventor： PLATH PETER ,  VON DEYN WOLFGANG ,  ENGEL STEFAN ,  KARDORFF UWE ,  NUEBLING CHRISTOPH ,  KOENIG HARTMANN ,  RANG HARALD ,  GERBER MATTHIAS ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO

    IPC: C07D275/04 ,  A01N43/80 ,  C07D275/06

    Abstract: PCT No. PCT/EP95/02977 Sec. 371 Date Feb. 3, 1997 Sec. 102(e) Date Feb. 3, 1997 PCT Filed Jul. 27, 1995 PCT Pub. No. WO96/05183 PCT Pub. Date Feb. 22, 1996Saccharin derivatives of the formula I I where the substituents have the following meanings: L and M are hydrogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio, chlorine, cyano, methylsulfonyl, nitro or trifluoromethyl; Z is hydrogen, C1-C4-alkyl, C3-C8-cycloalkyl, C3-C6-alkenyl, C3-C5-alkynyl, C1-C4-acyl, benzyl or phenyl, the phenyl rings being unsubstituted or substituted by halogen or C1-C4-alkyl; R1 is cyclopropyl, 1-methylcyclopropyl, 1-methylthiocyclopropyl or tert-butyl; and agriculturally customary salts of the compounds I are described.

    16.
    发明专利
    未知

    公开(公告)号：AT198189T

    公开(公告)日：2001-01-15

    申请号：AT96915021

    申请日：1996-05-07

    Applicant: BASF AG

    Inventor： NUEBLING CHRISTOPH ,  LADNER WOLFGANG

    IPC: C07C213/02 ,  C07C213/08 ,  C07C213/10 ,  C07C217/52 ,  C07C233/23 ,  C07C271/24 ,  C07C271/56

    Abstract: PCT No. PCT/EP96/01884 Sec. 371 Date Oct. 28, 1997 Sec. 102(e) Date Oct. 28, 1997 PCT Filed May 7, 1996 PCT Pub. No. WO96/35660 PCT Pub. Date Nov. 14, 1996A process for preparing enantiomerically pure cis-1-amino-2-hydroxyindane, which comprises a) converting racemic trans-1-aminoindan-2-ol with acids or acid derivatives of the general formula RCOX by conventional methods into amides of type A A b) adding seed crystals of one enantiomer to a super-saturated solution or melt of the racemic amide A, c) isolating the crystals which have separated out, and again supersaturating the remaining mother liquor or melt after dissolving racemic amide A, and adding seed crystals of the other enantiomer, leading to selective crystallization of the latter, d) converting the resulting enantiomerically pure trans amide by conventional methods into the enantiomerically pure cis-1-amino-2-hydroxyindane.

    20.
    发明专利
    未知

    公开(公告)号：BR9204546A

    公开(公告)日：1993-06-01

    申请号：BR9204546

    申请日：1992-11-25

    Applicant: BASF AG

    Inventor： DEYN WOLFGANG VON ,  THEOBALD HANS ,  NUEBLING CHRISTOPH ,  KARDORFF UWE ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  KAPPE THOMAS ,  GERBER MATTHIAS

    IPC: A01N43/42 ,  C07D215/56 ,  C07D409/12

    Abstract: Quinoline-3-carboxamides I in which the substituents have the following meaning: R is hydrogen, alkyl, alkenyl, alkynyl or cycloalkyl, where the abovementioned organic radicals can in each case be substituted; R is hydrogen, hydroxyl, alkoxy, alkenyloxy, dialkylamino, alkyl, alkenyl, alkynyl or cycloalkyl, where the abovementioned organic radicals can in each case be substituted; or R and R together are an alkylene chain having 4 to 7 members which can be interrupted by oxygen, sulphur or N-methyl; R -R are hydrogen, alkyl, alkoxy, haloalkyl, haloalkoxy, alkylthio, haloalkylthio, halogen, cyano or nitro; X is oxygen or sulphur; with the proviso that R is not hydrogen, C1-C3-alkyl, n-butyl, 3-methylbutyl, cyclohexyl, hexyl, heptyl, octyl, 2-chlorobenzyl, 3-(dimethylamino)propyl, 3-(diethylamino)propyl, 2-morpholinoethyl and 2-(3,4-dimethoxyphenyl)ethyl if R and R to R are hydrogen and X is oxygen, and R is not benzyl if R is methyl, R to R are hydrogen and X is oxygen, and R and R together are not morpholino if R to R are hydrogen and X is oxygen.

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