公开(公告)号：IN17CH2003A

公开(公告)日：2005-04-08

申请号：IN17CH2003

申请日：2003-01-03

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BASSLER PETER ,  BERG ANNE ,  RIEBER NORBERT ,  RUDOLF PETER

IPC: C07D20060101 ,  C07D301/12 ,  C07D301/32 ,  C07D303/04

Abstract: A process for the preparation of propylene oxide in which (i) propene is reacted with hydrogen peroxide in the presence of methanol to give propylene oxide, giving a mixture (Gi) comprising propylene oxide, methanol, water and unreacted hydrogen peroxide, (ii) a mixture (Gii) comprising methanol, water and hydrogen peroxide is separated off from the mixture (Gi), giving a mixture (Ga) comprising propylene oxide, and (iii) water is separated off from the mixture (Gii), giving a mixture (Giii) comprising methanol and methyl formate.

公开(公告)号：DE50105418D1

公开(公告)日：2005-03-31

申请号：DE50105418

申请日：2001-03-19

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  TELES HENRIQUE ,  RIEBER NORBERT ,  WALCH ANDREAS ,  BASSLER PETER ,  REHFINGER ALWIN ,  BERG ANNE ,  HARDER WOLFGANG

IPC: B01J8/02 ,  B01J29/90 ,  C07D301/12

Abstract: Continuous reaction of an organic compound with hydroperoxide using a catalyst comprises using at least two parallel reactors and a high stream flow. An independent claim is included for the apparatus used comprising at least two parallel isothermal fixed bed reactors, a separator(s) and an adiabatic fixed bed reactor(s).

公开(公告)号：DE50009495D1

公开(公告)日：2005-03-17

申请号：DE50009495

申请日：2000-07-31

Applicant: BASF AG

Inventor： TELES HENRIQUE ,  REHFINGER ALWIN ,  BASSLER PETER ,  RIEBER NORBERT ,  WENZEL ANNE ,  WALCH ANDREAS ,  HARDER WOLFGANG

IPC: C07B61/00 ,  C07D301/12 ,  C07D303/04

Abstract: In a process for reacting an organic compound with a hydroperoxide using at least one heterogeneous catalyst, both the pH and the temperate of the reaction medium are changed during the reaction

公开(公告)号：AT281442T

公开(公告)日：2004-11-15

申请号：AT01969340

申请日：2001-07-05

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BASSLER PETER ,  BERG ANNE ,  RIEBER NORBERT ,  RUDOLF PETER

IPC: C07D20060101 ,  C07D301/12 ,  C07D301/32 ,  C07D303/04

Abstract: A process for the preparation of propylene oxide in which (i) propene is reacted with hydrogen peroxide in the presence of methanol to give propylene oxide, giving a mixture (Gi) comprising propylene oxide, methanol, water and unreacted hydrogen peroxide, (ii) a mixture (Gii) comprising methanol, water and hydrogen peroxide is separated off from the mixture (Gi), giving a mixture (Ga) comprising propylene oxide, and (iii) water is separated off from the mixture (Gii), giving a mixture (Giii) comprising methanol and methyl formate.

公开(公告)号：CZ294316B6

公开(公告)日：2004-11-10

申请号：CZ20003237

申请日：1999-02-23

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: In the present invention, there is disclosed a hydrogenation process of alpha-, omega-dinitriles in the presence of a catalyst, said process being characterized in that as a catalyst, there is used a mixture containing the following components: (a) iron or iron-based compound or mixtures thereof, (b) 0.001 to 0.3 percent by weight of a promoter based on 2, 3, 4 or 5 elements being selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium,(c) from 0 to 0.3 percent by weight based on the component (a) weight of a compound based on an alkali and/or alkaline earth metal, and also (d) from 0.001 to 1 percent by weight based on the component (a) weight of manganese. The above-specified mixture for the catalysis is obtained by reduction and optional passivation of magnetite, or by precipitation of substances that provide on carrier materials or without their presence the above components (a), (b), (d) and optionally (c), or by impregnating a carrier with a solution of the components (a), (b), (d) and optionally (c), or spraying the components (a), (b), (d) and optionally (c) to a carrier.

公开(公告)号：AT275137T

公开(公告)日：2004-09-15

申请号：AT01982272

申请日：2001-09-11

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  BERG ANNE ,  HARDER WOLFGANG ,  RUDOLF PETER ,  REHFINGER ALWIN ,  BASSLER PETER ,  RIEBER NORBERT

IPC: B01J29/89 ,  B01J29/90 ,  C07D301/12

Abstract: A process for regenerating a zeolite catalyst comprises thermal treatment of the catalyst at above 120° C. in the presence of a gas stream comprising hydrogen.

公开(公告)号：MY118008A

公开(公告)日：2004-08-30

申请号：MYPI9704168

申请日：1997-09-09

Applicant: BASF AG

Inventor： REHFINGER ALWIN ,  VOIT GUIDO ,  RUST HARALD ,  LUYKEN HERMANN ,  MERGER MARTIN ,  BABLER PETER ,  FISCHER ROLF

IPC: C07C209/86 ,  C07C211/12 ,  C07C211/36

Abstract: A PROCESS FOR SEPARATING 2-AMINOMETHYLCYCLOPENTYLAMINE FROM A MIXTURE CONSISTING OF HEXAMETHYLENEDIAMINE AND 2-AMINOMETHYLCYCLOPENTYLAMINE BY DISTILLING THE MIXTURE AT A PRESSURE FROM 1 TO 300 X 102 PA(L TO 300 MBAR).

公开(公告)号：DE59909485D1

公开(公告)日：2004-06-17

申请号：DE59909485

申请日：1999-08-17

Applicant: BASF AG

Inventor： FISCHER ROLF ,  BASSLER PETER ,  LUYKEN HERMANN ,  OHLBACH FRANK ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  ANSMANN ANDREAS ,  REHFINGER ALWIN ,  VOIT GUIDO

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/86 ,  C07C211/12

Abstract: A process for catalytic hydrogenation of adiponitrile to hexamethylenediamine at elevated temperature and elevated pressure in the presence of catalysts based on elemental iron as catalytically active component and ammonia as solvent comprisesa) hydrogenating adiponitrile at from 70 to 220° C. and from 100 to 400 bar in the presence of catalysts based on elemental iron as catalytically active component and ammonia as solvent to obtain a mixture comprising adiponitrile,6-aminocapronitrile, hexamethylenediamine and high boilers until the sum total of the 6-aminocapronitrile concentration and the adiponitrile concentration is within the range from 1 to 50% by weight, based on the ammonia-free hydrogenation mixture,b) removing ammonia from the hydrogenation effluent,c) removing hexamethylenediamine from the remaining mixture,d) separating 6-aminocapronitrile and adiponitrile from high boilers individually or together, ande) returning 6-aminocapronitrile, adiponitrile or mixtures thereof into step a).

公开(公告)号：ZA200300106B

公开(公告)日：2004-01-21

申请号：ZA200300106

申请日：2003-01-06

Applicant: BASF AG

Inventor： BASSLER PETER ,  REHFINGER ALWIN ,  REIBER NORBERT ,  RUDOLF PETER ,  HENRIQUE TELES JOAQUIM ,  BERG ANNE

IPC: C07D20060101 ,  C07D301/12 ,  C07D301/32 ,  C07D303/04 ,  C07D

Abstract: A process for the preparation of propylene oxide in which (i) propene is reacted with hydrogen peroxide in the presence of methanol to give propylene oxide, giving a mixture (Gi) comprising propylene oxide, methanol, water and unreacted hydrogen peroxide, (ii) a mixture (Gii) comprising methanol, water and hydrogen peroxide is separated off from the mixture (Gi), giving a mixture (Ga) comprising propylene oxide, and (iii) water is separated off from the mixture (Gii), giving a mixture (Giii) comprising methanol and methyl formate.

公开(公告)号：DE59907216D1

公开(公告)日：2003-11-06

申请号：DE59907216

申请日：1999-07-02

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  OHLBACH FRANK ,  ANSMANN ANDREAS ,  BASSLER PETER ,  FISCHER ROLF ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  REHFINGER ALWIN ,  VOIT GUIDO ,  ACHHAMMER GUENTHER

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C209/86 ,  C07C211/12 ,  C07C253/30 ,  C07C253/34 ,  C07C255/24

Abstract: The invention relates to a method for simultaneous production of 6-aminocapronitrile and hexamethylenediamine from adipodinitrile, comprising the following steps: a) hydrogenating adipodinitrile in the presence of a catalyst containing an element of the VIII subgroup thereby obtaining a mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and high boilers; b) distillative separation of hexamethylenediamine from the mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and high boilers or c1) distillative separating 6-aminocapronitrile and subsequently d1) distillative separation of adipodinitrile or c2) simultaneous distillative separation of 6-aminocapronitrile and adipodinitrile into separate fractions. The invention is characterized in that temperatures in the bottoms of the column in steps d1) or c2) are under 185 DEG C. The adipodinitrile thus obtained contains less impurities than for instance 1-amino-2-cyanocyclopentenes.