13.
    发明专利
    未知

    公开(公告)号:AT281442T

    公开(公告)日:2004-11-15

    申请号:AT01969340

    申请日:2001-07-05

    Applicant: BASF AG

    Abstract: A process for the preparation of propylene oxide in which (i) propene is reacted with hydrogen peroxide in the presence of methanol to give propylene oxide, giving a mixture (Gi) comprising propylene oxide, methanol, water and unreacted hydrogen peroxide, (ii) a mixture (Gii) comprising methanol, water and hydrogen peroxide is separated off from the mixture (Gi), giving a mixture (Ga) comprising propylene oxide, and (iii) water is separated off from the mixture (Gii), giving a mixture (Giii) comprising methanol and methyl formate.

    PROCESS FOR THE PREPARATION OF PROPYLENE OXIDE

    公开(公告)号:CA2453988A1

    公开(公告)日:2003-01-30

    申请号:CA2453988

    申请日:2002-07-18

    Applicant: BASF AG

    Abstract: The invention relates to a method for producing propylene oxide, comprising at least the following steps: (a) propene is reacted with a hydroperoxide in a solvent in the presence of a zeolite catalyst, in order to obtain a mixture (G0), said mixture (G0) containing propylene oxide, solvent, non-reacted propene, non-reacted hydroperoxide and oxygen; (b) the propylene oxide is separated from the mixture (G0) in such a way that a mixture (G1) is obtaine d which comprises non-reacted propene and oxygen; (c) the mixture (G1) is brought into contact with a liquid medium containing at least solvent, in order to obtain the mixtures (G2) and (G3), said mixture (G3) containing a part of the non-reacted propene and oxygen, and said mixture (G2) containing the solvent and the rest of the propene, the separated mixture (G3) of non- reacted propene and oxygen having a ratio of oxygen to propene which renders the mixture (G3) non-inflammable, and the mixture (G2) supplying at least on e reaction between the propene and the hydroperoxide.

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