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公开(公告)号:CA1246095A
公开(公告)日:1988-12-06
申请号:CA469131
申请日:1984-12-03
Applicant: BASF AG
Inventor: MERGER FRANZ , SCHWARZ WOLFGANG
IPC: C07B61/00 , B01J31/00 , B01J31/04 , C07C67/00 , C07C231/00 , C07C231/10 , C07C233/09 , C11C3/00 , C07C103/133 , C07C103/19
Abstract: .alpha.-Substituted acrylamides of the general formula I (I), where R1 is a straight-chain, branched or cyclic alkyl radical of not more than 15 carbon atoms which can be unsubstituted or further substituted, are prepared by a process in which the corresponding .alpha.-substituted acrolein oximes are heated at from 40 to 250.degree.C in the presence of a copper (II) carboxylate. The acrylamides of formula I that are so-obtained are useful intermediates for the preparation of modifiable polymers, for example for dispersions and surface coatings.
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公开(公告)号:CA1240704A
公开(公告)日:1988-08-16
申请号:CA469130
申请日:1984-12-03
Applicant: BASF AG
Inventor: MERGER FRANZ , SCHWARZ WOLFGANG
IPC: C07B61/00 , B01J31/00 , B01J31/04 , C07C67/00 , C07C231/00 , C07C231/10 , C07C233/09 , C07C103/133 , C07C103/19
Abstract: ?-Substituted acrylamides of the general formula I (I), where R1 is a straight-chain, branched or cyclic alkyl radical of not more than 15 carbon atoms which can be unsubstituted or further substituted, are prepared by a process in which the corresponding ?-substituted atrolein oximes are heated at from 40 to 250.degree.C in the presence of a copper(II) carboxylate and of an unsubstituted or substituted acrylonitrile as cocatalyst.
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公开(公告)号:DE3632010A1
公开(公告)日:1988-04-07
申请号:DE3632010
申请日:1986-09-20
Applicant: BASF AG
Inventor: MERGER FRANZ , SCHWARZ WOLFGANG
IPC: C07C263/04 , C07C263/06 , C07C265/04 , C07C265/12 , C07C265/14 , C07C269/06 , C07C271/02 , C07C271/04 , C07C271/06 , C07C271/20 , C08G18/70 , C08G18/73 , C08G18/77 , C07C119/042 , C07C118/00 , C07C119/045 , C07C119/048 , C07C125/03 , C07C125/073
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公开(公告)号:DK151814B
公开(公告)日:1988-01-04
申请号:DK369575
申请日:1975-08-15
Applicant: BASF AG
Inventor: HERRLE KARL , DENZINGER WALTER , SEELERT KURT , SCHWARZ WOLFGANG
IPC: A61K31/18 , A61K31/785 , A61K31/79 , A61K33/18 , C08F8/00 , C08F8/20 , C08F126/10 , C08F8/22
Abstract: Polyvinylpyrrolidone-iodine, manufactured by reaction of iodine and a polyvinylpyrrolidone obtained by polymerization in an anhydrous organic solvent in the presence of a source of free radicals and optionally in the presence of a heavy metal of atomic number from 23 to 29, in the form of a complex compound or of a salt with an organic acid, as a co-activator, followed by steam distillation of this polyvinylpyrrolidone, if appropriate. The PVP-iodine of the invention is very stable and can be used as a disinfectant.
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公开(公告)号:CA1081394A
公开(公告)日:1980-07-08
申请号:CA334554
申请日:1979-08-28
Applicant: BASF AG
Inventor: HERRLE KARL , DENZINGER WALTER , SEELERT KURT , SCHWARZ WOLFGANG
IPC: C08F126/08
Abstract: A process for the manufacture of polyvinylpyrrolidoneiodine from polyvinyl pyrrolidone and iodine which comprises: - the free radical polymerization of vinylpyrrolidone in a anhydrous organic solvent selected from the group consisting of aromatic hydrocarbons, lower aliphatic monohydric alcohols of 1 to 4 carbon atoms, in the presence of free radicals supplied by an organic per-compound in an amount of about 0.5 to 5% by weight on the basis of the weight of the vinylpyrrolidone; - converting the obtained polyvinylpyrrolidone, after completion of polymerization and before drying, into an aqueous solution by adding water and distilling off the organic solvent, the aqueous solution then being subjected to treatment with steam and reacting the aqueous polyvinylpyrrolidone solution with iodine.
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公开(公告)号:CA1079443A
公开(公告)日:1980-06-10
申请号:CA233153
申请日:1975-08-08
Applicant: BASF AG
Inventor: HERRLE KARL , DENZINGER WALTER , SEELERT KURT , SCHWARZ WOLFGANG
IPC: A61K31/18 , A61K31/785 , A61K31/79 , A61K33/18 , C08F8/00 , C08F8/20 , C08F126/10 , C08F8/22
Abstract: A process for the manufacture of polyvinylpyrrolidoneiodine from polyvinyl pyrrolidone and iodine which comprises: -the free radical polymerization of vinylpyrrolidone in a anhydrous organic solvent selected from the group consisting of aromatic hydrocarbons, lower aliphatic monohydric alcohols of 1 to 4 carbon atoms, in the presence of free radicals supplied by an organic per-compound in an amount of about 0.5 to 5% by weight on the basis of the weight of the vinylpyrrolidone; -mixing the resulting polyvinylpyrrolidone in the form of a powder having a K value of from 10 to 50 and a water content of from 0.5 to 11% by weight with iodine in an amount of about 5 to 25% based on the total weight of the polyvinylpyrrolidoneiodine, at about room temperature up to about 50.degree.C and, -heating the resulting mixture for about 5 to 20 hours at about 70 to 100.degree.C.
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公开(公告)号:DE3776244D1
公开(公告)日:1992-03-05
申请号:DE3776244
申请日:1987-09-18
Applicant: BASF AG
Inventor: MERGER FRANZ , SCHWARZ WOLFGANG
IPC: C07C263/04 , C07C263/06 , C07C265/04 , C07C265/12 , C07C265/14 , C07C269/06 , C07C271/02 , C07C271/04 , C07C271/06 , C07C271/20 , C08G18/70 , C08G18/73 , C08G18/77
Abstract: 2-(alkoxymethyl) -pentane-1,5-diisocyanate of formula (I) are new: in which R = straight or branched 1-20C alkyl, straight or branched 2-20C alkylene, straight or branched 3-20C oxaalkyl, opt. substd. 5-12C cycloalkyl or opt. substd. 7-20C aralkyl gp. and X1 and X2 = NCO. Also specifically claimed is 2-(2-alkoxymethyl)-pentane -1,5-diurethane of formula (I) in which X1 and X2 (same or different) = -NH-COOR in which R = straight or branched 1-20C alkyl or 3-15C cycloalkyl; and (Ib) 2-(alkoxymethyl)-pentane-1,5-dicarbamic acid chlorides of formula (I) in which X1 and X2 = -COCl.
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公开(公告)号:DE3677833D1
公开(公告)日:1991-04-11
申请号:DE3677833
申请日:1986-06-27
Applicant: BASF AG
Inventor: MERGER FRANZ , SCHWARZ WOLFGANG
IPC: C07C265/04 , C07C67/00 , C07C241/00 , C07C263/00 , C07C263/04 , C07C263/06 , C07C265/02 , C07C269/04 , C07C271/06 , C07C271/16
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公开(公告)号:DE3061514D1
公开(公告)日:1983-02-03
申请号:DE3061514
申请日:1980-10-10
Applicant: BASF AG
Inventor: DENZINGER WALTER , HARTMANN HEINRICH , SCHWARZ WOLFGANG
Abstract: A process for the preparation of PVP-iodine having an iodine:iodide ratio of about 2:1 and a partition coefficient of 180-250, by reacting PVP with elementary iodine in the presence of formic acid, oxalic acid or an ammonium salt or amide of carbonic acid, formic acid or oxalic acid, in aqueous solution.
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公开(公告)号:AU8374875A
公开(公告)日:1977-02-10
申请号:AU8374875
申请日:1975-08-07
Applicant: BASF AG
Inventor: HERRLE KARL , DENZINGER WALTER , SEELERT KURT , SCHWARZ WOLFGANG
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