4.
    发明专利
    未知

    公开(公告)号:DE3688912D1

    公开(公告)日:1993-09-23

    申请号:DE3688912

    申请日:1986-06-27

    Applicant: BASF AG

    Abstract: Prodn. of N-omega-hydroxyalkyl and (poly)oxaalkyl carbamates HO-A-NH-CO2R' (I) comprises reacting an omega-aminoalcohol or amino-(poly)oxaalcohol HO-A-NH2 (II) with urea and an alcohol or ether alcohol R'-OH (III) at 170-250 deg.C with removal of ammonia. A = 2-12C alkylene, oxa-alkylene or polyoxa-alkylene; R' = 1-6C alkyl opt. contg. an O atom. The reaction is pref. carried out at 180-235 deg.C; and the ratio (II):urea:(III) is pref. 1:1-1.5:5-50. The reaction can be carried out in the presence of a metal ion catalyst, e.g. a chloride, bromide, sulphate etc. of Fe, Co, Ni, Zn, Sn, Ti etc.

    5.
    发明专利
    未知

    公开(公告)号:DK151814C

    公开(公告)日:1988-06-06

    申请号:DK369575

    申请日:1975-08-15

    Applicant: BASF AG

    Abstract: Polyvinylpyrrolidone-iodine, manufactured by reaction of iodine and a polyvinylpyrrolidone obtained by polymerization in an anhydrous organic solvent in the presence of a source of free radicals and optionally in the presence of a heavy metal of atomic number from 23 to 29, in the form of a complex compound or of a salt with an organic acid, as a co-activator, followed by steam distillation of this polyvinylpyrrolidone, if appropriate. The PVP-iodine of the invention is very stable and can be used as a disinfectant.

    PREPARATION OF POLYVINYLPYRROLIDONE-IODINE

    公开(公告)号:CA1136342A

    公开(公告)日:1982-11-23

    申请号:CA325383

    申请日:1979-04-11

    Applicant: BASF AG

    Abstract: O.Z. 0050/033151 A process for the preparation of PVP-iodine by reacting polyvinylpyrrolidone powder with elementary iodine at from 70 to 100.degree.C. The reaction is carried out in the presence of formic acid, oxalic acid or an ammonium salt or amide of carbonic acid, formic acid or oxalic acid. The process avoids the disadvantage of long periods of heating, which can result in degradation of the polyvinylpyrrolidone, and is particularly suitable for the preparation of an stable PVP-iodine using a low molecular weight polyvinylpyrrolidone.

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