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公开(公告)号：DE2832405A1
公开(公告)日：1980-02-14
申请号：DE2832405
申请日：1978-07-24
Applicant: BASF AG
IPC: C07C47/127 , B01J23/00 , B01J27/00 , C07B61/00 , C07C45/00 , C07C45/29 , C07C45/38 , C07C67/00 , C07C47/12 , C07C45/16
Abstract: A process for the preparation of glyoxal by vapor phase oxidation of ethylene glycol with oxygen over a copper-containing oxidation catalyst at an elevated temperature and in the presence of a phosphorus compound which is volatile under the reaction conditions, the amount of phosphorus (calculated as P) being from 1 to 100 ppm, based on the weight of ethylene glycol.
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公开(公告)号：DE2442911A1
公开(公告)日：1976-03-25
申请号：DE2442911
申请日：1974-09-07
Applicant: BASF AG
Inventor： ENGELBACH HEINZ DR , SPRAGUE MICHAEL JOLYON DR
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公开(公告)号：DK0901982T3
公开(公告)日：2002-03-04
申请号：DK98117210
申请日：1998-09-09
Applicant: BASF AG
Inventor： KUMBERGER OTTO DR , SPRAGUE MICHAEL JOLYON DR , HOFSTADT OTTO
Abstract: The catalyst is in tablet form having a diameter of 0.8-5 mm and a height of 0.8-5 mm. The catalyst is prepared by: (a) precipitating a solution of zinc and aluminium salts (Zn:Al ratio is 3-1:1-3) with and alkali carbonate or hydroxide solution at a pH of 5-12 and a temperature of 20-100 degrees C; (b) removing and washing the precipitate to remove alkali ions; (c) drying the precipitate; (d) calcining the precipitate at 250-800 degrees C to a mixed oxide; (e) dispersing the mixed oxide in an acid solution of copper and zinc salts (Cu:Zn ratio is 1-20:5-1); (f) precipitating the dispersion with an alkali carbonate or hydroxide solution at a pH of 6-9 and a temperature of 20-100 degrees C; and (g) repeating steps (b) to (d). The solutions in steps (a) and/or (e) additionally contain oxides of platinum group metals, groups 5, 11 and the lanthanides.
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公开(公告)号：DE19739773A1
公开(公告)日：1999-03-11
申请号：DE19739773
申请日：1997-09-10
Applicant: BASF AG
Inventor： KUMBERGER OTTO DR , SPRAGUE MICHAEL JOLYON DR , HOFSTADT OTTO
Abstract: The catalyst is in tablet form having a diameter of 0.8-5 mm and a height of 0.8-5 mm. The catalyst is prepared by: (a) precipitating a solution of zinc and aluminium salts (Zn:Al ratio is 3-1:1-3) with and alkali carbonate or hydroxide solution at a pH of 5-12 and a temperature of 20-100 degrees C; (b) removing and washing the precipitate to remove alkali ions; (c) drying the precipitate; (d) calcining the precipitate at 250-800 degrees C to a mixed oxide; (e) dispersing the mixed oxide in an acid solution of copper and zinc salts (Cu:Zn ratio is 1-20:5-1); (f) precipitating the dispersion with an alkali carbonate or hydroxide solution at a pH of 6-9 and a temperature of 20-100 degrees C; and (g) repeating steps (b) to (d). The solutions in steps (a) and/or (e) additionally contain oxides of platinum group metals, groups 5, 11 and the lanthanides.
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公开(公告)号：DE3819437A1
公开(公告)日：1989-12-14
申请号：DE3819437
申请日：1988-06-08
Applicant: BASF AG
Inventor： AMBACH EBERHARD DR , SPRAGUE MICHAEL JOLYON DR , STEIGLEITER WERNER , MROSS WOLF DIETER DR , GRUENDLER KARL-HEINZ DR , IRGANG MATTHIAS DR
Abstract: The application relates to the preparation of a sulphur-free iron-oxide- and chromium-oxide-containing high temperature conversion catalyst, an iron oxide being used which is prepared from iron carbonyl and which has a mean grain size below 10 mu m and a specific surface area of more than 10 m /g. The chromium oxide component is applied to the iron oxide by precipitation. The chromium component used is CrO3 and is precipitated as insoluble chromium(III) compounds by reducing agents.
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Patent Agency Ranking16.发明专利
公开(公告)号：DE2962372D1
公开(公告)日：1982-05-06
申请号：DE2962372
申请日：1979-03-20
Applicant: BASF AG
Inventor： ENGELBACH HEINZ DR , HOFFMANN HARRY , PALM PETER , SOMMER KARL DR , SPRAGUE MICHAEL JOLYON DR
IPC: C07C50/16 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/847 , B01J27/08 , B01J27/232 , B01J37/02 , C07C45/00 , C07C46/02 , C07C50/18 , C07C67/00
Abstract: Novel coated catalysts and a process for their preparation by atomizing a mixture of water and a vanadium-V compound, with or without other metal compounds, and applying this mixture to carrier particles which are themselves in motion, drying the coating and subjecting the catalyst particles, which are themselves in motion, to repeated brief treatment with a flame or plasma, followed by rapid cooling, defined temperatures and rates of coating being employed. The catalysts may be used with advantage for the preparation of anthraquinones by oxidation of indans.
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公开(公告)号：DE2135421A1
公开(公告)日：1973-01-25
申请号：DE2135421
申请日：1971-07-15
Applicant: BASF AG
Inventor： WISTUBA HERMANN DR , SPRAGUE MICHAEL JOLYON DR , ENGELBACH HEINZ DR , ARMBRUST HERBERT , STURM HANS-JUERGEN DR
Abstract: Production of anthraquinone by catalytic oxidation of indans with oxygen in the presence of a vanadium (V) compound with one or more than one compound of thallium and antimony. Anthraquinone which can be prepared by the process according to this invention is a valuable starting material for the production of dyes and pesticides.
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公开(公告)号：MY137707A
公开(公告)日：2009-02-27
申请号：MYPI20015608
申请日：2001-12-10
Applicant: BASF AG
Inventor： FISCHER ROLF-HARTMUTH DR , WECK ALEXANDER , STEIN FRANK DR , PINKOS ROLF DR , HESSE MICHAEL DR , SPRAGUE MICHAEL JOLYON DR , SCH MARKUS R XD DR , BORCHERT HOLGER DR , SCHLITTER STEPHAN DR , RAHN RALF-THOMAS DR
IPC: B01J23/72 , B01J23/80 , C07C27/06 , C07D307/08
Abstract: UNSUBSTITUTED OR ALKYL-SUBSTITUTED THF IS OBTAINED BY CATALYTIC HYDROGENATION IN THE GAS PHASE OF C4-DICARBOXYLIC ACIDS AND/OR THEIR DERIVATIVES USING A CATALYST COMPRISING 20BY WEIGHT, PREFERABLY >30BY WEIGHT IN PARTICULARLY FROM 35 TO 90BY WEIGHT, OF AN OXIDIC SUPPORT HAVING ACID CENTERS, AT A HOT SPOT TEMPERATURE OF FROM 240 TO 310°C, PREFERABLY FROM 240 TO 280°C, AND A WHSV OVER THE CATALYST OF FROM 0.01 TO 1.0, PREFERABLY FROM0.02 TO 1, IN PARTICULARLY FROM 0.05 TO 0.5, kg OF STARTING MATERIAL/L OF CATALYST x HOUR.
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公开(公告)号：DE3869033D1
公开(公告)日：1992-04-16
申请号：DE3869033
申请日：1988-09-22
Applicant: BASF AG
Inventor： BECKER HANS-JUERGEN DR , GEIERHAAS HERBERT DR , IRGANG MATTHIAS DR , SPRAGUE MICHAEL JOLYON DR
Abstract: A zine oxide contg desulphurisation material is claimed, contg 20-80 wt% high surface-area Zn0 and 20-80 wt% basic zinc carbonate, mixed with water to form, dried and calcined. The surface area of the zinc oxide is min 10 m2/g, pref over 30 m2/g; technical grade zinc carbonate is used, of formula 5Zno.2C02.3H20 The oxide and carbonate are blended with water (10-60 wt%, pref 20-50%, taken as proportion of total content), blending time 1-10h, usually 1-5h. The mixt is formed, and dried, and calcined.
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公开(公告)号：DE3837308A1
公开(公告)日：1990-05-10
申请号：DE3837308
申请日：1988-11-03
Applicant: BASF AG
Inventor： WANJEK HERBERT DR , WITTE CLAUS DR , SPRAGUE MICHAEL JOLYON DR , IRGANG MATTHIAS DR , HOELDERICH WOLFGANG DR , MROSS WOLF DIETER DR
Abstract: Copper-containing catalysts for low-temperature conversion at temperatures of from 150 to 300 DEG C and at from 10 to 40 bar which additionally contain aluminium, and zinc, if desired in the form of the compounds or oxides, and are prepared by joint precipitation, the copper-containing catalysts containing potassium and having a BET surface area matched to the potassium content, the potassium content being set to from 0.1 to 3.0% by weight at a BET surface area of from 30 to 160 m /g, and their use for the production of hydrogen and carbon dioxide from carbon monoxide and water.
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