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公开(公告)号:HU0500331A2
公开(公告)日:2005-06-28
申请号:HU0500331
申请日:2002-10-17
Applicant: BASF AG
Inventor: ROHDE THORSTEN , STAMM ARMIN , HENKELMANN JOCHEM
IPC: C07C263/10 , C07C265/08 , C07C265/10 , C07C265/12 , C07C265/14
Abstract: In a process for preparing isocyanates by reacting the corresponding primary amines with phosgene in an inert solvent, use is made of from 0.01 to 50 mol % of a sulfoxide, a sulfone or a mixture thereof, based on the total amount of primary amine and isocyanate formed in the reaction solution.
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公开(公告)号:HU0402128A2
公开(公告)日:2005-04-28
申请号:HU0402128
申请日:2002-10-17
Applicant: BASF AG
Inventor: ROHDE THORSTEN , STAMM ARMIN , HENKELMANN JOACHEM
IPC: C07B61/00 , C07C263/10 , C07C265/10
Abstract: In a process for preparing isocyanates by reacting the corresponding primary amines with phosgene in an inert solvent, use is made of from 0.01 to 50 mol % of a phosphine oxide, based on the total amount of primary amine and isocyanate formed in the reaction solution.
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公开(公告)号:DE50009431D1
公开(公告)日:2005-03-10
申请号:DE50009431
申请日:2000-08-31
Applicant: BASF AG
Inventor: BUSCH RALPH , KNEUPER HEINZ-JOSEF , WEBER THEODOR , MUELLER WINFRIED , STAMM ARMIN , HENKELMANN JOCHEM
Abstract: Process for the purification of carbonyl chlorides which have been prepared by reacting carboxylic acids with phosgene or thionyl chloride in the presence of a catalyst adduct, in which the carbonyl chlorides are treated with a hydrohalide of carboxamides of the formula (I)in which R is hydrogen or C1- to C3-alkyl; R and R independently of one another are C1- to C4-alkyl, or R and R together are a C4- or C5-alkylene chain, and the carbonyl chloride purified in this way is isolated by separation off from the carboxamide hydrohalide phase.
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公开(公告)号:CZ20040418A3
公开(公告)日:2004-06-16
申请号:CZ20040418
申请日:2002-10-17
Applicant: BASF AG
Inventor: ROHDE THORSTEN , STAMM ARMIN , HENKELMANN JOCHEM
IPC: C07C263/10 , C07C265/08 , C07C265/10 , C07C265/12 , C07C265/14 , C07C265/04
CPC classification number: C07C263/10 , C07C2601/14 , C07C265/14 , C07C265/10 , C07C265/08 , C07C265/12
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公开(公告)号:CZ20040410A3
公开(公告)日:2004-06-16
申请号:CZ20040410
申请日:2002-10-17
Applicant: BASF AG
Inventor: ROHDE THORSTEN , STAMM ARMIN , HENKELMANN JOCHEM
IPC: C07C263/10 , C07C265/08 , C07C265/10 , C07C265/12 , C07C265/14
CPC classification number: C07C263/10 , C07C2601/14 , C07C265/14 , C07C265/08 , C07C265/10 , C07C265/12
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公开(公告)号:ES2205829T3
公开(公告)日:2004-05-01
申请号:ES99925022
申请日:1999-05-21
Applicant: BASF AG
Inventor: WEYER HANS-JURGEN , STAMM ARMIN , WEBER THEODOR , HENKELMANN JOCHEM
Abstract: The present invention relates to a process for preparing alkyl, alkenyl and alkynyl chlorides from alcohols by reaction with a chlorinating agent in the presence of a catalyst, wherein the catalyst is a urea compound.
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公开(公告)号:HU0301077A2
公开(公告)日:2003-08-28
申请号:HU0301077
申请日:2001-02-28
Applicant: BASF AG
Inventor: BUSCH RALPH , HENKELMANN JOCHEM , KNEUPER HEINZ-JOSEF , STAMM ARMIN , WEBER THEODOR
Abstract: The invention relates to a method for producing chlorocarboxylic acid chlorides of formula (I), wherein R and R , independently from one another, mean a hydrogen atom, an organic radical containing carbon, a halogen, a nitro or cyano group and Y means an alkylene chain having 1 to 10 carbon atoms in the chain which is unsubstituted or is substituted by organic radicals that contain carbon, by halogen, nitro and/or cyano groups, whereby the alkylene chain can be interrupted by an ether-, thioether-, tertiary amino- or keto group, whereby the organic radicals of Y and/or R and/or R can be connected to one another and thereby form a non-aromatic system, whereby said radicals contain carbon, by converting a lactone of formula (II), wherein R , R and Y have the aforementioned meanings, using a hydrogen chloride and phosgene in the presence of a catalyst. Hydrogen chloride is added before and/or while phosgene is added. The hydrogen chloride is only introduced at a temperature of at least 60 DEG C. A pyridine compound is used as the catalyst.
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公开(公告)号:AT241580T
公开(公告)日:2003-06-15
申请号:AT99911747
申请日:1999-03-08
Applicant: BASF AG
Inventor: STAMM ARMIN , HENKELMANN JOCHEM , WEYER HANS-JUERGEN
Abstract: The invention relates to a continuous method for producing propargyl chloride by reacting propargyl alcohol with a chlorinating agent in the presence of a catalyst. According to the invention, the chlorinating agent, propargyl alcohol and 0.1 to 10 mol.% of the catalyst with regard to the amount of propargyl alcohol is continuously dosed in a reaction zone and is reacted at a temperature ranging from 40 to 70 DEG C.
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公开(公告)号:HU0203482A2
公开(公告)日:2003-02-28
申请号:HU0203482
申请日:2000-11-27
Applicant: BASF AG
Inventor: GOETZ NORBERT DR , GOETZ ROLAND , HENKELMANN JOCHEM , KNEUPER HEINZ-JOSEF , STAMM ARMIN , WOLF BERND DR
Abstract: The invention relates to a method for producing o-choromethyl benzenecarbonyl chlorides of formula (I), wherein R -R can be the same or different and stand for hydrogen, C1-C4-alkyl, halogen or trifluoromnethyl, by converting benzocondensed lactones of formula (II), wherein R -R have the aforementioned meaning, with gaseous or liquid phosgene and the dimers or trimers thereof. The inventive method is characterized in that the conversion is carried out in the presence of catalytical amounts of a Lewis acid and catalytical amounts of a phosgenation catalyst
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公开(公告)号:ES2174527T3
公开(公告)日:2002-11-01
申请号:ES98963492
申请日:1998-11-21
Applicant: BASF AG
Inventor: WEYER HANS-JURGEN , STAMM ARMIN , WEBER THEODOR , HENKELMANN JOCHEM
Abstract: The present invention provides process for the preparation of chlorocarbonyl chlorides of the formula IwhereR1 is for example hydrogen or C1- to C20-alkyl andY is for example a saturated or mono- or polyolefinically unsaturated C2-C8-alkylene chain,by reacting lactones with a chlorinating agent in the presence of a urea compound.
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