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公开(公告)号：WO0119767A3
公开(公告)日：2002-02-14
申请号：PCT/EP0008514
申请日：2000-08-31
Applicant: BASF AG , BUSCH RALPH , KNEUPER HEINZ JOSEF , WEBER THEODOR , MUELLER WINFRIED , STAMM ARMIN , HENKELMANN JOCHEM
Inventor： BUSCH RALPH , KNEUPER HEINZ-JOSEF , WEBER THEODOR , MUELLER WINFRIED , STAMM ARMIN , HENKELMANN JOCHEM
Abstract: The invention relates to a method for purifying acid chlorides which have been produced by converting carboxylic acids with carbon oxychloride or thionyl chloride in the presence of a catalyst adduct. The acid chlorides are treated with a hydro halide of carboxylic acid amides of general formula (I), wherein R stands for hydrogen or C1- to C3-alkyl; R and R , independently from one another, mean C1- to C4-alkyl or R and R together mean a C4- or C5-alkylene chain. The thus purified acid chloride is isolated by separation said acid chloride from the carboxylic acid amide hydro halide-phase.
Abstract translation: 一种用于已制备由羧酸与光气或亚硫酰氯在催化剂的加合物的存在下，其中具有通式（I）的羧酰胺的氢卤化物的羰基氯化物，其中R <1>是氢或反应羰基氯化物的提纯方法 C1-C3烷基; [R <2>和R <3>独立地是C1-C4烷基或R <2>和R <3>一起表示C 4或C 5亚烷基链，从羧酰胺氢卤化物处理，这样纯化的羧酸酰基氯的分离 相隔离。
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公开(公告)号：WO0142183A2
公开(公告)日：2001-06-14
申请号：PCT/EP0011814
申请日：2000-11-27
Applicant: BASF AG , STAMM ARMIN , GOETZ ROLAND , GOETZ NORBERT , HENKELMANN JOCHEM , KNEUPER HEINZ JOSEF , WOLF BERND
Inventor： STAMM ARMIN , GOETZ ROLAND , GOETZ NORBERT , HENKELMANN JOCHEM , KNEUPER HEINZ-JOSEF , WOLF BERND
Abstract: The invention relates to a method for producing o-chloromethyl benzenecarbonyl chlorides of formula (I), wherein R -R can be the same or different and stand for hydrogen, C1-C4-alkyl, halogen or trifluoromethyl, by converting benzocondensed lactones of formula (II), wherein R -R have the aforementioned meaning, with gaseous or liquid phosgene and the dimers or trimers thereof. The inventive method is characterised in that the conversion is carried out in the presence of catalytical amounts of a Lewis acid and catalytical amounts of a phosgenation catalyst.
Abstract translation: 本发明涉及一种用于制备式（I），其中R <1> -R <4>相同或不同，并代表氢，C1-C4烷基，卤素或三氟甲基，由反应的邻 - 氯甲基苯甲酰氯 苯并稠合的式（II）的内酯，其中R <1> -R <4>具有上述含义，与gesförmigem或液体光气，其二聚体或三聚体，其特征在于，在催化量的路易斯的存在下的反应 进行酸和催化量的光气化催化剂。
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公开(公告)号：WO0142182A3
公开(公告)日：2001-12-06
申请号：PCT/EP0011810
申请日：2000-11-27
Applicant: BASF AG , GOETZ ROLAND , GOETZ NORBERT , KEIL MICHAEL , WOLF BERND , STEINMETZ ADRIAN , STAMM ARMIN , HENKELMANN JOCHEM
Inventor： GOETZ ROLAND , GOETZ NORBERT , KEIL MICHAEL , WOLF BERND , STEINMETZ ADRIAN , STAMM ARMIN , HENKELMANN JOCHEM
Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R to R can be the same or different and represent hydrogen C1-C4 alkyl, halogen or trifluoromethyl, by reacting benzo-condensed lactones of formula (II), in which R to R have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a boric acid, boric acid anhydride, borate, boronic acid or boronic acid ester and in the presence of catalytic quantities of a quaternary ammonia salt.
Abstract translation: 本发明涉及一种用于制备式（I）的邻 - 氯甲基苯甲酰氯，于R的处理<4>可以<1>是相同的或R不同，并代表氢，C1-C4烷基，卤素或三氟甲基，通过使 苯并稠合的式内酯（II），至R <4>具有R <1>如上所定义，与亚硫酰氯，其特征在于gekennzeichet，在催化量的硼酸，的存在下进行反应硼酸酐，硼酸盐，硼酸或Boronsäureester一个和 催化量的季铵盐。
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公开(公告)号：WO0119768A2
公开(公告)日：2001-03-22
申请号：PCT/EP0008515
申请日：2000-08-31
Applicant: BASF AG , BUSCH RALPH , KNEUPER HEINZ JOSEF , WEBER THEODOR , MUELLER WINFRIED , STAMM ARMIN , HENKELMANN JOCHEM
Inventor： BUSCH RALPH , KNEUPER HEINZ-JOSEF , WEBER THEODOR , MUELLER WINFRIED , STAMM ARMIN , HENKELMANN JOCHEM
Abstract: The invention relates to a method for producing acid chlorides by converting carboxylic acids with carbon oxychlorides or thionyl chloride in the presence of a catalyst adduct of an N,N-disubstituted formamide of general formula (I) and carbon oxychloride or thionyl chloride. In the formula, R and R , independently from one another, mean C1- to C4-alkyl or R and R together mean a C4- or C5-alkylene chain. According to the inventive method, hydrogen chloride is added during and/or after the conversion.
Abstract translation: 通过羧酸与光气或亚硫酰氯，在通式（I）的N，N-二取代甲酰胺的催化剂加合物的存在下反应为羧酸酰氯的制备方法，其中R <1>和R <2>独立地是C1至 C4烷基或R1和R2一起表示C4或C5亚烷基链，以及光气或亚硫酰氯，其中氯化氢在反应过程中和/或反应后引入。
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公开(公告)号：WO0142185A3
公开(公告)日：2002-05-02
申请号：PCT/EP0011817
申请日：2000-11-27
Applicant: BASF AG , GOETZ ROLAND , GOETZ NORBERT , KEIL MICHAEL , WOLF BERND , STEINMETZ ADRIAN , STAMM ARMIN , HENKELMANN JOCHEM
Inventor： GOETZ ROLAND , GOETZ NORBERT , KEIL MICHAEL , WOLF BERND , STEINMETZ ADRIAN , STAMM ARMIN , HENKELMANN JOCHEM
Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R to R can be the same or different and represent hydrogen C1-C4 alkyl, halogen or trifluoromethyl, by reacting benzo-condensed lactones of formula (II), in which R to R have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.
Abstract translation: 本发明涉及一种用于制备式（I），其中R <1> -R <4>相同或不同，并代表氢，C1-C4烷基，卤素或三氟甲基，由反应的邻 - 氯甲基苯甲酰氯 苯并稠合的式（II）的内酯，其中R <1> -R <4>具有上述含义，与亚硫酰氯，其特征在于，一个执行在路易斯酸催化量和催化量的膦的存在下进行反应。
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Patent Agency Ranking
公开(公告)号：WO9929648A3
公开(公告)日：1999-08-12
申请号：PCT/EP9807500
申请日：1998-11-21
Applicant: BASF AG , WEYER HANS JUERGEN , STAMM ARMIN , WEBER THEODOR , HENKELMANN JOCHEM
Inventor： WEYER HANS-JUERGEN , STAMM ARMIN , WEBER THEODOR , HENKELMANN JOCHEM
Abstract: The invention relates to a method for producing chlorocarboxylic acid chlorides of formula (I) R -CHCl-Y-COCl, wherein R represents hydrogen or C1 to C20 alkyl for example and Y represents a saturated or a mono- or poly-olefinically unsaturated C2-C8 alkene chain for example, by reacting lactones with a chlorination agent in the presence of a urea compound.
Abstract translation: 本发明是制备下式的氯羰基氯化物（I）的方法中，R <1> -CHC1-Y-COC1，其中R <1> C1-C20烷基，例如，氢或和Y，例如，饱和的或 单或多烯属不饱和C 2 -C 8亚烷基链，通过使内酯与氯化剂在脲化合物存在下反应。
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公开(公告)号：BRPI0611122B1
公开(公告)日：2015-08-11
申请号：BRPI0611122
申请日：2006-05-02
Applicant: BASF AG
Inventor： OFTRING ALFRED , BRAUN GEROLD , WIRSING FRIEDRICH , STAMM ARMIN , BALDENIUS KAI-UWE
IPC: C07C227/26 , C07C229/16
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公开(公告)号：CA2336657C
公开(公告)日：2009-02-24
申请号：CA2336657
申请日：1999-07-06
Applicant: BASF AG
Inventor： HENKELMANN JOCHEM , STAMM ARMIN
IPC: C07D233/61 , C07D233/90 , C07D521/00
Abstract: The invention relates to a method for producing carbonyl diimidazoles of general formulas (Ia), (Ib), (Ic) or mixtures thereof, whereby R1 represents hydrogen or a C1-C4 alkyl radical and R2 represents hydrogen o r a methyl radical. According to the invention, stoichiometric quantities of an organic nitrogenous base which comprises a lower pK b value than imidazole is added to the reaction mixture with regard to the imidazoles by reacting at least one imidazole of general formulas (IIa) and (IIb) in which R1 and R2 have the aforementioned meanings with phosgene in an inert solvent.
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公开(公告)号：ES2256464T3
公开(公告)日：2006-07-16
申请号：ES02724288
申请日：2002-04-17
Applicant: BASF AG
Inventor： STAMM ARMIN , KNEUPER HEINZ-JOSEF , RITTINGER STEFAN , DRANSFELD PETER , SCHILDBERG HANS-PETER , HEILIG MANFRED
Abstract: Un procedimiento para la manipulación intrínsecamente segura del 3-cloropropino en presencia de un diluyente con un punto de ebullición que oscila entre los -50 °C (223 K) y los 200 °C (473 K) bajo presión atmosférica, caracterizado porque el diluyente, que hierve a la misma temperatura que el 3-cloropropino o a una temperatura superior, se utiliza en una cantidad de entre le 50 y el 2000% del peso en la fase líquida, basado en la cantidad de 3-cloropropino en la fase líquida, y porque la concentración de 3-cloropropino en la fase líquida y en la fase gaseosa se mantiene por debajo de las concentraciones susceptibles a la deflagración gracias al tipo y la cantidad de diluyente, la temperatura y la presión total del sistema.
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公开(公告)号：ES2235972T3
公开(公告)日：2005-07-16
申请号：ES00972657
申请日：2000-08-31
Applicant: BASF AG
Inventor： BUSCH RALPH , KNEUPER HEINZ-JOSEF , WEBER THEODOR , MULLER WINFRIED , STAMM ARMIN , HENKELMANN JOCHEM
Abstract: Procedimiento para la purificación de cloruros de ácido carboxílico que se han fabricado mediante reacción de ácidos carboxílicos con fosgeno o cloruro de tionilo en presencia de un aducto del catalizador y se han separado de la fase que contiene el aducto del catalizador, caracterizado porque los cloruros de ácido carboxílico se tratan con un hidrohalogenuro de amidas del ácido carboxílico de fórmula general (I) en la que R1 representa hidrógeno o alquilo C1 a C3; R2 y R3 significan independientemente entre sí alquilo C1 a C4 o R2 y R3 juntos significan una cadena alquileno C4 o C5, en la que la solubilidad mutua del cloruro de ácido carboxílico y del hidrohalogenuro de la amida del ácido carboxílico (I) es baja y que el cloruro de ácido carboxílico así impurificado se aísla mediante la separación de la fase del hidrohalogenuro de la amida del ácido carboxílico.
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