公开(公告)号：DE2424373A1

公开(公告)日：1975-12-11

申请号：DE2424373

申请日：1974-05-20

Applicant: BASF AG

Inventor： DECKER MARTIN DIPL CHEM DR ,  SCHOENLEBEN WILLIBALD DIPL CHE ,  TOUSSAINT HERBERT DIPL CHEM DR ,  HOFFMANN HERWIG DIPL CHEM DR

IPC: C07C251/30 ,  C07C67/00 ,  C07C241/00 ,  C07D239/42 ,  C07C119/08

Abstract: Compounds of the general formula + CH3 R1O- HC- CH- CH= N ANGLE Cl ,¦¦ CH3 Cl R2 which may be used in place of malondialdehyde in synthesis reactions are obtained in a one-step reaction form dimethylformamide, phosgene and an alkyl vinyl ether.

公开(公告)号：DE2651578A1

公开(公告)日：1978-06-22

申请号：DE2651578

申请日：1976-11-12

Applicant: BASF AG

Inventor： DOCKNER TONI DIPL CHEM DR ,  KRUG HERBERT ,  TOUSSAINT HERBERT DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  DECKER MARTIN DIPL CHEM DR

IPC: C07C209/18 ,  C07C87/62

Abstract: In parent patent, the continuous prodn. of N-alkylarylamines (I) comprises gas-phase reaction of arylamines (II) with alcohols (III) and/or dialkyl ethers (IV) at 180-450 degrees C in presence of carriers contg. oxyacids of P. The catalyst used is silica of internal surface 50-500 m2/g and H3PO4 content 0.1-20 wt.% and during the reaction H3PO4 and/or alkyl phosphates are continuously supplied to the catalyst. In this addition (II) and (III) or (IV) are introduced as gases at a temp. equal to or greater than the reaction temp. By using the reactants to heat the catalyst, surface coking is reduced.

公开(公告)号：DE2639648A1

公开(公告)日：1978-03-16

申请号：DE2639648

申请日：1976-09-03

Applicant: BASF AG

Inventor： HOFFMANN HERWIG DIPL CHEM DR ,  MUELLER HERBERT DIPL CHEM DR ,  TOUSSAINT HERBERT DIPL CHEM DR ,  WITTWER ARNOLD DIPL CHEM DR

IPC: C07C87/06 ,  C07C85/06

Abstract: Prepn. of mono- or poly-, symmetrical or asymmetrical tert-amines comprises reacting a prim. or sec. amine R1-NH-R2 (where R1 and R2 are each H, alkyl or cycloalkyl gps., opt. substd. by inert substs. which, in turn, may carry amino gps. -NHR1) with mono- or di-hydric prim. or sec. - alcohols. The reaction is catalysed by a hydrogenation/dehydrogenation catalyst, opt. in the presence of H2, and the amine is fed into the liq. reaction mixt. contg. the mixt. of alcohol required for the reaction and the proportion of water formed in the reaction is eliminated. High yields of tert-amines are obtd. with low amts. of prim- and sec-amine contamination. Since the alcohol reactant is completely consumed the sepn. of alcohol from tert-amine, which is usually difficult and energy-consuming, is avoided.

公开(公告)号：DE2547654A1

公开(公告)日：1977-04-28

申请号：DE2547654

申请日：1975-10-24

Applicant: BASF AG

Inventor： HIMMELE WALTER DIPL CHEM DR ,  HUPFER LEOPOL DIPL CHEM DR ,  TOUSSAINT HERBERT DIPL CHEM DR ,  PAUL GERHARD DIPL CHEM DR

IPC: C07C215/08 ,  C07C20060101 ,  C07C67/00 ,  C07C213/00 ,  C07C215/12 ,  C07D263/12 ,  C07D263/14 ,  C07C91/04

公开(公告)号：DE2445192A1

公开(公告)日：1976-04-01

申请号：DE2445192

申请日：1974-09-21

Applicant: BASF AG

Inventor： FUERST ERMST NEUSTADT DR ,  TOUSSAINT HERBERT DIPL CHEM DR ,  HOFFMANN HERWIG DIPL CHEM DR

IPC: C07D295/182 ,  C07D295/02

Abstract: N-formyl morpholine is prepared by reacting methyl formate and morpholine in a stoichiometric ratio, these reactants being a admixed and after 7-10 hrs at 85-95 degrees C, passed to a rapid vaporisation device where, at a surface temp. of 135-145 degrees C and residence time of 0.5-5 min, the mixture is freed from MeOH. The yield of N-formyl morpholine is almost quantitive.

公开(公告)号：DE3207614A1

公开(公告)日：1983-09-15

申请号：DE3207614

申请日：1982-03-03

Applicant: BASF AG

Inventor： TOUSSAINT HERBERT DIPL CHEM DR ,  PANDER HANS JOACHIM

IPC: C07B61/00 ,  B01J23/00 ,  B01J31/00 ,  C07C51/08 ,  C07C67/00 ,  C07C253/00 ,  C07C255/17 ,  C07C121/34 ,  C07C120/02

Abstract: 3-Cyanoaldehydes of the formula I I where R1 and R2 are each C1-C6-alkyl and R3 is hydrogen or C1-C3-alkyl, are prepared by a process wherein an aldehyde of the formula II II is reacted with anhydrous hydrocyanic acid in the presence of a basic catalyst, in a solvent.

公开(公告)号：DE2836831A1

公开(公告)日：1980-03-13

申请号：DE2836831

申请日：1978-08-23

Applicant: BASF AG

Inventor： MUELLER HERBERT DIPL CHEM DR ,  TOUSSAINT HERBERT DIPL CHEM DR ,  WITTWER ARNOLD DIPL CHEM DR

IPC: C07B61/00 ,  B01J23/00 ,  B01J25/00 ,  C07C67/00 ,  C07C213/00 ,  C07C213/08 ,  C07C215/08 ,  C07C91/06

Abstract: 5-Diethylaminopentan-2-ol is obtained from 1-diethylamino-pent-2-yn-4-ol by hydrogenation, if a nickel catalyst is used in the presence of a basic alkali metal compound or alkaline earth metal compound and the hydrogenation is carried out in the absence of water.

公开(公告)号：DE2725669A1

公开(公告)日：1978-12-07

申请号：DE2725669

申请日：1977-06-06

Applicant: BASF AG

Inventor： MERKEL KARL DR ,  TOUSSAINT HERBERT DIPL CHEM DR ,  MUELLER HERBERT DIPL CHEM DR ,  HOFFMANN HERWIG DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  MERCKER HANS JOCHEN DIPL CHEM

IPC: C07C209/26 ,  C07C87/127 ,  C07C85/08

公开(公告)号：DE2625196A1

公开(公告)日：1977-12-22

申请号：DE2625196

申请日：1976-06-04

Applicant: BASF AG

Inventor： HOFFMANN HERWIG DIPL CHEM DR ,  MUELLER HERBERT DIPL CHEM DR ,  TOUSSAINT HERBERT DIPL CHEM DR

IPC: C07C87/06 ,  C07C85/06

Abstract: Prepn. of mono- or poly-, symmetrical or asymmetrical tert-amines comprises reacting a prim. or sec. amine R1-NH-R2 (where R1 and R2 are each H, alkyl or cycloalkyl gps., opt. substd. by inert substs. which, in turn, may carry amino gps. -NHR1) with mono- or di-hydric prim. or sec. - alcohols. The reaction is catalysed by a hydrogenation/dehydrogenation catalyst, opt. in the presence of H2, and the amine is fed into the liq. reaction mixt. contg. the mixt. of alcohol required for the reaction and the proportion of water formed in the reaction is eliminated. High yields of tert-amines are obtd. with low amts. of prim- and sec-amine contamination. Since the alcohol reactant is completely consumed the sepn. of alcohol from tert-amine, which is usually difficult and energy-consuming, is avoided.

公开(公告)号：DE2543279A1

公开(公告)日：1977-04-07

申请号：DE2543279

申请日：1975-09-27

Applicant: BASF AG

Inventor： GOETZ NORBERT DIPL CHEM DR ,  ZEEH BERND DIPL CHEM DR ,  DECKER MARTIN DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  TOUSSAINT HERBERT DIPL CHEM DR

IPC: C07D295/02 ,  C07D295/023 ,  C07D295/03 ,  C07D295/033 ,  C07D265/30

Abstract: A new process for the manufacture of N-substituted tetrahydro-1,4-oxazines, also called morpholines, by conversion of N-substituted bis-(2-hydroxyalkyl)-amines in the presence of catalysts.