公开(公告)号：DE10129768A1

公开(公告)日：2003-01-02

申请号：DE10129768

申请日：2001-06-20

Applicant: BASF AG

Inventor： BOEHLING RALF ,  VOGEL HERBERT ,  RICHTER THOMAS

IPC: C07C37/58 ,  C07C201/12 ,  C07B41/02 ,  C07C39/00 ,  C07C39/24 ,  C07C205/06 ,  C07C205/11

Abstract: Processes for the production of phenol and corresponding derivatives comprises reaction of benzene or corresponding derivatives at 2-80 MPa and 200-500 deg C. The production of phenol (A), a phenol derivative (B) having at least one hydrogen atom replaced by halogen or nitro, or a condensed aromatic ring (C) that carries only hydrogen atoms and optionally halogen or nitro groups in addition to a hydroxyl group whereby the ring system comprises 2-4C atoms, comprises reaction of benzene (A1) (for the production of phenol (A)), a corresponding benzene derivative (B1) for the production of compound (B) or a corresponding ring system (C1) (for the production of compound (C) at 2-80 MPa and 200-500 deg C.

公开(公告)号：DE59603316D1

公开(公告)日：1999-11-18

申请号：DE59603316

申请日：1996-03-04

Applicant: BASF AG

Inventor： HEFNER WERNER ,  MACHHAMMER OTTO ,  NEUMANN HANS-PETER ,  TENTEN ANDREAS ,  RUPPEL WILHELM ,  VOGEL HERBERT

IPC: C07C47/22 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C45/33 ,  C07C45/35 ,  C07C51/215 ,  C07C51/25 ,  C07C57/04 ,  C07C57/05 ,  C07C57/055

Abstract: Prodn. of acrolein (I) and/or acrylic acid (II) from C3H8 involves (A) gas phase partial dehydrogenation of C3H8 to C3H6, using heterogeneous catalyst; (B) using the prod. gas mixt. of C3H6 and unreacted C3H8 for charging an oxidn. reactor, in which C3H6 is converted to (I) and/or (II) by gas phase selective partial oxidn. with pure O2 using heterogeneous catalyst; and (C) separating the prod. from the prod. gas stream and recycling at least the unreacted C3H8 from stage (B) to stage (A). The novelty is that, before entering stage (B), constituents other than C3H8 and C3H6, at least H2 and steam, are removed from the prod. gas mixt. from stage (A). Pref. all constituents except C3H8 and C3H6 are removed after stage (A). Stage (B) is carried out in 2 consecutive reactors charged with multi-metal oxide catalysts, the first of Mo-Bi-Fe and the second of Mo-V. The prod. gas mixt. from the first oxidn. reactor is passed directly into the second; and the vol. ratio of organic cpd. for partial oxidn. (C3H6 or (II)) to O2 is 1:(1-3) in both reactors.

公开(公告)号：ID17854A

公开(公告)日：1998-01-29

申请号：ID960588

申请日：1996-03-11

Applicant: BASF AG

Inventor： HEFNER WERNER ,  MACHHAMMER OTTO ,  NEUMANN HANS PETER ,  TENTEN ANDREAS ,  RUPPEL WILHELM ,  VOGEL HERBERT

IPC: C07C27/00 ,  C07C27/14 ,  C07C45/35 ,  C07C47/22 ,  C07C51/25 ,  C07C57/04 ,  C07C57/05 ,  C07C57/055

Abstract: In continuous gas phase oxidn. of C3H6 to acrolein (I) and/or acrylic acid (II) with heterogeneous catalyst in an oxidn. reactor, the charge gas mixt. (III) contains only inert diluent gas(es) (IIIA) in addn. to C3H6 and O2 and (pt. of) (IIIA) is sepd. from the prodn. gas mixt. and recycled to the oxidn. reactor. The novelty is that (IIIA) consists of over 85 vol. % 1-5C satd. hydrocarbon(s).

公开(公告)号：ES2098120T3

公开(公告)日：1997-04-16

申请号：ES94901917

申请日：1993-11-30

Applicant: BASF AG

Inventor： BOECK STEFAN ,  HERZOG KLAUS ,  FISCHER ROLF ,  VOGEL HERBERT ,  FISCHER MARTIN

IPC: C07D301/10 ,  B01J23/50 ,  B01J23/96 ,  B01J38/12 ,  B01J38/16 ,  C07D303/04

Abstract: PCT No. PCT/EP93/03352 Sec. 371 Date Mar. 17, 1995 Sec. 102(e) Date Mar. 17, 1995 PCT Filed Nov. 30, 1993 PCT Pub. No. WO94/13653 PCT Pub. Date Jun. 23, 19943,4-Epoxy-1-butene is prepared by the gas phase epoxidation of 1,3-butadiene by means of oxygen or oxygen-containing gases over silver-containing catalysts and isolation of the 3,4-epoxy-1-butene from the reaction exit mixture by performing the gas phase epoxidation in the presence of from 6 to 80 mol % of water vapor, based on the gas mixture supplied to the reactor.

公开(公告)号：CZ73396A3

公开(公告)日：1996-09-11

申请号：CZ73396

申请日：1996-03-08

Applicant: BASF AG

Inventor： HEFNER WERNER ,  MACHHAMMER OTTO ,  NEUMANN HANS PETER ,  TENTEN ANDREAS ,  RUPPEL WILHELM ,  VOGEL HERBERT

IPC: C07C47/22 ,  C07B61/00 ,  C07C5/333 ,  C07C11/06 ,  C07C45/33 ,  C07C45/35 ,  C07C51/215 ,  C07C51/25 ,  C07C57/04 ,  C07C57/05 ,  C07C57/055

Abstract: Prodn. of acrolein (I) and/or acrylic acid (II) from C3H8 involves (A) gas phase partial dehydrogenation of C3H8 to C3H6, using heterogeneous catalyst; (B) using the prod. gas mixt. of C3H6 and unreacted C3H8 for charging an oxidn. reactor, in which C3H6 is converted to (I) and/or (II) by gas phase selective partial oxidn. with pure O2 using heterogeneous catalyst; and (C) separating the prod. from the prod. gas stream and recycling at least the unreacted C3H8 from stage (B) to stage (A). The novelty is that, before entering stage (B), constituents other than C3H8 and C3H6, at least H2 and steam, are removed from the prod. gas mixt. from stage (A). Pref. all constituents except C3H8 and C3H6 are removed after stage (A). Stage (B) is carried out in 2 consecutive reactors charged with multi-metal oxide catalysts, the first of Mo-Bi-Fe and the second of Mo-V. The prod. gas mixt. from the first oxidn. reactor is passed directly into the second; and the vol. ratio of organic cpd. for partial oxidn. (C3H6 or (II)) to O2 is 1:(1-3) in both reactors.

公开(公告)号：DE102005027814A1

公开(公告)日：2006-12-21

申请号：DE102005027814

申请日：2005-06-15

Applicant: BASF AG

Inventor： FIENE MARTIN ,  BOEHLING RALF ,  STROEFER ECKHARD ,  VOGEL HERBERT ,  MESRI FATIMA

IPC: C07C263/20 ,  B09B3/00 ,  C07B43/04 ,  C07C209/62 ,  C07C263/10 ,  C08J11/10

Abstract: The present invention provides a process for working up isocyanate adducts, comprising the steps of a) reacting the isocyanate adducts with pure ammonia, b) working up the reaction products obtained in step a), c) recycling the amines formed into the isocyanate production.

公开(公告)号：CZ9600733A3

公开(公告)日：1996-09-11

申请号：CZ73396

申请日：1996-03-08

Applicant: BASF AG

Inventor： HEFNER WERNER ,  MACHHAMMER OTTO ,  NEUMANN HANS PETER ,  TENTEN ANDREAS ,  RUPPEL WILHELM ,  VOGEL HERBERT

IPC: C07C47/22 ,  C07B61/00 ,  C07C45/33 ,  C07C45/35 ,  C07C51/25 ,  C07C57/04 ,  C07C57/05 ,  C07C57/055

CPC classification number: C07C45/35 ,  C07C45/33 ,  C07C51/252 ,  C07C47/22 ,  C07C57/04

公开(公告)号：AU5629294A

公开(公告)日：1994-07-04

申请号：AU5629294

申请日：1993-11-30

Applicant: BASF AG

Inventor： BOECK STEFAN ,  HERZOG KLAUS ,  FISCHER ROLF ,  VOGEL HERBERT ,  FISCHER MARTIN

IPC: C07D301/10 ,  B01J23/50 ,  B01J23/96 ,  B01J38/12 ,  B01J38/16 ,  C07D303/04

Abstract: PCT No. PCT/EP93/03352 Sec. 371 Date Mar. 17, 1995 Sec. 102(e) Date Mar. 17, 1995 PCT Filed Nov. 30, 1993 PCT Pub. No. WO94/13653 PCT Pub. Date Jun. 23, 19943,4-Epoxy-1-butene is prepared by the gas phase epoxidation of 1,3-butadiene by means of oxygen or oxygen-containing gases over silver-containing catalysts and isolation of the 3,4-epoxy-1-butene from the reaction exit mixture by performing the gas phase epoxidation in the presence of from 6 to 80 mol % of water vapor, based on the gas mixture supplied to the reactor.