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公开(公告)号:US3920692A
公开(公告)日:1975-11-18
申请号:US44341474
申请日:1974-02-19
Applicant: BASF AG
Inventor: WIERSDORFF WALTER WIELANT , FISCHER MARTIN
IPC: C07D487/22 , C09B47/00
CPC classification number: C07D487/22
Abstract: Mesotetraarylporphines are produced by reaction of pyrrole with an aromatic aldehyde in the presence of an organic substance having a dehydrogenating effect as an oxidizing agent and of a lower aliphatic carboxylic acid. The mesotetraarylporphines are suitable as such or in the form of their metal complexes particularly as photooxidation sensitizers.
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公开(公告)号:US3902980A
公开(公告)日:1975-09-02
申请号:US45757874
申请日:1974-04-02
Applicant: BASF AG
Inventor: FISCHER MARTIN , EICKEN KARL
IPC: B01J19/12 , C07D327/04 , B01J1/10
CPC classification number: B01J19/122 , B29C2793/00 , C07D327/04
Abstract: Production of 3-sulfopropionic anhydride by reaction of propionic acid with chlorine and sulfur dioxide in specific proportions with irradiation. The 3-sulfopropionic anhydride prepared by the process of the invention is a valuable starting material for the production of dyes, pesticides and fibers.
Abstract translation: 通过丙酸与氯和二氧化硫的反应以特定比例的照射生产3-磺基丙酸酐。 通过本发明方法制备的3-磺基丙酸酐是用于生产染料,农药和纤维的有价值的起始原料。
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公开(公告)号:WO02083550A3
公开(公告)日:2003-09-04
申请号:PCT/EP0204052
申请日:2002-04-11
Applicant: BASF AG , BUTZ THOMAS , FISCHER MARTIN , MASSONNE KLEMENS
Inventor: BUTZ THOMAS , FISCHER MARTIN , MASSONNE KLEMENS
IPC: C01B15/029
CPC classification number: C01B15/029
Abstract: The invention relates to a continuous method for producing a hydrogen peroxide solution in a medium that comprises a water-miscible organic solvent, by reacting hydrogen and oxygen in the presence of an inert gas, the gas flow being circulated and the hydrogen and oxygen only being supplemented in the form of pure gases as they are consumed. The invention further relates to the use of the solution so produced in the epoxidation of olefins.
Abstract translation: 本发明涉及一种连续方法用于在介质中制备的过氧化氢溶液,其包含水混溶性orgnaisches溶剂,通过在大容量在惰性气体的存在下氢与氧的反应,其中所述气流被循环Wassersteoff和氧NU 通过被消耗在形式赖纳·加斯来补充。 此外,本发明涉及使用用于烯烃的环氧化,从而制得的溶液。
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公开(公告)号:MXPA03002660A
公开(公告)日:2003-06-24
申请号:MXPA03002660
申请日:2001-10-01
Applicant: BASF AG
Inventor: FISCHER MARTIN
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公开(公告)号:DK1203000T3
公开(公告)日:2003-06-02
申请号:DK00951493
申请日:2000-08-10
Applicant: BASF AG
Inventor: AUST NICOLA CHRISTIANE , BUTZ THOMAS , FISCHER MARTIN
Abstract: The present invention relates to a process for the preparation of phosphonomethylglycine in which N-phosphonomethyliminodiacetic acid N-oxide is brought into contact with a catalytically active quantity of at least one catalyst, selected from amongst a thionyl halide, ammonium dithionite or an alkali metal dithionite, a dialkyl sulfite, sulfur dichloride, sulfur dioxide and sulfurous acid, in a reaction chamber by metering the N-phosphonomethyliminodiacetic acid N-oxide into the reaction chamber in such a way that always at least 50% of the N-oxide metered into the reaction chamber are converted.
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公开(公告)号:CZ20020495A3
公开(公告)日:2002-08-14
申请号:CZ20020495
申请日:2000-08-10
Applicant: BASF AG
Inventor: AUST NICOLA CHRISTIANE , BUTZ THOMAS , FISCHER MARTIN
CPC classification number: C07F9/3813
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公开(公告)号:DE59802965D1
公开(公告)日:2002-03-14
申请号:DE59802965
申请日:1998-06-05
Applicant: BASF AG
Inventor: GROSCH HEINRICH , MUELLER ULRICH , WALCH ANDREAS , RIEBER NORBERT , FISCHER MARTIN , QUAISER STEFAN , HARDER WOLFGANG , ELLER KARSTEN , BASSLER PETER , WENZEL ANNE , KAIBEL GERD , STAMMER ACHIM , HENKELMANN JOCHEM , BOETTCHER ARND , TELES HENRIQUE , SCHULZ MICHAEL , TREIBER GERT
IPC: B01J29/90 , B01J38/14 , C07B41/00 , C07B61/00 , C07D301/12 , C07D301/19
Abstract: A process for oxidizing an organic compound having at least one C-C double bond or a mixture of two or more thereof comprises the following steps:(I) preparing a hydroperoxide,(II) reacting an organic compound having at least one C-C double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst,(III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and(IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III).
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公开(公告)号:CA2381413A1
公开(公告)日:2001-02-22
申请号:CA2381413
申请日:2000-08-10
Applicant: BASF AG
Inventor: FISCHER MARTIN , BUTZ THOMAS , AUST NICOLA CHRISTIANE
Abstract: The invention relates to a method for the production of phosphonomethylglycine, by adding N-phosphonomethyl iminodiacetic acid-N-oxi de to a catalytic quantity of thiocyanic acid or one of the salts thereof.
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公开(公告)号:DE19915681A1
公开(公告)日:2000-10-12
申请号:DE19915681
申请日:1999-04-07
Applicant: BASF AG
Inventor: FISCHER MARTIN , HOELZLE MARKUS , QUAISER STEFAN , STAMMER ACHIM
IPC: B01J23/40 , B01J23/44 , B01J23/46 , B01J23/62 , B01J35/10 , B01J37/02 , B01J37/03 , C01B15/026 , B01J37/16 , C01B15/029 , C07C29/145 , C07B31/00
Abstract: The invention relates to a method for producing catalysts by immersion coating a metallic support with at least one platinum metal. An aqueous medium which comprises at least one platinum metal complex, at least one reduction agent and at least one complexer and which has a pH value of more than 4 is brought into contact with the metallic support in order to deposit the platinum metal, the platinum metal being deposited in the form of discreet, immobilised particles. The invention also relates to the catalysts obtained using this method and to their use for producing hydrogen peroxide and for hydrogenating organic compounds.
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公开(公告)号:AT193843T
公开(公告)日:2000-06-15
申请号:AT96934716
申请日:1996-10-17
Applicant: BASF AG
Inventor: FISCHER MARTIN
IPC: B01J31/02 , B01J31/40 , B01J38/00 , C07D307/28
Abstract: PCT No. PCT/EP96/04504 Sec. 371 Date Apr. 21, 1998 Sec. 102(e) Date Apr. 21, 1998 PCT Filed Oct. 17, 1996 PCT Pub. No. WO97/15392 PCT Pub. Date May 1, 1997An improved process is provided for the recovery of catalyst components from oligomeric impurities which are formed during the industrial preparation of 2,5-dihydrofuran by the catalytic isomerization of vinyl oxirane followed by an essential separation of the oligomeric by-products which otherwise cause deactivation of the catalyst. The catalyst components consist essentially of (a) an onium iodide and (b) a Lewis acid selected from the group consisting of the chloride, bromide or iodide of the metals zinc, tin, cobalt and bismuth, preferably zinc, where the catalyst optionally includes a donor ligand. This separation is carried out by the steps of extracting the initial product mixture containing zinc, cobalt or bismuth halides as Lewis acids with hydrocarbons or chlorinated hydrocarbons containing from 5 to 14 carbon atoms in order to form two separate phases on standing, separating off the extraction solvent phase which contains the dissolved catalyst and then recovering the separated catalyst by distilling off the extraction solvent. The recovery of tin iodide requires the presence of a special onium halide component such as phosphazenium or phosphazanium halides, preferably the iodides, having a high molecular weight and especially those which contain from 16 to 72 carbon atoms while remaining soluble in the extracting agent.
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