11.
    发明专利
    未知

    公开(公告)号:ID17935A

    公开(公告)日:1998-02-12

    申请号:ID971545

    申请日:1997-05-09

    Applicant: BASF AG

    Abstract: Elastic polyurethane moldings having a compact surface and a cellular core are produced by reactinga) modified organic polyisocyanates withb) at least one relatively high molecular weight compound containing at least two reactive hydrogen atoms and, if desired,c) low molecular weight chain extenders in the presence ofd) blowing agents,e) catalysts and, if desired,f) customary auxiliaries and/or additivesin a closed mold with compaction, wherein the modified organic polyisocyanate used is at least one reaction product of pure MDI and at least one polyether alcohol (polyoxyalkylene polyol), the modified organic polyisocyanate having an NCO content of

    MANUFACTURE OF THIN LAYERS OF POLYURETHANE ELASTOMERS

    公开(公告)号:CA1007595A

    公开(公告)日:1977-03-29

    申请号:CA187265

    申请日:1973-12-03

    Applicant: BASF AG

    Abstract: 1450906 Polyurethane layers; photopolymerizing unsaturated monomers BASF AG 3 Dec 1973 [4 Dec 1972] 55919/73 Headings C3R and C3P Polyurethane layers are prepared by adding a compatible monomer having at least two photocross-linkable C-C multiple bonds or a compatible monomer mixture comprising at least 50% by weight of one of such monomers and not more than 50% by weight of a photopolymerizable monoethylenically unsaturated monomer, and optionally also a photopolymerization initiator, to a liquid polyurethane elastomer forming reaction mixture comprising (A) (i) a polyether, polyester, hydroxypolyether urethane or hydroxypolyester urethane or a mixture thereof with a polyalcohol and/or a diamino and (ii) a diisocyanate or (B) (i) a prepolymer of a hydroxyl compound as defined in (A) and a diisocyanate and (ii) a polyester, polyether, hydroxypolyester urethane, hydroxypolyetherurethane, polyhydric alcohol, or diamine or a mixture of two or more thereof, the resulting mixture containing a major amount of the polyurethane elastomer-forming reaction mixture, applying the resulting mixture to a substrate to form a layer, irradiating the layer with electromagnetic radiation of wavelength less than 0À7 Ám to effect photocrosslinking of the monomer(s) and gelling of the layer and thermally curing the so-treated layer. The layer is suitably formed on a continuously moving substrate and has a thickness of from 0À2 to 5 mm. Conventional polyurethane elastomer-forming reactants are used. The monomer having at least two C-C multiple bonds is preferably an olefinically poly-unsaturated carboxylate, for example a diester of a C 2-6 aliphatic diol and acrylic or methacrylic acid, a triester of a C 3-10 aliphatic triol and acrylic or methacrylic acid, a divinyl ester of a C 2-8 dicarboxylic acid, a diallyl ester of a C 2-8 dicarboxylic acid and a vinyl ester or allyl ester of a C 3-5 olefinically unsaturated monocarboxylic acid. The unsaturated monomers are preferably used in amounts not exceeding 10% weight of the reaction mixture.

    17.
    发明专利
    未知

    公开(公告)号:DE19914076A1

    公开(公告)日:2000-09-28

    申请号:DE19914076

    申请日:1999-03-27

    Applicant: BASF AG

    Abstract: A reactant for making compact or cellular polyurethanes are di- or tri-functional polyoxypropylenepolyols whose terminal secondary OH groups are linked via a divalent bridging member to diols having only primary OH groups. Process for preparing compact or cellular polyurethanes by reacting (a) at least one compound with at least two active H at with (b) at least one polyisocyanate in the presence of (c) catalysts and optionally (d) blowing agents and (e) assistants and additives, characterized in that component (a) is at least one polyoxypropylene-polyol in which the secondary OH groups are link via a bridging member of formula (I) X -R-X (I) X and X (same or different) = functional groups which are reactive with OH groups; R = a suitable aliphatic, cycloaliphatic or aromatic residue with diols which contain only primary OH groups.

    18.
    发明专利
    未知

    公开(公告)号:DE59800060D1

    公开(公告)日:2000-01-13

    申请号:DE59800060

    申请日:1998-06-10

    Applicant: BASF AG

    Abstract: In the production of rigid polyurethane (PUR) foam with low thermal conductivity by reacting (a) organic and/or modified organic polyisocyanates with (b) compounds containing NOTLESS 2 reactive hydrogen atoms in the presence of (c) blowing agent, (d) catalyst and optionally (e) ancillaries and/or additives, the novelty is that graphite is added to (a) and/or (b). Also claimed is rigid PUR foam produced in this way.

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