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    11.
    发明专利
    未知

    公开(公告)号：DK0539819T3

    公开(公告)日：1998-10-12

    申请号：DK92117788

    申请日：1992-10-17

    Applicant: BASF AG

    Inventor： HINZ WERNER DR ,  ADAMS STEFAN DR ,  KOEHLER ULRICH DR ,  MALETZKO CHRISTIAN DR ,  VORSPOHL KLAUS DR ,  ZSCHIESCHE RUTH DR

    IPC: C08G18/50 ,  C08G65/26 ,  C08G65/02

    Abstract: The invention relates to highly reactive polyoxyalkylenepolyols prepared by oxalkylation of an initiator molecule containing at least 2 reactive hydrogen atoms and at least one tertiary amino group bonded via a spacer bridge, which preferably comprises an alkylene radical having at least 3 carbon atoms, by means of at least one alkylene oxide, preferably ethylene oxide and/or 1,2-propylene oxide, to a process for the preparation of these polyoxyalkylenepolyols, and to their use for the preparation of compact or cellular, preferably flexible, polyisocyanate polyaddition products.

    12.
    发明专利
    未知

    公开(公告)号：ES2117023T3

    公开(公告)日：1998-08-01

    申请号：ES92117788

    申请日：1992-10-17

    Applicant: BASF AG

    Inventor： HINZ WERNER DR ,  ADAMS STEFAN DR ,  KOEHLER ULRICH DR ,  MALETZKO CHRISTIAN DR ,  VORSPOHL KLAUS DR ,  ZSCHIESCHE RUTH DR

    IPC: C08G18/50 ,  C08G65/26

    Abstract: The invention relates to highly reactive polyoxyalkylenepolyols prepared by oxalkylation of an initiator molecule containing at least 2 reactive hydrogen atoms and at least one tertiary amino group bonded via a spacer bridge, which preferably comprises an alkylene radical having at least 3 carbon atoms, by means of at least one alkylene oxide, preferably ethylene oxide and/or 1,2-propylene oxide, to a process for the preparation of these polyoxyalkylenepolyols, and to their use for the preparation of compact or cellular, preferably flexible, polyisocyanate polyaddition products.

    Open cell poly:urethane foams for mouldings
    13.
    发明专利
    Open cell poly:urethane foams for mouldings 未知

    公开(公告)号：DE19545165A1

    公开(公告)日：1997-06-05

    申请号：DE19545165

    申请日：1995-12-04

    Applicant: BASF AG

    Inventor： HINZ WERNER DR ,  VORSPOHL KLAUS DR ,  GUETTES BERND

    IPC: C08G18/65 ,  C08G18/66 ,  C08G18/36 ,  C08L75/04 ,  C08J9/02 ,  C08J9/04

    Abstract: Preparation of open cell polyurethane foams comprises reacting the following components: (A) (modified) organic di- and/or polyisocyanates; (B) high molecular weight compounds with at least two reactive hydrogen atoms; (C) fatty chemical, cell-opening polyols obtained by the addition of nucleophilic compounds to triglycerides containing epoxy groups; and (D) optional chain extenders and/or cross-linking agents, in the presence of (E) propellants, (F) catalysts and (G) optional additives. Also claimed are (i) foams prepared by this method, and (ii) the use of (C) for the preparation of open cell polyurethane foams.

    Ester gp.-contg. polyurethane prods. resistant to hydrolysis - contg. phenylene-bis-oxazoline cpd., used as moulded articles, foams in furniture, etc.
    14.
    发明专利
    Ester gp.-contg. polyurethane prods. resistant to hydrolysis - contg. phenylene-bis-oxazoline cpd., used as moulded articles, foams in furniture, etc. 未知

    公开(公告)号：DE4112793A1

    公开(公告)日：1992-10-22

    申请号：DE4112793

    申请日：1991-04-19

    Applicant: BASF AG

    Inventor： LEHRICH FRIEDHELM DR ,  HORN PETER DR ,  VORSPOHL KLAUS DR

    IPC: C08K5/353

    Abstract: Elastomers (I) with bound ester and urethane gps. contain on (I) 0.1-10% (all pts.wt.) of at least one phenylenebisoxazoline (II) of formula (A) and/or (B), where R1-R3 (same or different) are H, Ph or 1-5C alkyl. Also claimed is the prepn. of polyurethanes (III) contg. bound ester gps. by reacting (A) organic polyisocyanates with (B) higher molecular at least difunctional, polyesterols and (C) chain lengthening agents and/or crosslinking agents in presence of (D) a (II), opt. in presence of (E) blowing agents, (F) catalysts, (G) auxiliaries and/or additives. USE/ADVANTAGE - Used as moulded articles, partic. in machinery construction and transport industries, esp. as flexible pipes, skins, sheets, spring elements, buffers and top coats; foams in furniture, household appts., shoe and motor car industries, e.g. in seats, insulating or cladding materials, sun blinds, head rests, shoe soles, ski cores and receptacles for skis. (I) and (III) have improved hydrolysis resistance and mechanical properties (partic. tensile strength, extension to break), (II) are soluble in starting materials or can be readily incorporated in (I) granulate, do not affect morphology of (I) or (III) and do not migrate.

    Coupling agent(s) for 2-component polyurethane adhesive(s) - comprise enamine(s), esp. 2-N-morpholinyl-cyclo:hex-1-ene, which are incorporated in poly:ol component
    15.
    发明专利
    Coupling agent(s) for 2-component polyurethane adhesive(s) - comprise enamine(s), esp. 2-N-morpholinyl-cyclo:hex-1-ene, which are incorporated in poly:ol component 未知

    公开(公告)号：DE4006645A1

    公开(公告)日：1991-09-05

    申请号：DE4006645

    申请日：1990-03-03

    Applicant: BASF AG

    Inventor： VORSPOHL KLAUS DR ,  HORN PETER DR

    IPC: C09J175/04

    Abstract: Enamines of formula (I) are useful as coupling agents in 2-component polyurethane (PU) adhesives (II). In (I), R4, R5 = 1-8C alkyl, 7-13C aralkyl or 4-8C cycloalkyl, or the two gps. plus the N atom can form a 5-7 membered heterocycle; CnH2n = 3-12C alkylene with at least 3 directly linked C atoms. Pref. (I) is 1-(N-morpholinyl)-cyclohex-1-ene (IA). USE/ADVANTAGE - Coupling agents for 2-component PU adhesives, which can be incorporated into component 2 (i.e. the active H-contg. component based on polyhydric alcohols, etc.). Prior-art coupling agents are either only suitable for 1-component PU adhesives or have to be mixed with the polyisocyanate (component 1). The use of (I) gives improved adhesion on glass, metal, etc., together with improved mechanical properties.

    18.
    发明专利
    未知

    公开(公告)号：DK0458095T3

    公开(公告)日：1995-01-23

    申请号：DK91107075

    申请日：1991-05-02

    Applicant: BASF AG

    Inventor： SCHUSTER LUDWIG DR ,  HINZ WERNER DR ,  HENN ROLF DR ,  VORSPOHL KLAUS DR

    IPC: C08G18/48 ,  C08G65/26 ,  C08G65/28

    Abstract: The invention relates to a process for the production of rigid foams containing urethane or urethane and isocyanurate groups by reacting a) polyoxypropylene- or polyoxyethylene-polyoxypropylene-polyols containing secondary hydroxyl groups, having a functionality of from 3.5 to 4.3, a hydroxyl number of from 350 to 650 and a viscosity of from 500 to 2,500 mPa.s at 23 DEG C, prepared by anionic polymerisation of 1,2-propylene oxide or ethylene oxide and 1,2-propylene oxide onto an initiator molecule mixture containing, based on the total weight, a1) from 40 to 80 % by weight of hexanetetrols, a2) from 1 to 30 % by weight of hexanetriols, a3) from 0 to 35 % by weight of glycerol and a4) from 0 to 15 % by weight of sorbitol or mannitol or mixtures thereof, and b) optionally low-molecular-weight chain extenders and/or crosslinking agents with c) organic, optionally modified polyisocyanates, in the presence of d) blowing agents, e) catalysts and optionally f) assistants and/or additives, and to the polyoxypropylene-polyols and polyoxyethylene- polyoxypropylene-polyols which can be used for this purpose.

    19.
    发明专利
    未知

    公开(公告)号：DE59103623D1

    公开(公告)日：1995-01-12

    申请号：DE59103623

    申请日：1991-05-02

    Applicant: BASF AG

    Inventor： HENN ROLF DR ,  HINZ WERNER DR ,  SCHUSTER LUDWIG DR ,  VORSPOHL KLAUS DR

    IPC: C08G18/48 ,  C08G65/26 ,  C08G65/28

    Abstract: The invention relates to a process for the production of rigid foams containing urethane or urethane and isocyanurate groups by reacting a) polyoxypropylene- or polyoxyethylene-polyoxypropylene-polyols containing secondary hydroxyl groups, having a functionality of from 3.5 to 4.3, a hydroxyl number of from 350 to 650 and a viscosity of from 500 to 2,500 mPa.s at 23 DEG C, prepared by anionic polymerisation of 1,2-propylene oxide or ethylene oxide and 1,2-propylene oxide onto an initiator molecule mixture containing, based on the total weight, a1) from 40 to 80 % by weight of hexanetetrols, a2) from 1 to 30 % by weight of hexanetriols, a3) from 0 to 35 % by weight of glycerol and a4) from 0 to 15 % by weight of sorbitol or mannitol or mixtures thereof, and b) optionally low-molecular-weight chain extenders and/or crosslinking agents with c) organic, optionally modified polyisocyanates, in the presence of d) blowing agents, e) catalysts and optionally f) assistants and/or additives, and to the polyoxypropylene-polyols and polyoxyethylene- polyoxypropylene-polyols which can be used for this purpose.

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