公开(公告)号：JPH11323291A

公开(公告)日：1999-11-26

申请号：JP11412699

申请日：1999-04-21

Applicant: BASF AG

Inventor： GERST MATTHIAS DR ,  AUCHTER GERHARD DR ,  ZETTL ALEXANDER

IPC: C09J7/02 ,  C08L33/08 ,  C09J133/08

Abstract: PROBLEM TO BE SOLVED: To provide a pressure sensitive adhesive having an improved adhesive power and/or cohesive power. SOLUTION: This adhesive consists of a polymer including 60 to 95 wt.% of a monomer mixture (monomer a) comprising one or more kinds of 4C alkylacrylate and one or more kinds of 6 to 12C alkylacrylate, 5 to 30 wt.% of ethylenic unsaturated compound(monomer b) excluding other functional groups except ethylenic unsaturated group and the polymer of this monomer has glass transition temperature >=0 deg.C, 0 to 10 wt.% of an ethylenic unsaturated compound (monomer c) including one or more acid group or acid anhydride group, and 0 to 20 wt.% of other ethylenic unsaturated compound (monomer d), the weight ratio in wt.% is based on the obtained polymer, and the polymer dispersion includes an emulsifier including at least 5 wt.% of aromatic carbon atoms (abbreviated as aromatic emulsifier) or an emulsifier mixture comprising at least 10 wt.% of the aromatic emulsifier.

公开(公告)号：EP0629664B1

公开(公告)日：1997-12-29

申请号：EP94108932

申请日：1994-06-10

Applicant: BASF AG

Inventor： WALLON ALEXANDER DR ,  AUCHTER GERHARD DR ,  LICHT ULRIKE DR ,  HAEBERLE KARL DR ,  FUNHOFF ANGELIKA DR

IPC: C08G18/08 ,  C08G18/00 ,  C08L75/00 ,  C08L75/04 ,  C08L101/00 ,  C09D175/04 ,  C09J175/04

CPC classification number: C09D175/04 ,  C08L33/00 ,  C09J175/04

公开(公告)号：MY125776A

公开(公告)日：2006-08-30

申请号：MYPI20003689

申请日：2000-08-11

Applicant: BASF AG

Inventor： GERST MATTHIAS DR ,  AUCHTER GERHARD DR ,  SCHULER BERNHARD DR

IPC: C09J157/00 ,  C08F2/18 ,  C08F2/22 ,  C08F212/08 ,  C08F220/06

Abstract: THE INVENTION PROVIDES A PROCESS FOR PREPARING AN AQUEOUS POLYMER DISPERSION OF A COPOLYMER CP OF AT LEAST TWO DIFFERENT MONOMERS M1 AND M2 BY FREE-RADICAL AQUEOUS EMULSION POLYMERIZATION OF THE MONOMERS M IN THE PRESENCE OF AT LEAST ONE INITIATOR, AT LEAST 80 % OF THE MONOMERS M AND AT LEAST 75%OF THE INITIATOR BEING SUPPLIED CONTINUOUSLY TO THE POLYMERIZATION REACTION DURING ITS COURSE, WHICH COMPRISES CHANGING THE RATE AT WHICH THE INITIATOR IS SUPPLIED TO THE POLYMERIZATION REACTION A NUMBER OF TIMES, OR CONTINUOUSLY, DURING THE POLYMERIZATION REACTION. THE INVENTION FURTHER PROVIDES THE POLYMER DISPERSIONS OBTAINABLE BY THIS PROCESS, POLYMER POWDERS PREPARED THEREFROM, AND FOR THE USE OF THE DISPERSIONS AND/OR OF THE POLYMER POWDERS TO PREPARE PRESSURE SENSITIVE ADHESIVES.

公开(公告)号：DE59108983D1

公开(公告)日：1998-06-18

申请号：DE59108983

申请日：1991-06-15

Applicant: BASF AG

Inventor： REHMER GERD DR ,  BARWICH JUERGEN DR ,  AUCHTER GERHARD DR

IPC: C08F2/00 ,  C08F2/04 ,  C08F2/06 ,  C08F220/10 ,  C08F220/18 ,  C08L33/04 ,  C08L33/08 ,  C09J133/04 ,  C09J133/08

Abstract: Polymers of olefinically unsaturated monomers and solutions of polymers of olefinically unsaturated monomers obtainable by polymerising the olefinically unsaturated monomers in the presence of free radical-forming initiators in solution under otherwise prespecified polymerisation conditions in a process in which a solvent and/or a liquid part of one or more reaction components of the polymerisation batch is initially introduced and heated to the polymerisation temperature, and, while maintaining or initiating the polymerisation, some or all of the monomers to be polymerised are fed continuously, via at least one feed, to the initially introduced part of the polymerisation batch (which is kept in motion), in such a manner that the exit opening of the at least one feed is above the surface of the initially introduced liquid part of the polymerisation batch.

公开(公告)号：AT145926T

公开(公告)日：1996-12-15

申请号：AT91107745

申请日：1991-05-14

Applicant: BASF AG

Inventor： REHMER GERD DR ,  AUCHTER GERHARD DR ,  JAEGER HELMUT

IPC: C08F20/12 ,  C08F2/50 ,  C08F8/00 ,  C08F8/14 ,  C08F8/30 ,  C08F8/32 ,  C08F20/34 ,  C08F20/36 ,  C08F20/52 ,  C08F20/58 ,  C08F220/10 ,  C08F220/12 ,  C09J4/00 ,  C09J4/02

Abstract: Synthetic resins are obtainable by chemically bonding one or more compounds of the general formula I (* CHEMICAL STRUCTURE *) (I) where R1 is -OH, -NH2, (* CHEMICAL STRUCTURE *) -NHR3 or (* CHEMICAL STRUCTURE *) R2 is -H, -CH3 or -C2H5, R3 is -CmH2m+1, where m is from 1 to 6, R4 is -H or -CH3 and n is from 1 to 12, via the oxygen or nitrogen atom of R1 to one or more polymers A which consist of a) from 50 to 100% by weight of one or more esters of acrylic or methacrylic acid with monohydric alcohols of 1 to 18 carbon atoms or a mixture of these esters (monomers a) and b) from 0 to 50% by weight of other copolymerizable monomers (monomers b) in polymerized form, in amounts such that the synthetic resin contains from 0.01 to 1 mole of double bonds per kg of polymer A. After exposure to ultraviolet light or to electrons, these synthetic resins are suitable as contact adhesives.

公开(公告)号：DE4442684A1

公开(公告)日：1996-06-05

申请号：DE4442684

申请日：1994-11-30

Applicant: BASF AG

Inventor： REHMER GERD DR ,  AUCHTER GERHARD DR ,  JAEGER HELMUT ,  BARWICH JUERGEN DR

IPC: C09D133/06 ,  C09J133/06 ,  C08L33/06 ,  C08F218/04 ,  C08F220/18 ,  C08L31/02 ,  C09D4/00 ,  C09D131/02 ,  C09J11/06 ,  C09J131/02

Abstract: A material for adhesion to solid surfaces contains (A) copolymer(s) of (a) 65-99.9 wt.% cpds. of formula CH2=CR -CO-OR (I). R = H or 1-4C alkyl; R = 1-18C alkyl; and/or vinyl esters of formula R -CO-O-CH=CH2 (II). R = 1-12C alkyl; (b) 0-6 wt.% alpha,beta-unsatd. 3-8C mono- and/or dicarboxylic acids and/or anhydrides of 3-8C diacids, (c) 0.1-4 wt.% (meth)acrylamido-glycolic acid and (d) 0-34.9 wt.% other unsatd. comonomers, pref. with 2-10 C atoms; (B) 0.05-5 wt.% (w.r.t. A) of a metal chelate, pref. a Zr chelate, and/or an opt. polymerised metal acid ester of formula RnT(OR )z (III) or (IV): T = di- to tetra-valent metal atom, pref. a Gp. II, III, IV or V metal, esp. pref. Ti; R = 1-8C alkyl or 6-16C aryl; R , R = 1-4C alkoxy or 1-18C aliphatic residue; R = as for R /R , or 1-4C alkylamino; n = 0 or a whole no.; z = at least 1, pref. at least 2; n + z = valency of T; (C) 10-900 wt.% (w.r.t. A) organic solvent or a mixt. thereof with water; and (D) opt. fillers, tackifying resins and/or stabilisers.

公开(公告)号：DE4011914A1

公开(公告)日：1991-10-17

申请号：DE4011914

申请日：1990-04-12

Applicant: BASF AG

Inventor： FILGES ULRICH DR ,  AYDIN ORAL DR ,  AUCHTER GERHARD DR

IPC: C08F2/06 ,  C08L29/10 ,  C08L31/02 ,  C08L33/06 ,  C08L33/14

Abstract: Non-aq., moisture-cured copolymer prepns. (I) are claimed, contg. (A) 4-90 pts. wt. of a copolymer of (a1) 40-99 wt% (1-14C alkyl) (meth)acrylate(s), opt. contg. an ether gp., (a2) 1-60 wt% monomer(s) of formula CH2=CR1-X-R2-NCO (i) and (a3) 0-40 wt% other unsatd. comonomer(s) and (B) 10-96 pts. wt. of a copolymer of (b1) 70-99.9 wt% of a monomer of type (a1), or a vinyl 1-20C carboxylate and/or 3-22C vinyl ether, (b2) 0.1-20 wt% unsatd. anhydride monomer and (b3) 0-40 wt% other unsatd. comonomer; monomers (a3), (b1), (b2) and (b3) contain no acidic OH, CH, NH or SH gps.. In (i) R1 = H or Me; R2 = 1-12C hydrocarbylene, opt. contg. one or more O atoms in the chain; X = -COO- or phenylene. (I) are produced by prepg. (A) and (B) under anhydrous conditions, and polymerising (B) in an aprotic solvent. Pref. (A) and (B) both have K value 10-150 (0.01 g/ml in THF); (a1) is ethyl, n-butyl, n-hexyl and/or 2-ethylhexyl acrylate contg. 0-10 wt% MMA; (a2) has the above formula with X = -COO-, and pref. (a2) is omega-isocyanato-ethyl (meth)acrylate or omega-isocyanato-3-oxapentyl methacrylate; (b1) is a (1-14C alkyl) (meth)acrylate opt. with an ether linkage in the alkyl gp.; (b2) is maleic, itaconic and/or citraconic anhydride. USE/ADVANTAGE - (I) are useful as moisture-cured adhesives, sealing materials or coating materials (claimed). (I) have a good storage life and cure rapidly under the action of moisture to give acrylate copolymers with increased elasticity and ductility, together with good adhesive, cohesive and surface properties, good filler capacity and compatibility with pigments. (7pp Dwg.No.0/0)

公开(公告)号：DE3930097A1

公开(公告)日：1991-03-14

申请号：DE3930097

申请日：1989-09-09

Applicant: BASF AG

Inventor： REHMER GERD DR ,  AUCHTER GERHARD DR ,  BOETTCHER ANDREAS DR ,  FRANZ LOTHAR DR ,  JAEGER HELMUT

IPC: C08F2/04 ,  C08F224/00 ,  C08F226/06 ,  C08F228/06 ,  C08F246/00 ,  C09J157/10

公开(公告)号：DE3927619A1

公开(公告)日：1991-02-28

申请号：DE3927619

申请日：1989-08-22

Applicant: BASF AG

Inventor： REHMER GERD DR ,  AUCHTER GERHARD DR

IPC: C08F220/18 ,  C08F224/00 ,  C08F226/06 ,  C08F228/06 ,  C08F246/00 ,  C09D157/04 ,  C09J157/04

Abstract: The invention relates to copolymers built up from A) from 99.5 to 75 % of olefinically unsaturated monomers containing hetero atoms, B) from 0.5 to 25 % of unsaturated compounds of the formula I and C) from 0 to 20 % of further olefinically unsaturated monomers where X is O, S or NR and R is optionally substituted C2-C6-alkylene, and R is C1- to C8-alkyl or phenyl. The products according to the invention are suitable as coating and impregnation compositions and in particular as contact adhesives.

公开(公告)号：DE3861552D1

公开(公告)日：1991-02-21

申请号：DE3861552

申请日：1988-06-16

Applicant: BASF AG

Inventor： AUCHTER GERHARD DR ,  SCHWERZEL THOMAS DR ,  OSTERLOH ROLF DR ,  NEUBERT GERHARD DR ,  PFOEHLER PETER DR ,  DRUSCHKE WOLFGANG DR ,  JAEGER HELMUT

IPC: C08F2/16 ,  C08J3/07 ,  C08K5/25 ,  C08L33/04 ,  C08L33/06 ,  C09J133/04 ,  C09J133/06

Abstract: The polymer dispersions are obtainable by dispersing a mixture of… 15 - 70% by weight of a copolymer (A) comprising… (I) 1.5 - 15% by weight of copolymerisable compounds containing 3 to 10 carbon atoms and one carboxyl or carboxylic anhydride group,… (II) 65 - 98.5% by weight of C1- to C20-alkyl acrylates or methacrylates,… (III) 0 - 20% by weight of vinylaromatic compounds,… (IV) 0 - 20% by weight of copolymerisable carbonyl compounds,… (V) 0 - 10% by weight of further copolymerisable organic compounds not mentioned under (I) to (IV),… and 30 - 85% by weight of a copolymer (B) comprising… 60 - 100% by weight of monomers (II) and… 0 - 40% by weight of monomers (III) to (V),… with the proviso that the copolymers (A) and (B) together contain more than 65% by weight of alkyl (meth)acrylates (II) as synthesis component whose homopolymers have glass transition temperatures of below 0 DEG C, and that at least one of the copolymers (A) and (B) contains the monomers (IV) as synthesis component,… in water with addition of ammonia and a polyhydrazide (C). … The dispersions are used as contact adhesives and as adhesives for multilayer films.