公开(公告)号：DE10306891A1

公开(公告)日：2004-08-26

申请号：DE10306891

申请日：2003-02-18

Applicant: BASF AG

Inventor： KNOLL KONRAD ,  WALTER HANS-MICHAEL ,  DARDIN ULRIKE ,  DESBOIS PHILIPPE ,  NAEGELE PAUL

IPC: C08F297/04 ,  C08L25/06 ,  C08L53/02

Abstract: In transparent block copolymers (I) with star structure having rigid blocks S1 and S2 of vinyl-aromatic monomer differing in molecular weight and random flexible blocks (B/S)1 and (B/S)2 of vinyl-aromatic and diene monomers differing in monomer ratio, at least one arm of the star has the block sequence S1-S2-(B/S)1-(B/S)2, at least one has the block sequence S2-(B/S)1-(B/S)2 and the diene monomer fraction of (I) is 15-20 wt.%. An independent claim is also included for transparent polymer blends containing 50-99.9 wt.% block copolymer(s) (I) and 0.1-50 wt.% other vinyl-aromatic polymer(s) (II).

公开(公告)号：AU2003291978A1

公开(公告)日：2004-04-23

申请号：AU2003291978

申请日：2003-09-04

Applicant: BASF AG

Inventor： DESBOIS PHILIPPE ,  SCHWABEN HANS-DIETER ,  DARDIN ULRIKE ,  WALTER HANS-MICHAEL

IPC: C08L25/04 ,  C08F2/38 ,  C08F2/44 ,  C08F4/46 ,  C08F279/00 ,  C08F287/00 ,  C08F297/04 ,  C08L51/00 ,  C08L53/02 ,  D01F6/30 ,  C08L25/06

Abstract: An anionically polymerized tough impact polystyrene of melt/volume flow rate MVR of at least 8-20 cm3/10 minutes (as measured by EN ISO 1133 at 200 degrees C test temperature and 5 kg nominal load) is new. Independent claims are also included for: (1) a process for preparation of the tough impact polystyrene by anionic polymerization of styrene in the presence of a styrene/butadiene block copolymer, using an alkali metal organyl as anionic polymerization initiator, e.g. s-butyl lithium, and an aluminum, magnesium or zinc organyl as retarder, e.g. triisobutylaluminum (TIBA); (2) a shaped body, film, fibers or foam obtained from the tough impact polystyrene.

公开(公告)号：DE10102647A1

公开(公告)日：2002-07-25

申请号：DE10102647

申请日：2001-01-20

Applicant: BASF AG

Inventor： BUETHE INGOLF ,  WALTER HANS-MICHAEL ,  DEHNICKE KURT ,  GREINER ANDREAS ,  KRIEGER MATTHIAS ,  MAST CHRIASTIAN OLIVER ,  SCHROERS MICHAEL

IPC: B01J23/755 ,  B01J31/14 ,  B01J31/18 ,  B01J31/28 ,  C08F4/606 ,  C08F132/08 ,  C08F255/00 ,  C08F297/06 ,  C08F297/08 ,  C08F232/00

Abstract: Catalysts containing a nickel-phosphoraniminato complex and a borane or borate. Catalyst comprises: (a) a nickel-phosphoraniminato complex of formula (I); and (b) a borane or borate. (NiX(NPR3))4 (I) X = a covalently-bonded or weakly-coordinating ligand; and R = 1-20C alkyl, 6-20C aralkyl or 1-20C alkyl-phosphacyclopentanyl. Independent claims are included for: (1) a method for the polymerisation of cyclo-olefins in presence of catalyst (I); (2) polycyclo-olefins with a glass transition point (Tg) of 100 deg C or above, a weight average molecular weight of 50000-2 million and a heterogeneity (Mw/Mn) of 1.3 or less; and (3) block copolymers or graft copolymers containing a polycyclo-olefin block as above.

公开(公告)号：DE102005055819A1

公开(公告)日：2007-05-24

申请号：DE102005055819

申请日：2005-11-21

Applicant: BASF AG

Inventor： HANEFELD PHILLIP ,  BOEHM VOLKER ,  SIGL MARCUS ,  CHALLAND NINA ,  ROEPER MICHAEL ,  WALTER HANS-MICHAEL

IPC: C08F10/10 ,  C08F4/14 ,  C08F10/00 ,  C08F110/10 ,  C08F210/10

Abstract: Preparation of highly reactive isobutene homo- or copolymers with M n =from 500 to 1 000 000 by polymerizing isobutene from technical C 4 hydrocarbon streams having an isobutene content of from 1 to 90% by weight in the liquid phase in the presence of a dissolved, dispersed or supported catalyst complex, by using, as the catalyst complex, a protic acid compound I [H + ] k Y k- .L x (I) Y k- weakly coordinating k-valent anion which comprises at least one hydrocarbon moiety, L neutral solvent molecules and x>=0.

公开(公告)号：DE102005038284A1

公开(公告)日：2007-02-22

申请号：DE102005038284

申请日：2005-08-12

Applicant: BASF AG

Inventor： WALTER HANS-MICHAEL ,  HANEFELD PHILLIP ,  KUEHN FRITZ ELMAR ,  AYYAMPERUMAL SAKTHIVEL ,  HIJAZI AHMED ,  VOIT BRIGITTE ,  NARAYANAN RADHA KRISHNAN

IPC: C08F4/00

Abstract: In polymerization of monomers with ethylenically unsaturated groups in open chain structures in the molecule, the polymerization catalyst is a heterogenized metal complex (I) obtained by contacting a homogeneous metal complex (II) with a suitable support material, where (II) has a mono- to hexa-valent solvated metal cation containing a group 3-12 transition metal, lanthanide or group 2 or 13 metal, 1 or more molecules of solvent and optionally charged ligand, and weakly or non-coordinating anion. In polymerization of monomers with ethylenically unsaturated groups in open chain structures in the molecule, the polymerization catalyst is a heterogenized metal complex (I) obtained by contacting a homogeneous metal complex of formula (II) with a suitable support material: [M(L)a(Z)b]m+> m(A->) (II); M : a group 3-12 transition metal, a lanthanide or a group 2 or 13 metal; L : a solvent molecule; Z : a ligand with 1 or more charges; A->a weakly or non-coordinating anion; a : 1 or more; b : 0, 1 or more; a+b : 4-8; m : 1-6. Independent claims are included for the following: (1) heterogenized metal complexes (IA), suitable as polymerization catalysts, obtained by contacting specified homogeneous metal complexes (IIA) with a suitable support material; (2) use of (I) as catalyst in the polymerization of ethylenically unsaturated monomers; (3) highly reactive copolymers of isobutene and vinylaromatic monomer(s) produced by this process.

公开(公告)号：DE102005038283A1

公开(公告)日：2007-02-22

申请号：DE102005038283

申请日：2005-08-12

Applicant: BASF AG

Inventor： WALTER HANS-MICHAEL ,  HERRLICH-LOOS MIRJAM ,  KUEHN FRITZ ELMAR ,  ZHANG YANMEI ,  VOIT BRIGITTE ,  NARAYANAN RADHA KRISHNAN

IPC: C08F4/00

Abstract: The invention relates to a solvent-stable metal catalyst having slightly coordinating counter anions of formula I [M(L) a (Z) b ] m+ m(A - )(I), wherein M represents a transition metal of groups 3-12 of the periodic system, a lanthanide or a metal of groups 2 or 13 of the periodic system; L represents a solvent molecule; Z represents a mono or polycharged ligand; A - represents a slightly or non coordinated anion; a represents a whole number which is greater than or equal to 1; b represents a whole number which is greater than or equal to 1, whereby the total from a and b is between 4 and 8, and m represents a whole number from 1 6. The invention also relates to a method for polymerising olefinically unsaturated compounds in the presence of said catalyst and copolymers which are made of monomers comprising isobutene and at least one vinylaromatic compound which is obtained according to said inventive method.

公开(公告)号：DE10316266A1

公开(公告)日：2004-10-28

申请号：DE10316266

申请日：2003-04-08

Applicant: BASF AG

Inventor： DESBOIS PHILIPPE ,  GRAMMATIS ZAFIRIOS ,  LOTH WOLFGANG ,  WALTER HANS-MICHAEL ,  KOCH JUERGEN ,  SUHM JUERGEN ,  MITULLA KONRAD ,  SCHWITTAY CLAUDIUS

IPC: C08F12/04 ,  C08F36/04 ,  C08F297/04 ,  C08F2/44 ,  C08F2/04 ,  C08F212/08 ,  C08F236/02 ,  C08F297/00 ,  C08J5/00

Abstract: Production of homo- or co-polymers from styrene and/or diene monomers by anionic polymerization followed by degassing and addition of a mineral oil additive is such that at least a part of the mineral oil is first added after the degassing step.

公开(公告)号：AU2002356675A1

公开(公告)日：2003-06-10

申请号：AU2002356675

申请日：2002-11-19

Applicant: BASF AG

Inventor： WALTER HANS-MICHAEL ,  KNOLL KONRAD ,  DESBOIS PHILIPPE

IPC: C08F279/02 ,  C08F297/04 ,  C08L25/04 ,  C08L53/02

Abstract: The present invention relates to mixtures comprising linear block copolymers made from vinylaromatic monomers and from dienes of the structure (I) S 1 -B 1 -S 2 and (II) S 3 -B 2 -S 4 , where S 1 is a block made from vinylaromatic monomers with number-average molar mass M n in the range from 40,000 to 100,000 g/mol, each of S 2 , S 3 and S 4 is a block made from vinylaromatic monomers with number-average molar mass M n in the range from 5,000 to 20,000 g/mol, each of B 1 and B 2 is a block made from dienes or a copolymer block made from dienes and from vinylaromatic monomers with numberaverage molar mass M n in the range from 15,000 to 40,000 g/mol, and the ratio of the block copolymers (I)/(II) is in the range from 0.6 to 2.