公开(公告)号：JP2004292453A

公开(公告)日：2004-10-21

申请号：JP2004093344

申请日：2004-03-26

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフト

Inventor： SIGL MARCUS ,  MUELLER ULRICH DR

IPC: B01J37/08 ,  B01J29/70 ,  B01J29/86 ,  B01J29/90 ,  B01J37/14 ,  B01J38/12 ,  C07B61/00 ,  C07C209/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/05 ,  C07C211/06 ,  C07C211/07 ,  C07C211/20 ,  C07C211/21

CPC classification number: B01J38/12 ,  B01J29/7007 ,  B01J29/86 ,  B01J29/90 ,  B01J37/14 ,  B01J2229/186 ,  B01J2229/37 ,  B01J2229/42 ,  C07C209/60 ,  Y02P20/584 ,  C07C211/03

Abstract: PROBLEM TO BE SOLVED: To provide a method for increasing hydroamination activity of a calcined zeolite catalyst which is not deactivated by hydroamination, and to provide a method for producing an alkylamine by reacting an olefin with ammonia, a primary amine or a secondary amine under a hydroamination condition on the calcined zeolite catalyst having the increased activity. SOLUTION: This method for producing the alkylamine comprises reacting the olefin with the ammonia, the primary amine or the secondary amine under the hydroamination condition on the calcined zeolite catalyst, wherein the calcined zeolite catalyst is thermally activated within a period after start of the reaction at a temperature of 100 to 550°C in a flow of gas comprising air, nitrogen, the other inert gas or a mixture thereof. COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 解决问题的方法：提供一种提高未经水解而不失活的煅烧沸石催化剂的水分活性的方法，提供一种通过使烯烃与氨，伯胺或仲胺反应生成烷基胺的方法 胺在活化沸石催化剂上的水解条件下进行。 解决方案：用于制备烷基胺的方法包括在煅烧沸石催化剂上的水解条件下使烯烃与氨，伯胺或仲胺反应，其中煅烧沸石催化剂在开始之后的一段时间内被热活化 在包含空气，氮气，其它惰性气体或其混合物的气体流中，在100至550℃的温度下进行反应。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：WO2004102488A3

公开(公告)日：2005-03-03

申请号：PCT/EP2004004818

申请日：2004-05-06

Applicant: BASF AG ,  SIGL MARCUS ,  STEINBRENNER ULRICH

Inventor： SIGL MARCUS ,  STEINBRENNER ULRICH

IPC: B01J23/04 ,  C07C5/25 ,  C07C11/08

CPC classification number: B01J23/04 ,  C07C5/2506 ,  C07C5/2512 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/04 ,  C07C11/08

Abstract: The invention relates to a method for producing a C4-C12 olefin (olefin A) from another C4-C12 olefin (olefin B), olefin (A) and olefin (B) differing in terms of the position of the double bond. According to said method, a gaseous mixture containing olefin (B) and between 0.01 and 10 wt. %, in relation to the total quantity of hydrocarbon compounds in said mixture, of a compound having a dipole moment of between 0.5 and 5 Debyes (compound P) is brought into contact with a basic catalyst at a temperature of between 200 and 700 DEG C.

Abstract translation: 一种制备一个C4至C12烯烃（烯烃A）从其他C 4至C 12烯烃（烯烃B），其中烯烃（A）和烯烃（B）在双键的位置不同，并且得到的处理 气态混合物包含烯烃（B）和0.01至10重量％，基于烃化合物的总量在该混合物中，具有0.5偶极矩为5德拜（化合物P）与在碱性催化剂的化合物 带来的在触点200至700℃的温度。

公开(公告)号：WO2006089956A3

公开(公告)日：2007-03-08

申请号：PCT/EP2006060275

申请日：2006-02-24

Applicant: BASF AG ,  SIGL MARCUS ,  SCHUBERT MARKUS ,  STEPHAN JUERGEN ,  POPLOW FRANK

Inventor： SIGL MARCUS ,  SCHUBERT MARKUS ,  STEPHAN JUERGEN ,  POPLOW FRANK

IPC: C07C6/04 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09

CPC classification number: C07C11/02 ,  C07C6/04 ,  C07C2521/04 ,  C07C2523/30 ,  C07C2523/36 ,  Y02P30/464

Abstract: The invention relates to a method for producing a product flow substantially consisting of ethene (C 2

Abstract translation: 一种生产基本上由乙烯材料流的（流C _{2 方法}

公开(公告)号：EA009785B1

公开(公告)日：2008-04-28

申请号：EA200601232

申请日：2004-12-30

Applicant: BASF AG

Inventor： JOHANN THORSTEN ,  SCHINDLER GOTZ-PETER ,  BRODHAGEN ANDREAS ,  CRONE SVEN ,  BENFER REGINA ,  SIGL MARCUS ,  DUDA MARK

IPC: C07C5/333 ,  C07C5/48 ,  C07C11/167

Abstract: Изобретениекасаетсяспособаполучениябутадиенаизн-бутана, включающегоследующиестадии: A) подготовкаисходногогазовогопотокаа, содержащегон-бутан; B) подачасодержащегон-бутанзагрузочногогазовогопотокаа поменьшеймерев первуюзонудегидрированияи неокислительноекаталитическоедегидрированиен-бутана, причемполучаютпотокгазообразныхпродуктов b, содержащийн-бутан, 1-бутен, 2-бутен, бутадиен, водород, низкокипящиепримесии, вслучаенеобходимости, водянойпар; C) подачапотокагазообразныхпродуктов b неокислительногокаталитическогодегидрированияи содержащегокислородгазапоменьшеймеревовторуюзонудегидрированияи окислительноедегидрированиен-бутана, 1-бутенаи 2-бутена, причемполучаютпотокгазообразныхпродуктовс, содержащийн-бутан, 2-бутен, бутадиен, водород, низкокипящиепримесии водянойпар, содержаниебутадиенав которомвыше, чемв потокегазообразныхпродуктов b; D) отделениеводорода, низкокипящихпримесейи водяногопара, причемполучаютпотокС-газообразныхпродуктов d, которыйв основномсостоитизн-бутана, 2-бутенаи бутадиена; E) разделениепотокаС-газообразныхпродуктов d насостоящийв основномизн-бутанаи 2-бутанапоток e1 инасостоящийв основномизбутадиенапотокцелевогопродуктае2 посредствомэкстракционнойдистилляции; F) подачасостоящегов основномизн-бутанаи 2-бутенапотокае1 исодержащего 1-бутени 2-бутенциркуляционногопотока g взонудистилляциии разделениенабогатый 1-бутеномпотокцелевогопродукта f1, содержащий 2-бутени н-бутанрециркуляционныйпоток f2 исодержащий 2-бутенпоток f3 ирециркуляциярециркуляционногопотока f2 напервуюзонудегидрирования; G) подачасодержащего 2-бутенпотока f3 взону

公开(公告)号：DE102005055818A1

公开(公告)日：2007-05-24

申请号：DE102005055818

申请日：2005-11-21

Applicant: BASF AG

Inventor： HANEFELD PHILLIP ,  SIGL MARCUS ,  BOEHM VOLKER ,  ROEPER MICHAEL ,  WALTER HANS-MICHAEL ,  KROSSING INGO

IPC: C08F10/10 ,  C08F4/14 ,  C08F10/00 ,  C08F110/10 ,  C08F210/10

Abstract: Preparation of highly reactive isobutene homo- or copolymers having Mn=from 500 to 1 000 000 by polymerizing isobutene in the liquid phase in the presence of a dissolved, dispersed or supported metal-containing catalyst complex by using, as the catalyst complex, a compound I Zn+[MXa(OR)b]n-.Lx (I) M metal atom from the group of boron, aluminum, gallium, indium and thallium, R each independently aliphatic, heterocyclic or aromatic hydrocarbon radicals which have in each case from 1 to 18 carbon atoms and may comprise fluorine atoms, or silyl groups comprising C1 to C18 hydrocarbon radicals, X halogen atoms, Z proton (n=1), optionally substituted ammonium (n=1) or n-valent metal cation, L neutral solvent molecules, a integer from 0 to 3, b integer from 1 to 4, where a+b=4, and x>=0.

公开(公告)号：DE10361823A1

公开(公告)日：2005-08-11

申请号：DE10361823

申请日：2003-12-30

Applicant: BASF AG

Inventor： JOHANN THORSTEN ,  SCHINDLER GOETZ-PETER ,  BRODHAGEN ANDREAS ,  CRONE SVEN ,  BENFER REGINA ,  SIGL MARCUS ,  DUDA MARK

IPC: C07C5/333 ,  C07C5/48 ,  C07C11/167 ,  C07C7/10 ,  C07C11/08 ,  C07C11/16

Abstract: The disclosure involves a process for the preparation of butadiene and 1-butene. The process includes at least a first catalytic dehydrogenation of n-butane to obtain a gas stream which is followed by at least a second oxidative dehydrogenation to form a second gas stream. The second gas stream is then subjected to distillation and isomeration steps to obtain butadiene and 1-butene.

公开(公告)号：DE10226120A1

公开(公告)日：2003-12-24

申请号：DE10226120

申请日：2002-06-12

Applicant: BASF AG

Inventor： SIGL MARCUS ,  MILLER CHRISTIAN ,  DOBLER WALTER ,  HAAKE MATHIAS

IPC: B01J8/00 ,  B01J8/02 ,  B01J8/12 ,  B01J19/24 ,  B01J21/04 ,  B01J23/10 ,  B01J23/92 ,  B01J35/02 ,  C07C45/72 ,  C07C45/74 ,  C07C49/203

Abstract: The supported catalyst has one or more metal oxides as active components on a carrier for aldol condensation. The catalyst carrier is gamma -aluminum oxide. The active components include one or more oxides of rare earth metals. The concentration of the active components is 5-12 wt.% of the catalyst carrier weight. The active component is preferably yttrium oxide or praseodymium oxide. The condensation column packing (1) is composed of packing sheets (2) with straight kinks (5) forming angled kink surfaces (6). Catalyst particles (4) fill the space (3) between neighboring sheets.

公开(公告)号：DE10154781A1

公开(公告)日：2003-05-22

申请号：DE10154781

申请日：2001-11-08

Applicant: BASF AG

Inventor： GROSCH GEORG HEINRICH ,  HEIDEMANN THOMAS ,  SIGL MARCUS ,  WUERZ HARALD ,  CORELL RAINER

IPC: C07C67/26 ,  C09D4/02 ,  B01J27/26 ,  C07C69/54

Abstract: Special multi-metal cyanide compounds in which at least one of the metals is iron(II) or iron(III) (other than the usual alkali or alkaline earth metal or quaternary ammonium ion) are used as catalysts in a method for the production of hydroxyalkyl esters by reacting carboxylic acids with alkylene oxides. A method for the production of hydroxyalkyl esters of carboxylic acids involves reacting carboxylic acids with alkylene oxides in presence of multi-metal cyanide catalysts of formula (I); M zM a(M (CN)b(A)c)d.fM gXn.mM pYq.h(H2O).eL.kP (I); M = metal ion(s) selected from Zn , Fe , Fe , Co , Ni , Mn , Co , Sn , Pb , Mo , Mo , Al , V , V , Sr , W , W , Cr , Cr , Cd , Hg , Pd , Pt , V , Mg , Ca , Ba and Cu ; M = metal ion(s) selected from Fe , Fe , Co , Co , Mn , Mn , V , V , Cr , Cr , Rh , Ru and Ir , where M and M may be the same or different and at least one of these is Fe or Fe ; M = metal ion(s) selected from Li , Na , K , Rb , Cs , Mg , Ca , Sr and Ba or ammonium ions of formula R R R R N ; R -R = 1-6C hydrocarbyl A, X, Y = halide, hydroxide, sulfate, carbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate, nitrate, nitrosyl, hydrogen sulfate, phosphate, dihydrogen phosphate, hydrogen phosphate or hydrogen carbonate ions; L = a water-miscible ligand selected from alcohols, aldehydes, ketones, polyethers, esters, polyesters, polycarbonate, ureas, amides, prim., sec. and tert. amines, ligands with pyridine nitrogen, nitriles, sulfides, phosphides, phosphites, phosphanes, phosphonates and phosphates; e, f, k, h, m = 0 or more (fraction or integer); P = an organic additive; a, b, c, d, g, n, p, q, z = numbers compatible with the electroneutrality of (I), where c or z or c and z may be zero.

公开(公告)号：CA2670935A1

公开(公告)日：2008-06-05

申请号：CA2670935

申请日：2007-11-29

Applicant: BASF AG

Inventor： SIGL MARCUS ,  HEIMANN FRANK ,  POPLOW FRANK ,  VOLLAND MARTIN ,  BITTERLICH STEFAN ,  PAPP RAINER ,  MACKEWITZ THOMAS ,  CRONE SVEN ,  HEIDEMANN THOMAS ,  UEBLER CHRISTOPH ,  PACIELLO ROCCO ,  WIEBELHAUS DAG

IPC: C07C5/25 ,  C07C11/08 ,  C07C45/50 ,  C07C47/02

Abstract: The present invention relates to a method for the production of hydroform ylation products from olefins having at least four carbon atoms. A high amou nt of the linear Ci-olefins with terminal double bonds that are present in t he inlet comprising olefins, and also of the linear Ci-olefins having intern al double bonds are converted to hydroformylation products. The invention fu rther relates to a method for the production of 2-propylheptanol, comprising said hydroformylation method.

公开(公告)号：MX2007010286A

公开(公告)日：2008-04-10

申请号：MX2007010286

申请日：2006-02-24

Applicant: BASF AG

Inventor： SIGL MARCUS ,  STEPHAN JURGEN ,  SCHUBERT MARKUS ,  POPLOW FRANK

IPC: C07C6/04 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09

Abstract: La invencion se relaciona con un metodo para producir un flujo de producto que consiste sustancialmente de eteno (flujo de C2=), un flujo de producto que consiste substancialmente de propeno (flujo C3=), un flujo de producto que consiste substancialmente de isobuteno y, opcionalmente de otras olefinas que tiene 4 atomos de carbono (flujo C4=) y un flujo de producto que consiste substancialmente de 2-metil-2-buteno y, opcionalmente de 2-buteno (flujo C5=), y opcionalmente otro flujo de producto que contiene otros hidrocarburos (flujo Cx), que consiste opcionalmente de varios flujos parciales individuales. El metodo inventivo comprende un paso de metatesis que consiste en llevar un flujo de hidrocarburo de C4 que contiene cuando menos 15% en peso de 2-buteno, por lo menos 5% en peso de isobuteno y cuando menos 5% en peso de 1-buteno (flujo de alimentacion) a contacto con eteno en presencia de un catalizador de metatesis usual, el flujo de hidrocarburo asi formado se separa en los flujos C2=, C3=, C4=, y opcionalmente Cx y el flujo C5= se recicla parcial o totalmente en la etapa de metatesis.