公开(公告)号：CA2419368A1

公开(公告)日：2003-02-10

申请号：CA2419368

申请日：2001-08-10

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  JUNG STEFAN ,  KARL JORN ,  ROPER MICHAEL ,  WERNER HELMUT ,  WOLF JUSTIN

IPC: B01J31/22 ,  C07B61/00 ,  C07C211/09 ,  C07C217/08 ,  C07C323/25 ,  C07F5/02 ,  C07F9/50 ,  C07F9/54 ,  C07F15/00 ,  C07F17/00 ,  C07F17/02

Abstract: In ruthenium complexes of general formula A or B, X1, X2 independently represent single or multidentate anionic ligands; R, R', R'' independently represent hydrogen or optionally substituted C1-20-alkyl, C6-20-aryl or C7-2 0- alkylaryl radicals; and L1, L2 independently represent neutral electron dono r ligands which are co-ordinated at the metallic centre as carboids, and which can be linked by a bridge W having 0 to 20 carbon atoms. Said bridge can be a constituent of a cyclic or aromatic group and can be split by heteroatoms, with the exception of C,N-heterocyclic five-membered ring systems.

公开(公告)号：ES2172201T3

公开(公告)日：2002-09-16

申请号：ES98946393

申请日：1998-08-20

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  STUER WOLFRAM ,  WERNER HELMUT

IPC: B01J31/00 ,  B01J31/22 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80 ,  C08F32/04 ,  C08G61/08

Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.

公开(公告)号：AU2160502A

公开(公告)日：2002-04-02

申请号：AU2160502

申请日：2001-09-18

Applicant: BASF AG

Inventor： STUER WOLFRAM ,  ROPER MICHAEL ,  JUNG STEFAN ,  WOLF JUSTIN ,  WERNER HELMUT

IPC: B01J23/46 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07F15/00

公开(公告)号：DK1005476T3

公开(公告)日：2002-03-25

申请号：DK98946393

申请日：1998-08-20

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  STUER WOLFRAM ,  WERNER HELMUT

IPC: B01J31/00 ,  B01J31/22 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80 ,  C08F32/04 ,  C08G61/08

Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.

公开(公告)号：AU8767701A

公开(公告)日：2002-02-25

申请号：AU8767701

申请日：2001-08-10

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  KARL JORN ,  ROPER MICHAEL ,  JUNG STEFAN ,  WOLF JUSTIN ,  WERNER HELMUT

IPC: B01J31/22 ,  C07B61/00 ,  C07C211/09 ,  C07C217/08 ,  C07C323/25 ,  C07F5/02 ,  C07F9/50 ,  C07F9/54 ,  C07F15/00 ,  C07F17/00 ,  C07F17/02

Abstract: In the ruthenium complexes of the general formula A or B, X 1 >and X 2>, independently of one another, are monodentate or polydentate anionic ligands, R, R' and R'', independently of one another, are hydrogen or substituted or unsubstituted C 1-20 -alkyl, C 6-20 -aryl or C 7-20 -alkylaryl radicals, and L 1 >and L 2>, independently of one another, are neutral electron donor ligands which are coordinated as carbenoids to the metal center and may be linked via a bridge W having 0 to 20 carbon atoms, which may be part of a cyclic or aromatic group and may be interrupted by heteroatoms, with the exception of C,N-heterocyclic five-membered ring systems.

公开(公告)号：DE19854869A1

公开(公告)日：2000-05-31

申请号：DE19854869

申请日：1998-11-27

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  WERNER HELMUT

IPC: B01J31/24 ,  C07F15/00

Abstract: The invention relates to a method of producing ruthenium complexes of general formula (I): RuX2(=CH-CH2R)L L , wherein X is an anionic ligand, R is hydrogen or an optionally substituted C1-20 alkyl radical or C6-20 aryl radical, and L and L independently are neutral electron-donor ligands. Said ruthenium complexes are produced by a) reacting RuX3 with a diene in a solvent on the basis of one or several aliphatic secondary alcohols in the presence of a reducing adjuvant, reacting said mixture with L and L in the presence of at least one coordinating weak base and hydrogen and without isolating any intermediates, b) reacting the mixture with compounds of general formula (II): R-C=CH, wherein R has the meaning indicated above, in the presence of a soluble chloride source.

公开(公告)号：AU3930199A

公开(公告)日：1999-11-29

申请号：AU3930199

申请日：1999-05-03

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  STUER WOLFRAM ,  WERNER HELMUT

IPC: B01J31/22 ,  B01J31/00 ,  C07B61/00 ,  C07C6/04 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80

公开(公告)号：DE59901120D1

公开(公告)日：2002-05-08

申请号：DE59901120

申请日：1999-05-03

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  STUER WOLFRAM ,  WERNER HELMUT

IPC: B01J31/22 ,  B01J31/00 ,  C07B61/00 ,  C07C6/04 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80

公开(公告)号：DE59802654D1

公开(公告)日：2002-02-21

申请号：DE59802654

申请日：1998-08-20

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  STUER WOLFRAM ,  WERNER HELMUT

IPC: B01J31/00 ,  B01J31/22 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80 ,  C08F32/04 ,  C08G61/08

Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.

公开(公告)号：ID29912A

公开(公告)日：2001-10-25

申请号：ID20011140

申请日：1999-11-23

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  WERNER HELMUT

IPC: B01J31/24 ,  C07F15/00

Abstract: The invention relates to a method of producing ruthenium complexes of general formula (I): RuX2(=CH-CH2R)L L , wherein X is an anionic ligand, R is hydrogen or an optionally substituted C1-20 alkyl radical or C6-20 aryl radical, and L and L independently are neutral electron-donor ligands. Said ruthenium complexes are produced by a) reacting RuX3 with a diene in a solvent on the basis of one or several aliphatic secondary alcohols in the presence of a reducing adjuvant, reacting said mixture with L and L in the presence of at least one coordinating weak base and hydrogen and without isolating any intermediates, b) reacting the mixture with compounds of general formula (II): R-C=CH, wherein R has the meaning indicated above, in the presence of a soluble chloride source.