公开(公告)号：DE10033955A1

公开(公告)日：2001-03-08

申请号：DE10033955

申请日：2000-07-13

Applicant: BASF AG

Inventor： WOLF JUSTIN ,  FRIES GUIDO ,  WERNER HELMUT

IPC: C07F9/50 ,  C07F9/74 ,  C07F9/66

Abstract: Symmetrical or asymmetrical bis-phosphino, bis-arsino or phosphino-arsino compounds are produced by reacting a dihalo-organic compound with two benzyl-diorganyl-phosphine or -arsine compounds which may or may not be identical and then hydrogenating the product. A process for the production of compounds of formula (V) involves reaction of a compound of formula (I) with a dihalo compound (II) and a compound of formula (III) followed by hydrogenation. Hal-X-Hal (II) R R E-X-ER R (V) E = phosphorus or arsenic; X = a bridging group with 1-10 atoms between the atoms of E; R , R , R , R = 1-20C alkyl, 3-10C cycloalkyl, aryl or heteroaryl with up to 4 condensed rings, or 7-20C aralkyl (all optionally substituted), or R , R and/or R , R together may form 2-20C alkylene, arylene or heteroarylene groups with up to 4 condensed rings, or 7-20C aralkylene (all optionally substituted; R -R = H, hydroxyl, halogen, acyl, CHO, 1-12C alkyl or 6-12C aryl, with the proviso that R and R are not both OH; Hal = F, Cl, Br or I; R -R = as defined for R -R .

公开(公告)号：CA2301713A1

公开(公告)日：1999-03-04

申请号：CA2301713

申请日：1998-08-20

Applicant: BASF AG

Inventor： STUER WOLFRAM ,  WOLF JUSTIN ,  SCHWAB PETER ,  WERNER HELMUT ,  SCHULZ MICHAEL

IPC: B01J31/00 ,  B01J31/22 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80 ,  C08F32/04 ,  C08G61/08

Abstract: The invention relates to ruthenium complexes of the general formulas (I) RuX2(=CH-CH2R)L1L2 or (IV) RuXY(=CH-CH2R)L1L2, where X, Y are anionic ligands, R is hydrogen or a possibly substituted C1-C20 alkyl rest or C6-C20 aryl rest, and L1 and L2 independently of each other are neutral electron donor ligands. Said ruthenium complexes are produced by (a) reacting RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen, and (b) by reacting the resulting product with compounds of the general formula (II) RCCH, where R has the meaning given above, possibly in the presence of water and possibly after isolation of the intermediate stage with HY, (HL1)Y or (HL2)Y.

公开(公告)号：DE10039389A1

公开(公告)日：2002-02-21

申请号：DE10039389

申请日：2000-08-11

Applicant: BASF AG

Inventor： STUEER WOLFRAM ,  KARL JOERN ,  ROEPER MICHAEL ,  JUNG STEFAN ,  WOLF JUSTIN ,  WERNER HELMUT

IPC: B01J31/22 ,  C07B61/00 ,  C07C211/09 ,  C07C217/08 ,  C07C323/25 ,  C07F5/02 ,  C07F9/50 ,  C07F9/54 ,  C07F15/00 ,  C07F17/00 ,  C07F17/02 ,  B01J31/12 ,  C07C6/00 ,  C07B37/00

Abstract: In ruthenium complexes of general formula A or B, X , X independently represent single or multidentate anionic ligands; R, R', R'' independently represent hydrogen or optionally substituted C1-20-alkyl, C6-20-aryl or C7-20-alkylaryl radicals; and L , L independently represent neutral electron donor ligands which are co-ordinated at the metallic centre as carboids, and which can be linked by a bridge W having 0 to 20 carbon atoms. Said bridge can be a constituent of a cyclic or aromatic group and can be split by heteroatoms, with the exception of C,N-heterocyclic five-membered ring systems.

公开(公告)号：AU5285699A

公开(公告)日：2000-02-28

申请号：AU5285699

申请日：1999-07-20

Applicant: BASF AG

Inventor： BARTH THOMAS ,  RIEBER NORBERT ,  BREUER KLAUS ,  SCHAFER MARTIN ,  WOLF JUSTIN ,  WERNER HELMUT

IPC: C07C67/30 ,  C07B61/00 ,  C07C51/353 ,  C07C67/347 ,  C07C69/602 ,  C07C57/10 ,  C07C69/587

公开(公告)号：DE19820652A1

公开(公告)日：1999-11-11

申请号：DE19820652

申请日：1998-05-08

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  STUER WOLFRAM ,  WERNER HELMUT

IPC: B01J31/22 ,  B01J31/00 ,  C07B61/00 ,  C07C6/04 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80

Abstract: Cationic ruthenium complexes are of specified formula. Cationic ruthenium complexes are of formula (A) and (B): X = anion which is weakly or not coordinated to the metal center; Y = anionic ligand; R and R' = H or optionally substituted 1-20C alkyl, 6-20C aryl or 7-20C alkylaryl; and L1, L2, L3 and L4 = neutral electron donor ligands. An Independent claim is also included for a process for producing the cationic ruthenium complexes comprising reacting a neutral vinylidene complex of formula: RuY(R')(CCHR)L1L2 with R X X = anion which is weakly or not coordinated to the metal center or complex anion; and R = alkyl, aryl, akylaryl or complex cation of the LH type or reacting a compound of the type RuYY'(CHR)L1L2 where, Y = Y'; X = anion which is weakly or not coordinated to the metal center or complex anion; and R = alkyl, aryl, akylaryl or complex cation of the LH type. R X = CF3SO3H, F3CCO2H, HclO4, HBF4, HPF6, HSbF6 or (PhNMe2H)(B(C6F5)4).

公开(公告)号：MXPA03001161A

公开(公告)日：2003-10-14

申请号：MXPA03001161

申请日：2001-08-10

Applicant: BASF AG

Inventor： WOLF JUSTIN

IPC: B01J31/22 ,  C07B61/00 ,  C07C211/09 ,  C07C217/08 ,  C07C323/25 ,  C07F5/02 ,  C07F9/50 ,  C07F9/54 ,  C07F15/00 ,  C07F17/00 ,  C07F17/02

公开(公告)号：DE19933743A1

公开(公告)日：2001-01-25

申请号：DE19933743

申请日：1999-07-19

Applicant: BASF AG

Inventor： WOLF JUSTIN ,  FRIES GUIDO ,  WERNER HELMUT

IPC: C07F9/50 ,  C07F9/74 ,  C07F9/547 ,  C07F9/66

Abstract: A process for the production of bisphosphino- and bisarsino-compounds comprises reaction of an aryl phosphorous or arsenic containing compound with a dihalogenated compound. A process for the production of compounds of formula (5) comprises reaction of a compound of formula (1) with a dihalo compound of formula (2) and a compound of formula (3) followed by hydrogenation. Hal - X - Hal (2) R R - E - X - E - R - R (5) E = P, As; X = a divalent bridging group whereby are separated by 1-10 atoms; R , R , R , R =1-20C alkyl, 3-10C (cycloalkyl, aryl or heteroaryl having up to 4 condensed aromatic rings or 7-20C aralkyl, optionally substituted or R , R and/or R , R together are 2-20C alkylene, arylene or heteroarylene with up to 4 aromatic rings, 7-20C aralalkylene, optionally substituted; R , R R , R , R , R = H, OH, halogen, acyl, CHO, 1-12C alkyl, 6-12C aryl whereby R and R are not both OH; Hal = F, Cl, Br or I.

公开(公告)号：AU1653400A

公开(公告)日：2000-06-19

申请号：AU1653400

申请日：1999-11-23

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  WERNER HELMUT

IPC: B01J31/24 ,  C07F15/00

Abstract: The invention relates to a method of producing ruthenium complexes of general formula (I): RuX2(=CH-CH2R)L L , wherein X is an anionic ligand, R is hydrogen or an optionally substituted C1-20 alkyl radical or C6-20 aryl radical, and L and L independently are neutral electron-donor ligands. Said ruthenium complexes are produced by a) reacting RuX3 with a diene in a solvent on the basis of one or several aliphatic secondary alcohols in the presence of a reducing adjuvant, reacting said mixture with L and L in the presence of at least one coordinating weak base and hydrogen and without isolating any intermediates, b) reacting the mixture with compounds of general formula (II): R-C=CH, wherein R has the meaning indicated above, in the presence of a soluble chloride source.

公开(公告)号：CA2352377A1

公开(公告)日：2000-06-08

申请号：CA2352377

申请日：1999-11-23

Applicant: BASF AG

Inventor： SCHWAB PETER ,  WOLF JUSTIN ,  WERNER HELMUT ,  SCHULZ MICHAEL

IPC: B01J31/24 ,  C07F15/00

Abstract: The invention relates to a method of producing ruthenium complexes of genera l formula (I): RuX2(=CH-CH2R)L1L2, wherein X is an anionic ligand, R is hydrog en or an optionally substituted C1-20 alkyl radical or C6-20 aryl radical, and L1 and L2 independently are neutral electron-donor ligands. Said ruthenium complexes are produced by a) reacting RuX3 with a diene in a solvent on the basis of one or several aliphatic secondary alcohols in the presence of a reducing adjuvant, reacting said mixture with L1 and L2 in the presence of a t least one coordinating weak base and hydrogen and without isolating any intermediates, b) reacting the mixture with compounds of general formula (II ): R-C~CH, wherein R has the meaning indicated above, in the presence of a soluble chloride source.

公开(公告)号：AU9345198A

公开(公告)日：1999-03-16

申请号：AU9345198

申请日：1998-08-20

Applicant: BASF AG

Inventor： SCHWAB PETER ,  SCHULZ MICHAEL ,  WOLF JUSTIN ,  STUER WOLFRAM ,  WERNER HELMUT

IPC: B01J31/00 ,  B01J31/22 ,  C07F9/50 ,  C07F15/00 ,  C08F4/80 ,  C08F32/04 ,  C08G61/08

Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.