OLIGOMERIC DIARYLBUTADIENE
    11.
    发明专利

    公开(公告)号:JP2000198762A

    公开(公告)日:2000-07-18

    申请号:JP35042399

    申请日:1999-12-09

    Applicant: BASF AG

    Abstract: PROBLEM TO BE SOLVED: To obtain an oligomeric diarylbutadiene carboxylic ester having a specified oligomeric structure and high absorption in UV-A range, optically stable, soluble in oil or water according to its substrate group and applicable to preparing a light-shielding agent useful for cosmetics and pharmaceuticals. SOLUTION: The oligomeric 4,4-diarylbutadiene carboxylic ester of formula I [R1 and R2 are each H, an aliphatic group or the like; R3 is an aliphatic group, a cycloaliphatic group or the like; Y is O or a group of formula II (R4 is H, an aliphatic group or the like); (m) is 2-10; (n) is 1-3; X is a (m)-valent polyol group having 2-10 hydroxyl group] is obtained by Knoevenagel condensation of (m) mol aldehyde of formula III with an oligomeric (substituted) acetate of formula IV in an organic polar solvent (e.g. dimethylformamide) preferably at 40-150 deg.C using a catalyst (e.g. ammonium acetate).

    COSMETIC OR MEDICINAL PREPARATION AND USE THEREOF

    公开(公告)号:JP2000143473A

    公开(公告)日:2000-05-23

    申请号:JP31255199

    申请日:1999-11-02

    Applicant: BASF AG

    Abstract: PROBLEM TO BE SOLVED: To obtain a cosmetic or a medicinal preparation exhibiting a high light-protecting factor as much as possible with a very low concentration of a UV-absorbing agent by containing a specific triazine derivative and zinc oxide in a specific ratio. SOLUTION: This cosmetic or medicinal preparation contains (A) 0.1-10 wt.% one or more kinds of 1,3,5-triazine derivatives of formula I R1 to R3 are each a (substituted) 1-20C alkyl or a (hetero)aryl; X is O or NR4 [R4 is H, a (substituted) 1-20C alkyl or a (hetero)aryl]} and (B) 0.1-15 wt.% zinc oxide. Preferably, it contains 1-8 wt.% compound of the formula I in which R1 to R3 are each a 4-8C alkyl, X is O or NR4 (R4 is H or a 4-8C alkyl) and 0.1-10 wt.% component B, and more preferably contains 2-6 wt.% compound of the formula II of 2,4,6-trianilino-p-(carbo-2'-ethyl-hexyl-1'-oxy)-1,3,5-triazine and 2-8 wt.% component B. Preferably it has a light protecting factor of >14.

    Use of 4,4-diarylbutadienes as photostable UV filters in cosmetics

    公开(公告)号:DE19755649A1

    公开(公告)日:1999-06-17

    申请号:DE19755649

    申请日:1997-12-15

    Applicant: BASF AG

    Abstract: Use of 4,4-diarylbutadienes (I) as photostable UV filters in cosmetics for protecting the skin and hair from the sun's rays. The use of 4,4-diarylbutadiene derivatives of formula (I) as a cosmetic preparation is new: Where the diene system is Z,Z; Z,E; E,Z or E,E; R1, R2 = H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, 1-12C alkoxy, 1-20C alkoxycarbonyl, 1-12C alkylamino, 1-12C dialkylamino, aryl, heteroaryl (optionally substituted by carboxylate, sulfonate or ammonium residues); R3 = H, COOR5, COR5, CONR5,R6, CN, O=S(R5)=O, O=S(OR5)=O, R7OP(OR8)=O, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 7-10C bicycloalkyl, 3-10C cycloalkenyl, 7-10C bicycloalkenyl, aryl or heteroaryl (optionally substituted); R4 = COOR6, COR6, CONR5,R6, CN, O=S(R6)=O, O=S(OR6)=O, R7OP(OR8)=O, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 7-10C bicycloalkyl, 3-10C cycloalkenyl, 7-10C bicycloalkenyl, aryl or heteroaryl (optionally substituted); R5-R8 = H, 1-20C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 7-10C bicycloalkyl, 3-10C cycloalkenyl, 7-10C bicycloalkenyl, aryl or heteroaryl (optionally substituted); and n = 1-3; where R3-R8 may in each case together with the C atoms to which they are bonded, form a 5- or 6-membered ring which may be further fused.

    16.
    发明专利
    未知

    公开(公告)号:DE4211062A1

    公开(公告)日:1993-10-07

    申请号:DE4211062

    申请日:1992-04-03

    Applicant: BASF AG

    Abstract: Polyester resins on the basis of hydroxyl groups-containing prepolymers from olefinically unsaturated monomers are prepared by (1) polymerizing a mixture of (a) 60 to 90% by weight styrol or a styrol derivate having the general formula (I), in which R , R and R stand for hydrogen, methyl or ethyl and n equals 1 or 2, or a C2-C10-olefin with one or two conjugated double bonds, or a mixture thereof; (b) 0 to 40% by weight C1-C12-alkylester of acrylic or methacrylic acid, acryl- or methacryl-nitril, acryl-or methacrylamide, which may be substituted at the amide-nitrogen by one or two C1-C4-alkyl groups, maleic anhydride or maleic acid imide, which may be substituted at the imide-nitrogen by a C1-C4-alkyl group, or a mixture thereof; (c) 0 to 20% by weight one or several hydroxyl group-containing acrylic or methacrylic acid derivates; and (d) 0 to 2% by weight one or several olefinically poly-unsaturated monomers; to obtain a prepolymer A, into which the hydroxyl groups are inserted by means of hydroxyl groups-containing regulators when the monomer component (c) is missing and by a mixture of (A) 5 to (95% by weight prepolymer A; (B) 0 to 95% by weight another low molecular or high molecular polyol, a polyester or a polyamid, or a mixture thereof; and (C) 5 to 70% by weight one or several aliphatic or aromatic dicarboxylic acids C or their C1-C4-alkylesters. Carboxylic acids or their C1-C4-alkylesters having more than two carboxyl groups per molecule, monocarboxylic acids or their C1-C4 alkylesters, hydroxymonocarboxylic acids or their C1-C4-alkylesters or mixtures thereof, as well as waxes may also be present during polycondensation. These polyester resins are suitable as binders for electrophotographic toners and for the receiving layers in the thermodiffusion printing method.

    17.
    发明专利
    未知

    公开(公告)号:AT339181T

    公开(公告)日:2006-10-15

    申请号:AT00110272

    申请日:2000-05-22

    Applicant: BASF AG

    Abstract: Use of new and known bicyclic and tricyclic enamines as UV filters in cosmetic and pharmaceutical preparations is new. Also new is their use for the protection of plastics. Use of bicyclic and tricyclic enamines as UV filters in cosmetic and pharmaceutical preparations is new. R and R = CN; alkylcarbonyl; alkoxycarbonyl; aryloxycarbonyl; or optionally substituted aminocarbonyl; R = H; 1-20C alkyl; 3-20C cycloalkyl; or -CH2-CH2-SO3 M ; M = cation; X = -O-; -S-; or -N(R )-; Z' = group of formula (ii) or (iii): R = H; alkyl, cycloalkyl, alkoxy, cycloalkoxy, alkoxycarbonyl, alkyl-NH-CO-, (alkyl)2-NH-CO-, alkyl-NH- or (alkyl)2N- (each with up to 20C); CN; NH2; or SO3 M and more than 1 R can be present. Independent claims are also included for: (1) the use of compounds (I) as light screening agents for the protection of plastics; (2) (I; Z' = (iii); and (3) (I; Z' = (ii); R4 = R40; R1, R2 = R10, R20 respectively) R and R = CN or 2-10C alkoxycarbonyl optionally substituted with -(CH2)n-SO3 M ; R = H; CH3; or -(CH2)n-SO3 M ; R = H; 1-8C alkyl; 1-8C alkoxy; or -SO3 M ; n = 2 or 3; M = H or HN(R )(R )(R ) ; R -R = H lower alkyl optionally substituted with OH; or a metal cation; but at least one -(CH2)n-SO3 M or -SO3 M must be present.

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