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    PREPARATION OF 5-HYDROXYMETHYLFURFURAL (HMF) FROM SACCHARIDE SOLUTIONS IN THE PRESENCE OF A SOLVENT HAVING A BOILING POINT GREATER THAN 60ºC AND LESS THAN 200ºC (AT STANDARD PRESSURE, CALLED LOW BOILER FOR SHORT)
    12.
    发明申请
    PREPARATION OF 5-HYDROXYMETHYLFURFURAL (HMF) FROM SACCHARIDE SOLUTIONS IN THE PRESENCE OF A SOLVENT HAVING A BOILING POINT GREATER THAN 60ºC AND LESS THAN 200ºC (AT STANDARD PRESSURE, CALLED LOW BOILER FOR SHORT) 有权
    在具有超过60ºC且小于200ºC的锅炉点的溶剂存在下，从SACCHARIDE溶液中制备5-羟基甲基丙烯（HMF）（标准压力，低压锅炉）

    公开(公告)号：US20130150597A1

    公开(公告)日：2013-06-13

    申请号：US13712056

    申请日：2012-12-12

    Applicant: BASF SE

    Inventor： René Backes ,  Benoit Blank ,  Alois Kindler ,  Carmen Feldner

    IPC: C07D307/46

    CPC classification number: C07D307/46 ,  Y02P20/127

    Abstract: A process for preparing 5-hydroxymethylfurfural (HMF), which comprises a) feeding solutions (hereinafter called starting solution) comprising one or more saccharides and an organic solvent having a boiling point greater than 200° C. (at standard pressure) (called high boiler for short) and water,  and a solvent having a boiling point greater than 60° C. and less than 200° C. (at standard pressure, called low boiler for short) to a reaction vessel, b) effecting a conversion of hexose to HMF in the reaction vessel in the presence of water vapor with simultaneous distillative removal of the HMF and c) obtaining, as the distillate, an aqueous, HMF-comprising solution (hereinafter called distillate).

    Abstract translation: 一种制备5-羟甲基糠醛（HMF）的方法，其包括a）将包含一种或多种糖和沸点大于200℃的有机溶剂（在标准压力下）（称为高浓度）的进料溶液（以下称为起始溶液） 锅炉）和水，以及沸点大于60℃且小于200℃（在标准压力下简称为低锅炉）的溶剂，b）进行己糖转化 在水蒸汽存在下在反应容器中的HMF，同时蒸馏除去HMF，和c）获得作为馏出物的含水HMF溶液（以下称为馏出物）。

    PROCESS FOR THE SYNTHESIS OF L-IDITOL AND RECYCLING OF THE CATALYST
    13.
    发明申请
    PROCESS FOR THE SYNTHESIS OF L-IDITOL AND RECYCLING OF THE CATALYST 有权

    公开(公告)号：US20250019328A1

    公开(公告)日：2025-01-16

    申请号：US18576314

    申请日：2022-05-10

    Applicant: BASF SE

    Inventor： Thomas Schaub ,  Steffen Mader ,  Alois Kindler ,  A.Stephen K. Hashmi ,  Daniel James Tindall

    IPC: C07C29/143 ,  B01J23/46 ,  B01J31/24 ,  B01J38/60 ,  C07C29/86

    Abstract: A process for the preparation of L-lditol comprising at least the process steps: i) a L-Sorbose comprising composition is subjected to hydrogenation with hydrogen in the presence of a hydrophobic stereoselective ruthenium catalyst complex in a homogeneous solution, wherein the ruthenium catalyst complex comprises at least one chiral ligand containing at least two phosphorus atom, which are capable of coordinating to the ruthenium yielding in a composition comprising L-lditol as the main product; ii) separation of the reaction products produced in step i) from the ruthenium catalyst complex; iii) reactivating the separated ruthenium catalyst complex of step ii) by adding a chloride source and reusing the reactivated ruthenium catalyst complex in step i).

    Production of furfural from xylose
    17.
    发明授权
    Production of furfural from xylose 有权

    公开(公告)号：US09944614B2

    公开(公告)日：2018-04-17

    申请号：US15103336

    申请日：2014-12-10

    Applicant: BASF SE

    Inventor： Stefan Koch ,  Alois Kindler

    IPC: C07D307/50

    CPC classification number: C07D307/50

    Abstract: Described is a method for producing furfural from one or more substances selected from the group consisting of xylose, oligosaccharides comprising xylose units and polysaccha-rides comprising xylose units.

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