公开(公告)号：WO2014122152A1

公开(公告)日：2014-08-14

申请号：PCT/EP2014/052205

申请日：2014-02-05

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  MÜLLER, Ulrich ,  LÜTZEL, Hans-Jürgen ,  UHL, Georg ,  BAYER, Robert ,  VOGELSANG, Regina ,  TELES, Joaquim Henrique ,  RIEDEL, Dominic ,  URBANCZYK, Daniel ,  WEGERLE, Ulrike

IPC: C01B37/00 ,  B01J29/89

CPC classification number: B01J37/0045 ,  B01J29/7038 ,  B01J29/89 ,  C01B39/085

Abstract: A process for the preparation of a titanium-containing zeolitic material having an MWW framework structure, the process comprising(i)providing a zeolitic material having an MWW framework structure comprising SiO 2 and B 2 O 3 , (ii)incorporating titanium into the zeolitic material provided in (i) comprising(ii.1) preparing an aqueous synthesis mixture containing the zeolitic material provided in (i), an MWW template compound and a titanium source, (ii.2) hydrothermally synthesizing a titanium-containing zeolitic material having an MWW framework structure from the aqueous synthesis mixture prepared in (ii.1), obtaining a mother liquor comprising the titanium-containing zeolitic material having an MWW framework structure;(iii)spray-drying the mother liquor obtained from (ii.2) comprising the titanium-containing zeolitic material having an MWW framework structure.

Abstract translation: 一种制备具有MWW骨架结构的含钛沸石材料的方法，该方法包括（i）提供具有包含SiO 2和B 2 O 3的MWW骨架结构的沸石材料，（ii）将钛掺入提供于（ i）包括（ii.1）制备含有（i）中提供的沸石材料的水性合成混合物，MWW模板化合物和钛源，（ii.2）水热合成具有MWW骨架结构的含钛沸石材料 从（ii.1）中制备的水性合成混合物得到包含具有MWW骨架结构的含钛沸石材料的母液;（iii）喷雾干燥由（ii.2）得到的母液， 含有MWW骨架结构的沸石材料。

公开(公告)号：WO2014060982A2

公开(公告)日：2014-04-24

申请号：PCT/IB2013/059417

申请日：2013-10-17

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED ,  TOKYO INSTITUTE OF TECHNOLOGY

Inventor： YILMAZ, Bilge ,  MÜLLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  TATSUMI, Takashi ,  XIAO, Feng-Shou ,  GIES, Hermann ,  IMAI, Hiroyuki

CPC classification number: C07C1/044 ,  B01J29/76 ,  B01J29/89 ,  B01J35/1019 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J2229/186 ,  C10G25/003 ,  C10G25/03

Abstract: The present invention relates to a process for the production of a pillared silicate comprising: (i) providing a layered silicate; (ii)interlayer expanding the layered silicate provided in step (i) comprising a step of treating the layered silicate with one or more swelling agents; (iii)treating the interlayer expanded silicate obtained in step (ii) with one or more hydrolyzable silicon containing compounds; (iv)treating the interlayer expanded compound obtained in step (iii) with an aqueous solution to obtain a pillared silicate; (v)removing at least a portion of the one or more swelling agents from the pillared silicate obtained in step (iv); (vi) impregnating the pillared silicate obtained in step (v) with one or more elements selected from the group consisting of Fe, Ru, Ir, and combinations of two or more thereof, as well as to a pillared silicate optionally obtainable from said process and its use, in particular in a process for the production of one or more olefins according to the invention.

Abstract translation: 本发明涉及一种生产柱状硅酸盐的方法，包括：（i）提供层状硅酸盐; （ii）层间膨胀步骤（i）中提供的层状硅酸盐，包括用一种或多种溶胀剂处理层状硅酸盐的步骤; （iii）用一种或多种可水解含硅化合物处理在步骤（ii）中获得的层间发泡硅酸盐; （iv）用水溶液处理步骤（iii）中得到的层间发泡化合物，得到柱状硅酸盐; （v）从步骤（iv）中获得的柱状硅酸盐中去除至少一部分一种或多种溶胀剂; （vi）将步骤（v）中获得的柱状硅酸盐浸入一种或多种选自Fe，Ru，Ir的元素，以及两种或更多种的组合，以及任选地可从所述方法获得的柱状硅酸盐 及其用途，特别是用于生产根据本发明的一种或多种烯烃的方法。

公开(公告)号：WO2014060259A1

公开(公告)日：2014-04-24

申请号：PCT/EP2013/071040

申请日：2013-10-09

Applicant: BASF SE

Inventor： PARVULESCU, Andrei-Nicolae ,  YANG, Jeff ,  MAURER, Stefan ,  GAAB, Manuela ,  SEIDEL, Karsten ,  GERLACH, Olga ,  MÜLLER, Ulrich

IPC: C01B39/02 ,  B01J21/00

CPC classification number: C01B39/026 ,  B01J29/7007 ,  B01J35/1014 ,  B01J2229/38 ,  C01B39/46

Abstract: A process for the post-treatment of a zeolitic material having a BEA framework structure, the process comprising (i) providing a zeolitic material having a BEA framework structure, wherein the framework structure of the zeolitic material comprises X 2 O 3 and YO 2 , wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X 2 O 3 : YO 2 is greater than 0.02 : 1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X 2 O 3 : YO 2 of at most 0.02 : 1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75 °C.

Abstract translation: 一种用于后处理具有BEA骨架结构的沸石材料的方法，该方法包括（i）提供具有BEA骨架结构的沸石材料，其中沸石材料的骨架结构包含X 2 O 3和YO 2，其中Y是 四价元素，X是三价元素，其中X 2 O 3 :YO 2的摩尔比大于0.02:1; （ii）用液体溶剂系统处理（i）中提供的沸石材料，从而获得摩尔比X2O3：YO2至多0.02:1的沸石材料，并至少部分地将沸石材料与液体溶剂系统分离; （iii）用pH为5.5〜8，温度为至少75℃的液态水系统处理由（ⅱ）得到的沸石材料。

公开(公告)号：WO2014057382A1

公开(公告)日：2014-04-17

申请号：PCT/IB2013/058907

申请日：2013-09-27

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： WEICKERT, Mathias ,  MARX, Stefan ,  MÜLLER, Ulrich ,  RENZE, Peter

IPC: F17C11/00 ,  F17C1/12

CPC classification number: F17C11/007 ,  F17C11/00

Abstract: Method of charging a sorption store with a gas, wherein the sorption store comprises a closed container (10) and a feed device which has a passage (21) through the container wall, through which the gas can flow into the container, and the container has at least two parallel, channel-shaped subchambers (30,31,32,33) which are located in its interior and are each at least partly filled with an adsorption medium (40) and whose channel walls are coolable, wherein, in a first step, gas is fed in in such an amount that a pressure in the store of at least 30% of a predetermined final pressure is reached as quickly as possible and in a second step, the amount of gas fed in is subsequently varied in such a way that the course of the pressure in the store approximates the adsorption kinetics of the adsorption medium (40) until the predetermined final pressure in the store is reached after a predetermined period of time.

Abstract translation: 一种用气体填充吸附存储器的方法，其中所述吸附储存器包括密封容器（10）和进料装置，所述进料装置具有通过所述容器壁的通道（21），所述气体可以通过所述通道流入所述容器中，并且所述容器 具有位于其内部并且至少部分地填充有吸附介质（40）并且其通道壁可冷却的至少两个平行的通道形子室（30,31,32,33），其中，在 在第一步骤中，气体的供给量使得储存器中的压力尽可能快地达到预定最终压力的至少30％，并且在第二步骤中，供给的气体的量随后在其中变化 在存储器中的预定最终压力在预定时间段之后达到在商店内的压力过程接近吸附介质（40）的吸附动力学的方式。

公开(公告)号：WO2012042410A1

公开(公告)日：2012-04-05

申请号：PCT/IB2011/053892

申请日：2011-09-06

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED ,  LEUNG, Emi ,  MÜLLER, Ulrich ,  TRUKHAN, Natalia ,  MATTENHEIMER, Hendrik ,  COX, Gerhard ,  BLEI, Stefan

Inventor： LEUNG, Emi ,  MÜLLER, Ulrich ,  TRUKHAN, Natalia ,  MATTENHEIMER, Hendrik ,  COX, Gerhard ,  BLEI, Stefan

IPC: C07F5/06 ,  B01J20/22

CPC classification number: C07F5/069

Abstract: The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20°C to 100°C at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.

Abstract translation: 本发明涉及一种制备多孔金属 - 有机骨架的方法，其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物，其中所述至少一种金属离子基于铝离子，并且所述至少一种 至少二齿有机化合物是基于富马酸，在至少一种碱的存在下，在至少一种碱的存在下，使至少一种铝化合物与至少富马酸在碱性水性介质中反应，温度范围为20℃至 100℃，绝对压力不大于2巴，时间为0.2-4小时。

公开(公告)号：WO2011006990A1

公开(公告)日：2011-01-20

申请号：PCT/EP2010/060310

申请日：2010-07-16

Applicant: BASF SE ,  THE DOW CHEMICAL COMPANY ,  TELES, Joaquim, Henrique ,  GÖBBEL, Hans-Georg ,  BAßLER, Peter ,  KAMPE, Philip ,  GUMLICH, Kai ,  BARTOSCH, Christian ,  MÜLLER, Ulrich ,  JACUBINAS, Richard ,  TRUKHAN, Natalia ,  WEIDENBACH, Meinolf ,  COGSWELL, Martin

Inventor： TELES, Joaquim, Henrique ,  GÖBBEL, Hans-Georg ,  BAßLER, Peter ,  KAMPE, Philip ,  GUMLICH, Kai ,  BARTOSCH, Christian ,  MÜLLER, Ulrich ,  JACUBINAS, Richard ,  TRUKHAN, Natalia ,  WEIDENBACH, Meinolf ,  COGSWELL, Martin

IPC: C07D301/12 ,  B01D17/00

CPC classification number: C07D301/12 ,  B01D17/0208 ,  B01D17/047 ,  Y02P20/582

Abstract: A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile : water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene : propane of 7:3; (iii) subjecting S2 to a temperature of 92 °C at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase 12 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile : water in L2 is less than 1; (iv) separating L1 from L2.

Abstract translation: 一种从水中分离乙腈的方法，包括（i）提供基于S1的总重量，乙腈和水的至少95重量％的流S1，其中乙腈：水的重量比大于1; （ii）将基于流P的总重量的至少95重量％C 3的流P加入到S1中，以获得混合物流S2，将任选地与丙烷混合的丙烯以最小重量比的丙烯 ：丙烷7：3; （iii）使S2达到至多92℃的温度和至少10巴的压力，得到基本上由C3，乙腈和水组成的第一液相L1和基本上由水和 乙腈，其中乙腈：水中L2的重量比小于1; （iv）将L1与L2分离。

公开(公告)号：WO2010106105A2

公开(公告)日：2010-09-23

申请号：PCT/EP2010/053467

申请日：2010-03-17

Applicant: BASF SE ,  LEUNG, Emi ,  MÜLLER, Ulrich ,  SANDLER, Jan Kurt Walter ,  SKUPIN, Gabriel ,  YAMAMOTO, Motonori ,  VAN DER NET, Antje

Inventor： LEUNG, Emi ,  MÜLLER, Ulrich ,  SANDLER, Jan Kurt Walter ,  SKUPIN, Gabriel ,  YAMAMOTO, Motonori ,  VAN DER NET, Antje

IPC: B65D65/46 ,  C08K3/08

CPC classification number: B65D65/466 ,  B65D81/267 ,  C08J5/12 ,  C08J2367/02 ,  Y02A40/961 ,  Y02W90/13

Abstract: Die vorliegende Erfindung betrifft ein biologisch abbaubares Material in Form einer Folie oder eines Films, wobei das Material ein Polymer enthält, wobei das Polymer mindestens ein poröses metallorganisches Gerüstmaterial enthält und das mindestens eine poröse metallorganische Gerüstmaterial mindestens eine an mindestens ein Metallion koordinativ gebundene, mindestens zweizähnige organische Verbindung enthält. Die Erfindung betrifft weiterhin Lebensmittelverpackungen enthaltend ein solches Material sowie dessen Verwendung zur Verpackung von Lebensmitteln und die Verwendung eines porösen metallorganischen Gerüstmaterials bei der Lebensmittelverpackung zum Absorbieren von Ethen.

Abstract translation:

本发明涉及在片材或膜，其中所述材料是聚合物形式的生物可降解的材料含有＆AUML; LT，其中所述聚合物是由POR＆OUML至少; SES有机金属GER导航用途stmaterial包含HOLDS和 至少一种多孔有机金属聚集体含有至少一种与至少一种金属离子配位的至少两种有机化合物。 本发明进一步涉及含有这种材料的食品包装及其用于包装食品的用途以及在食品包装中使用多孔有机金属聚集体以吸收乙烯

公开(公告)号：WO2010100191A2

公开(公告)日：2010-09-10

申请号：PCT/EP2010/052695

申请日：2010-03-03

Applicant: BASF SE ,  Tokyo Institute of Technology ,  YILMAZ, Bilge ,  MÜLLER, Ulrich ,  XIAO, Feng-Shou ,  GIES, Hermann ,  TATSUMI, Takashi ,  DE VOS, Dirk ,  BAO, Xinhe ,  ZHANG, Weiping

Inventor： YILMAZ, Bilge ,  MÜLLER, Ulrich ,  XIAO, Feng-Shou ,  GIES, Hermann ,  TATSUMI, Takashi ,  DE VOS, Dirk ,  BAO, Xinhe ,  ZHANG, Weiping

CPC classification number: C01B37/005 ,  C01B32/05 ,  C01B37/02 ,  C01B39/026 ,  C01B39/46 ,  C01B39/48 ,  C04B35/16 ,  C04B2235/3201 ,  C04B2235/3222 ,  C04B2235/3427 ,  C04B2235/5409

Abstract: The present invention relates to a process for the preparation of a silicate compound, comprising (1) providing at least one layered silicate; and (2) mixing said layered silicate with water and at least one silicon containing compound according to formula R 4-m Si[-(SiR 2 ) n -R] m wherein at least one residue R is a leaving group and none of the residues R contains Si; m is 0, 1, 2, 3, or 4; and n is an integer greater than or equal to 0.

Abstract translation: 本发明涉及一种制备硅酸盐化合物的方法，包括（1）提供至少一种层状硅酸盐; 和（2）将所述层状硅酸盐与水和至少一种根据式R 4-m Si [ - （SiR 2）n -R] m的含硅化合物混合，其中至少一个残基R是离去基团，并且残基R都不含有Si; m为0,1,2,3或4; 并且n是大于或等于0的整数。

公开(公告)号：WO2010010050A1

公开(公告)日：2010-01-28

申请号：PCT/EP2009/059252

申请日：2009-07-17

Applicant: BASF SE ,  SCHUBERT, Markus ,  RICHTER, Ingo ,  MÜLLER, Ulrich ,  POPLOW, Frank ,  DOLAN, William ,  KIENER, Christoph

Inventor： SCHUBERT, Markus ,  RICHTER, Ingo ,  MÜLLER, Ulrich ,  POPLOW, Frank ,  DOLAN, William ,  KIENER, Christoph

IPC: C07C7/12

CPC classification number: C07C7/12 ,  C07C11/06

Abstract: Die vorliegende Erfindung betrifft Verfahren zur technischen Gewinnung von Propen aus einem zumindest Propen und Propan enthaltenden Gasstrom, den Schritt enthaltend - In Kontakt bringen des Gasstromes mit einem Adsorbens enthaltend ein poröses metallorganisches Gerüstmaterial enthaltend mindestens eine an mindestens ein Metallion koordinativ gebundene mindestens zweizähnige organische Verbindung, wobei das Adsorbens mit Propan beladen wird und der Gasstrom dadurch einen erhöhten Propenanteil aufweist, wobei die mindestens zweizähnige organische Verbindung ein Imidazolat ist, das unsubstituiert ist oder einen oder mehrere Substituenten unabhängig voneinander ausgewählt aus der Gruppe bestehend aus Halogen, C 1-6 Alkyl, Phenyl, NH 2 , NH(C 1-6 Alkyl), N(C 1-6 Alkyl) 2 , OH, O-Phenyl und O-C 1-6 Alkyl aufweist. Weiterhin betrifft die vorliegende Erfindung die Verwendung eines solchen porösen metallorganischen Gerüstmaterials zur technischen Gewinnung von Propen aus einem zumindest Propen und Propan enthaltenden Gasstrom durch Propanabreicherung des Gasstromes.

Abstract translation: 本发明涉及一种用于丙烯的由至少丙烯和含丙烷的气体流，该方法包括步骤工业分离方法 - 所述气流的接触与至少一种至少双齿有机化合物配位的至少一种金属的吸附剂，其包括多孔金属有机骨架，其包括带， 其中所述吸附剂负载有丙烷，从而所述气体流具有增加的丙烯，其中所述至少二齿有机化合物是咪唑，其是未取代或一个或多个取代基选自卤素的独立选择的，C 1-6烷基，苯基 ，NH 2，NH（C 1-6烷基），N（C 1-6烷基）2，具有OH，O-苯基和O- C 1-6烷基。 此外，本发明涉及使用这样的多孔金属 - 有机骨架材料的丙烯的来自至少丙烯和含丙烷的气流通过Propanabreicherung气流工业隔离。

公开(公告)号：WO2009007267A1

公开(公告)日：2009-01-15

申请号：PCT/EP2008/058379

申请日：2008-06-30

Applicant: BASF SE ,  SCHUBERT, Markus ,  MÜLLER, Ulrich ,  KIENER, Christoph ,  RICHTER, Ingo ,  WILLIAM, Dolan ,  POPLOW, Frank

Inventor： SCHUBERT, Markus ,  MÜLLER, Ulrich ,  KIENER, Christoph ,  RICHTER, Ingo ,  WILLIAM, Dolan ,  POPLOW, Frank

IPC: C07C7/135 ,  C07C7/12

CPC classification number: C07C7/12 ,  B01J20/22 ,  B01J20/226 ,  B01J2220/56 ,  C07C7/135 ,  C10G25/003 ,  C07C9/00

Abstract: The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of - contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

Abstract translation: 本发明涉及从含有非支链烃和非支链烃的至少一种支链异构体的流体混合物中分离至少一种未分支的C 4 -C 20烃的方法，其包括以下步骤：将流体混合物与 吸附剂，其包含多孔金属有机骨架材料，该材料包含与至少一种金属离子配位结合的至少一种至少二齿有机化合物，以获得非支化烃被吸附，其中至少一种至少二齿有机化合物是单环， 衍生自选自吡咯，α-吡啶酮和γ-吡啶酮的至少一种杂环的双环或多环系统，并且具有至少两个环氮并且是未取代的或带有一个或多个独立地选自以下的取代基： 的卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，Ophenyl和OCi-6-alk 其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自卤素，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH， 苯基和OC 1-6烷基。 本发明还涉及所述多孔金属 - 有机骨架材料在从其支化异构体中分离未分支烃的方法中的用途。