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    14.
    发明专利
    未知

    公开(公告)号：DK1836146T3

    公开(公告)日：2009-10-19

    申请号：DK06700188

    申请日：2006-01-04

    Applicant: BASF SE

    Inventor： CRONE SVEN ,  MACHHAMMER OTTO ,  SCHINDLER GOETZ-PETER ,  BORGMEIER FRIEDER

    IPC: C07C5/327 ,  C07C7/04 ,  C07C7/11

    Abstract: A process for preparing propene from propane, comprising the steps: A) a feed gas stream a comprising propane is provided; B) the fed gas stream a comprising propane, if appropriate steam and, if appropriate, an oxygenous gas stream are fed into a dehydrogenation zone and propane is subjected to a dehydrogenation to propene to obtain a product gas stream b comprising propane, propene, methane, ethane, ethene, carbon monoxide, carbon dioxide, steam, if appropriate hydrogen and, if appropriate, oxygen; C) product gas stream b is cooled, if appropriate condensed and steam is removed by condensation to obtain a steam-depleted product gas stream c; D) product gas stream c is contacted in a first absorption zone with a selective, inert absorbent which selectively absorbs propene to obtain an absorbent stream d1 laden substantially with propene and a gas stream d2 comprising propane, methane, ethane, ethene, carbon monoxide, carbon dioxide and hydrogen; E) if appropriate, the absorbent stream d1 is decompressed to a lower pressure in a first desorption zone to obtain an absorbent stream e1 laden substantially with propene and a gas stream e2 comprising propene, and gas stream e2 is recycled into the first absorption zone, F) from the absorbent stream d1 or e1 laden substantially with propene, in at least one second desorption zone, by decompression, heating and/or stripping the absorbent stream d1 or e1, a gas stream f1 comprising propene is released and the selective absorbent is recovered.

    15.
    发明专利
    未知

    公开(公告)号：DE50213396D1

    公开(公告)日：2009-05-07

    申请号：DE50213396

    申请日：2002-10-14

    Applicant: BASF SE

    Inventor： WALSDORFF CHRISTIAN ,  SCHINDLER GOETZ-PETER ,  MACHHAMMER OTTO ,  HARTH KLAUS

    IPC: C07C5/48 ,  C07B61/00 ,  C07C5/327 ,  C07C5/333 ,  C07C11/02

    Abstract: C 2 -C 30 -alkanes are dehydrogenated in a process in which (i) ethylbenzene is dehydrogenated to styrene in a first part process to give a hydrogen-containing offgas stream, and (ii) one or more C 2 -C 30 -alkanes are dehydrogenated in the presence of a heterogeneous catalyst in one or more reaction zones in a second part process to give the corresponding olefins, with a hydrogen-containing gas stream being mixed into the reaction gas mixture of the dehydrogenation in at least one reaction zone, wherein at least part of the hydrogen-containing offgas stream obtained in the dehydrogenation of ethylbenzene is mixed into the reaction gas mixture of the alkane dehydrogenation.

    16.
    发明专利
    未知

    公开(公告)号：DE502004007163D1

    公开(公告)日：2008-06-26

    申请号：DE502004007163

    申请日：2004-07-06

    Applicant: BASF SE

    Inventor： DUDA MARK ,  MACHHAMMER OTTO ,  WECK ALEXANDER

    IPC: C07C51/215

    Abstract: Maleic anhydride production by gas-phase oxidation of n-butane with oxygen-containing gases on a heterogeneous vanadium-, phosphorus- and oxygen-containing (VPO) catalyst at 350-500[deg]C with recycling of unconverted n-butane is such that (a) the stream entering the reactor has n-butane and O 2 concentrations of 0.5-1.5 and 5-21 volume % respectively; (b) pressure at the inlet is 0.4-2 MPa abs.; and (c) 40-100% of the n-butane is converted. Maleic anhydride (MA) production by gas- phase oxidation of n-butane with oxygen-containing gases on a heterogeneous vanadium-, phosphorus- and oxygen-containing (VPO) catalyst at 350-500[deg]C with MA separation by forming a gas stream containing unconverted n-butane and water and recycling part of the n-butane to the reactor unit is such that (a) the stream entering the reactor has n-butane and oxygen concentrations of 0.5-1.5 and 5-21 volume % respectively; (b) the pressure at the inlet is 0.4-2 MPa abs.; and (c) 40-100% of the n-butane is converted.

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