6.
    发明专利
    未知

    公开(公告)号:AT499336T

    公开(公告)日:2011-03-15

    申请号:AT05849467

    申请日:2005-12-07

    Applicant: BASF SE

    Abstract: A process for preparing butadiene, comprising nonoxidatively dehydrogenating n-butane from a stream (a) in a first dehydrogenation zone to obtain stream (b) comprising 1-butene and 2-butene; oxidatively dehydrogenating the 1-butene and 2-butene of (b) in the presence of an oxygenous gas in a second dehydrogenation zone to obtain stream (c) comprising n-butane, butadiene, hydrogen, carbon dioxide, and steam; compressing and cooling (c) to obtain stream (d2) comprising n-butane, butadiene, hydrogen, carbon dioxide, and steam; extractively distilling (d2) into stream (e1) comprising butadiene and stream (e2) comprising n-butane, hydrogen, carbon dioxide, and steam; compressing and cooling (e2) to obtain stream (f1) comprising n-butane and water and stream (f2) comprising n-butane, hydrogen, and carbon dioxide; cooling (f2) to obtain stream (g1) comprising n-butane and stream (g2) comprising carbon dioxide and hydrogen; phase separating water from (f1) to obtain stream (h1) comprising n-butane; and recycling (h1) into the first dehydrogenation zone.

    PROCESS FOR PURIFYING ALKANESULFONIC ACIDS

    公开(公告)号:CA3004795A1

    公开(公告)日:2017-05-18

    申请号:CA3004795

    申请日:2016-11-08

    Applicant: BASF SE

    Abstract: The invention relates to a method for purifying alkanesulfonic acids, having the following steps: (a) distilling a melt which contains raw alkanesulfonic acid (1) in order to completely or partly separate low-boiling constituents, wherein the low-boiling constituents are drawn at the head of a distillation column (3) or of a single-stage evaporation device, and a material flow (7) containing alkanesulfonic acid, high-boiling constituents, and residual low-boiling constituents is removed at the bottom of the distillation column (3) or of the single-stage evaporation device, (b) supplying the flow (7) containing alkanesulfonic acid, high-boiling constituents, and residual low-boiling constituents as a discharge melt to a melt crystallization process (9), in which crystals of the alkanesulfonic acid, of hydrates of the alkanesulfonic acid, or of a mixture of both are formed in the mother liquor in a suspended manner, (c) carrying out a solid/liquid separation in order to separate the crystals from the mother liquor, and (d) optionally washing the crystals in order to remove mother liquor adhering to the crystals.

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