公开(公告)号：JP2011098981A

公开(公告)日：2011-05-19

申请号：JP2011024977

申请日：2011-02-08

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： MACHHAMMER OTTO ,  SCHINDLER GOETZ-PETER ,  HARTH KLAUS ,  ZEHNER PETER

IPC: B01J23/62 ,  C07C5/333 ,  B01J8/02 ,  B01J19/26 ,  B01J27/199 ,  C07B61/00 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09 ,  C07C45/33 ,  C07C45/35

CPC classification number: B01J19/26 ,  B01J8/025 ,  B01J8/0278 ,  B01J23/002 ,  B01J27/199 ,  B01J2523/00 ,  C07C45/33 ,  C07C45/35 ,  Y02P20/582 ,  C07C47/22 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/3706 ,  B01J2523/41 ,  B01J2523/43 ,  B01J2523/48 ,  B01J2523/828

Abstract: PROBLEM TO BE SOLVED: To provide a continuous heterogeneously catalyzed partial dehydrogenation of a hydrocarbon in the gas phase and in the presence of molecular oxygen, in which a part of a product gas is recirculated to a reaction zone, and a reactor for carrying out such a process. SOLUTION: In the process, a reaction gas containing at least one hydrocarbon to be dehydrogenated is supplied to the reaction zone; the reaction gas is passed in the reaction zone through at least one fixed catalyst bed, wherein the reaction gas is subjected to catalytic dehydrogenation to produce molecular hydrogen and at least one partial dehydrogenated hydrocarbon; the reaction gas, before and/or after entering the reaction zone, is added with a gas containing at least one molecular oxygen-containing gas; the molecular oxygen partially oxidizes the molecular hydrogen contained in the reaction gas in the reaction zone to form water steam; a gas product containing the molecular hydrogen, water steam, at least one dehydrogenated hydrocarbon, and at least one hydrocarbon to be dehydrogenated is withdrawn from the reaction zone; at least one hydrocarbon to be dehydrogenated in the gas phase is partially dehydrogenated by a continuous heterogeneous catalyst. In the partial dehydrogenation method using the continuous heterogeneous catalyst, the reaction gas withdrawn from the reaction zone is divided into two parts being the same in composition, one of which is recycled into reaction zone as a circulating gas. COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 待解决的问题：提供在气相中和在存在分子氧的情况下烃的连续不均匀催化的部分脱氢，其中一部分产物气体再循环到反应区，以及用于 进行这样一个过程。 解决方案：在该方法中，将含有至少一种待脱氢烃的反应气体供入反应区; 反应气体通过至少一个固定催化剂床在反应区中通过，其中反应气体进行催化脱氢以产生分子氢和至少一种部分脱氢烃; 反应气体在进入反应区之前和/或之后加入含有至少一种含分子氧的气体的气体; 分子氧部分地氧化反应区中反应气体中所含的分子氢，形成水蒸气; 从反应区中取出含有分子氢，水蒸气，至少一个脱氢烃和至少一种待脱氢烃的气体产物; 在气相中要脱氢的至少一种烃被连续的多相催化剂部分脱氢。 在使用连续多相催化剂的部分脱氢方法中，将从反应区抽出的反应气体分成两部分组成相同，其中一部分作为循环气体再循环到反应区中。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2014040414A

公开(公告)日：2014-03-06

申请号：JP2013160791

申请日：2013-08-01

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： HECHLER CLAUS ,  RUPPEL WILHELM DR ,  SCHINDLER GOETZ-PETER ,  HORSTMANN CATHARINA ,  HANS-JUERGEN BASSLER ,  DIETERLE MARTIN ,  KLAPPERT KARL-HEINRICH ,  MULLER-ENGEL KLAUS JOACHIM

IPC: C07C5/48 ,  B01J8/02 ,  B01J19/02 ,  C07B61/00 ,  C07C11/06

CPC classification number: C07C5/333 ,  B01J8/067 ,  B01J19/02 ,  B01J2219/0236 ,  C07C51/215 ,  C22C30/00 ,  C22C38/40 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/02 ,  C07C57/04

Abstract: PROBLEM TO BE SOLVED: To provide a reaction vessel having high resistance to a thermal cycle (high resistance to long time embrittlement, carburization, metal dusting) and capable of reducing undesired catalysis effects, and to provide a method for a serial partial dehydrogenation of hydrocarbon by a heterogeneous catalyst with using the reaction vessel.SOLUTION: In a catalytic dehydrogenation of a hydrocarbon such as propane to an unsaturated hydrocarbon such as propene, a reaction vessel of which an inner surface of a reaction chamber consists of steel containing Cr: 18 to 30 mass%, Ni: 9 to 37 mass%, Si: 1 to 4 mass% and the like and an outer surface at opposite side of the reaction chamber is made from a composite material metal-plated on a steel containing Cr: 15 to 20 mass%, Ni: 6 to 18 mass%, Si: 0 to 0.8 mass% and the like directly or through layers of copper, nickel or copper and nickel is used. A method of a serial partial dehydrogenation of hydrocarbon by a heterogeneous catalyst with using the reaction vessel is provided.

Abstract translation: 要解决的问题：提供一种对热循环具有高耐受性（高耐久性脆化，渗碳，金属粉尘）并能够减少不期望的催化作用的反应容器，并提供一种烃的连续部分脱氢方法 通过使用反应容器的非均相催化剂。解决方案：在烃如丙烷到不饱和烃如丙烯的催化脱氢反应器中，反应室的内表面由含有Cr：18至 30质量％，Ni：9〜37质量％，Si：1〜4质量％等，反应室的相反侧的外表面由金属镀覆在含有Cr：15〜 20质量％，Ni：6〜18质量％，Si：0〜0.8质量％等，直接或通过铜，镍或铜和镍层。 提供了一种使用反应容器通过非均相催化剂连续部分脱氢烃的方法。

公开(公告)号：JP2014114293A

公开(公告)日：2014-06-26

申请号：JP2014000309

申请日：2014-01-06

Applicant: Basf Se ,  ビーエーエスエフ ソシエタス・ヨーロピアBasf Se

Inventor： DIETERLE MARTIN ,  HORSTMANN CATHARINA ,  SCHINDLER GOETZ-PETER ,  MULLER-ENGEL KLAUS JOACHIM ,  JENS SCHEIDEL ,  CHRISTOPH ADAMI

IPC: C07C5/333 ,  B01J23/62 ,  C07B61/00 ,  C07C11/06

CPC classification number: B01J8/0453 ,  B01J8/0496 ,  B01J8/062 ,  B01J8/067 ,  B01J19/0033 ,  B01J2208/00221 ,  B01J2208/00407 ,  B01J2208/00415 ,  B01J2208/00522 ,  B01J2208/025 ,  C07C5/3337 ,  C07C45/33 ,  C07C45/35 ,  C07C67/08 ,  C07C2523/42 ,  Y02P20/52 ,  C07C11/02 ,  C07C11/06 ,  C07C47/22 ,  C07C69/54

Abstract: PROBLEM TO BE SOLVED: To provide a long-term implementation method of a continuously implemented partial heterogeneous catalytic dehydrogenation of a to-be-dehydrogenated hydrocarbon.SOLUTION: A reactive gas mixture flow including a to-be-dehydrogenated hydrocarbon of a starting molar quantity HC is transmitted through a total catalyst bed including a dehydrogenation catalyst at a total sum M, and in a case where the implementation period proliferates, the deactivation of the total catalyst bed is attenuated by decreasing the conversion contribution of the first of three zones of the dehydrogenation catalyst of the total sum M along the fluidizing direction thereof, by increasing the conversion contribution of the last of the three zones of the dehydrogenation catalyst of the total sum M along the fluidizing direction thereof, and by maximizing the conversion contribution of the second of the three zones of the dehydrogenation catalyst of the total sum M along the fluidizing direction thereof.

Abstract translation: 要解决的问题：提供一种连续进行的待脱氢烃的部分多相催化脱氢的长期实施方法。溶液：包括起始摩尔数的待脱氢烃的反应气体混合物流 HC通过包含脱氢催化剂的总催化剂床以总和M传输，并且在实施期增加的情况下，通过降低总催化剂床的三个区域中的第一个区域的转化贡献来减弱总催化剂床的失活 通过增加脱氢催化剂的最后三个区域沿着其流化方向的总和M的最后一个转化贡献，并且通过使第二个催化剂的流化方向的转化贡献最大化， 脱氢催化剂的三个区域沿着流化方向的总和M. 它们。

公开(公告)号：WO2012101567A3

公开(公告)日：2013-01-03

申请号：PCT/IB2012050303

申请日：2012-01-23

Applicant: BASF SE ,  BASF CHINA CO LTD ,  HANNEMANN STEFAN ,  STUETZER DIETER ,  SCHINDLER GOETZ-PETER ,  PFAB PETER ,  KLEINE JAEGER FRANK ,  GROSSCHMIDT DIRK

Inventor： HANNEMANN STEFAN ,  STUETZER DIETER ,  SCHINDLER GOETZ-PETER ,  PFAB PETER ,  KLEINE JAEGER FRANK ,  GROSSCHMIDT DIRK

IPC: B01J32/00 ,  B01J23/56 ,  C01G25/02

CPC classification number: C01G25/02 ,  B01J21/066 ,  B01J21/08 ,  B01J23/626 ,  B01J23/63 ,  B01J23/96 ,  B01J35/1014 ,  B01J37/036 ,  B01J37/082 ,  B01J37/349 ,  B01J38/10 ,  B01J38/12 ,  C01B33/193 ,  C01P2006/12 ,  C07C5/3337 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/62 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06

Abstract: Provided is a method of production of catalyst support particles, containing zirconium dioxide and optionally silicon oxide, comprising the steps: (i) preparation of a solution containing precursor compounds of zirconium dioxide and optionally of silicon dioxide, (ii)conversion of the solution to an aerosol, (iii)bringing the aerosols into a directly or indirectly heated pyrolysis zone, (iv) carrying out the pyrolysis, (v)separation of the catalyst particles formed from the pyrolysis gas.

Abstract translation: 本发明涉及一种用于催化剂载体颗粒的制备，其包括氧化锆和任选的氧化硅的方法，包括以下步骤：（i）提供含有锆的前体化合物的溶液，以及任选的二氧化硅; （ii）该溶液装入气雾剂的转换; （三）将所述气溶胶成直接或间接加热的热解区; （ⅳ）进行热解; 从热分解气体形成的催化剂颗粒（V）的沉积。

公开(公告)号：WO2011032900A2

公开(公告)日：2011-03-24

申请号：PCT/EP2010063349

申请日：2010-09-13

Applicant: BASF SE ,  KOLIOS GRIGORIOS ,  PATCAS FLORINA CORINA ,  SCHINDLER GOETZ-PETER ,  SEEBER ALEXANDRA ,  WATERS GERRIT

Inventor： KOLIOS GRIGORIOS ,  PATCAS FLORINA CORINA ,  SCHINDLER GOETZ-PETER ,  SEEBER ALEXANDRA ,  WATERS GERRIT

CPC classification number: B01J19/123 ,  A23L3/28 ,  B01D53/885 ,  B01D2255/20707 ,  B01D2255/802 ,  B01J21/063 ,  B01J35/004 ,  B01J37/0009 ,  B01J2219/0875 ,  B01J2219/0877 ,  B01J2219/0892 ,  C02F1/325 ,  C02F1/722 ,  C02F1/725 ,  C02F1/74 ,  C02F1/76 ,  C02F1/78 ,  C02F2103/003 ,  C02F2103/28 ,  C02F2103/32 ,  C02F2103/36 ,  C02F2103/365 ,  C02F2201/3223 ,  C02F2201/3228

Abstract: The present invention relates to a reactor for the photocatalytic treatment of liquid or gas currents, comprising a pipe which the current to be treated flows through. At least one light source, at least one planar means M1 and at least one planar means M2 are arranged inside said pipe, wherein M1 has at least one photocatalytically active material and M2 reflects the light radiation emitted from the at least one light source. The reflective surface of the at least one means M2 and the inner wall of the pipe together form an angle that is greater than or equal to 0°, such that the light emitted from the light source is reflected from the at least one means M2 onto the photocatalytically active material. The invention further relates to a method for the photocatalytic treatment of liquid or gas currents by irradiation of light in the reactor according to the invention.

Abstract translation: 本发明涉及用于液体或气体流中的光催化处理的反应器，其包括一个管，通过该流被处理流，其中，在设置有至少一种光催化活性材料，片状介质M1和至少所述管的至少一个光源，至少一个 一个从反射所述至少一个光源的光发射的辐射的，平面的装置M2被设置，其中，所述至少一个的反射表面装置M2和管道的描述大于或等于的角度为0°的内壁，从而使从该光源发出的光 至少一种试剂M2被反射到光催化活性材料上，以及在根据本发明的反应器中通过用光照射光催化处理液体或气体流的方法。

公开(公告)号：WO2009027433A3

公开(公告)日：2009-05-14

申请号：PCT/EP2008061221

申请日：2008-08-27

Applicant: BASF SE ,  SEEBER ALEXANDRA ,  SCHINDLER GOETZ-PETER ,  FREITAG KATRIN ,  KLEINE JAEGER FRANK ,  KLINGLER DIRK ,  BORGMEIER FRIEDER

Inventor： SEEBER ALEXANDRA ,  SCHINDLER GOETZ-PETER ,  FREITAG KATRIN ,  KLEINE JAEGER FRANK ,  KLINGLER DIRK ,  BORGMEIER FRIEDER

IPC: B01J35/00 ,  B01D53/86 ,  B01J19/26 ,  B01J37/34 ,  C01G23/07

CPC classification number: B01J35/004 ,  B01J2/003 ,  B01J2/04 ,  B01J19/24 ,  B01J19/26 ,  B01J21/08 ,  B01J35/0013 ,  B01J37/349 ,  B01J2219/00123 ,  B01J2219/00157 ,  B01J2219/00166 ,  B82Y30/00 ,  C01G23/07 ,  C01P2002/85 ,  C01P2004/04 ,  C01P2004/64 ,  C01P2004/84 ,  C01P2004/86 ,  C09C1/3661 ,  C09C1/3684 ,  Y10T428/2991 ,  Y10T428/2993

Abstract: The invention relates to a method for producing coated nanoparticles which comprise a core holding at least one first substance and at least one envelope from at least one additional substance that at least partially surrounds the core, in a fluid system. The invention also relates to nanoparticles obtainable by said method, to nanoparticles comprising a non-porous core that holds at least one first substance, and at least one envelope from at least one additional substance that at least partially surrounds the core, the nanoparticles having a narrow particle-size distribution. The invention finally relates to the use of the nanoparticles in photocatalysis and to a device for carrying out the method.

Abstract translation: 本发明涉及一种方法，其包括一个芯涂覆的纳米颗粒的制剂，其包含至少一个第一材料和至少一个芯，其可以在流动的系统来制备至少一种另外的物质的至少部分地包围鞘，根据该方法的纳米颗粒，所述纳米颗粒包含非 多孔芯，其包括至少一种第一材料和至少一个芯至少部分地围绕至少一种其它物质的多孔壳，其中，所述纳米颗粒具有较窄的粒度分布，使用这些Nanopartikelin光催化，以及用于执行该方法的装置。

公开(公告)号：SG176041A1

公开(公告)日：2011-12-29

申请号：SG2011083516

申请日：2010-05-05

Applicant: BASF SE ,  DOW CHEMICAL CO

Inventor： KAMPE PHILIP ,  RESCH PETER ,  CHIN SOO YIN ,  BASLER PETER ,  MUELLER ULRICH ,  SCHINDLER GOETZ-PETER ,  GOEBBEL HANS-GEORG ,  TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  GRASLER THOMAS ,  BARTOSCH CHRISTIAN ,  JACUBINAS RICHARD ,  WEIDENBACH MEINOLF

Abstract: A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (Gl) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (Gl) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.

公开(公告)号：DE502005011011D1

公开(公告)日：2011-04-07

申请号：DE502005011011

申请日：2005-12-07

Applicant: BASF SE

Inventor： CRONE SVEN ,  KLANNER CATHARINA ,  SCHINDLER GOETZ-PETER ,  DUDA MARK ,  BORGMEIER FRIEDER

IPC: C07C5/333 ,  C07C11/167

公开(公告)号：AT492610T

公开(公告)日：2011-01-15

申请号：AT08787515

申请日：2008-08-27

Applicant: BASF SE

Inventor： SEEBER ALEXANDRA ,  SCHINDLER GOETZ-PETER ,  FREITAG KATRIN ,  JAHNS EKKEHARD ,  RAFFAELE ADDAMO ANTONINO ,  KLEINE JAEGER FRANK ,  KLINGLER DIRK

IPC: C09D7/00 ,  C09D7/12

公开(公告)号：CA2763397A1

公开(公告)日：2010-12-29

申请号：CA2763397

申请日：2010-06-23

Applicant: BASF SE

Inventor： PATCAS FLORINA CORINA ,  KOLIOS GRIGORIOS ,  SCHINDLER GOETZ-PETER ,  PFAB PETER ,  HESS REINHARD

IPC: C02F1/32 ,  C02F1/72

Abstract: The present invention relates to a method for purifying a contaminant-laden current by bringing the current to be purified in contact with a heterogeneous photocatalyst and irradiating it with light, wherein it is brought into contact in the presence of at least one compound, which is dissolved in the current and contains at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese, and mixtures thereof, and to the use of a heterogeneous photocatalyst for purifying a contaminant-laden current, wherein at least one compound containing at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese, and mixtures thereof, is present in dissolved form in the current to be purified.