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    PROCESS FOR PRODUCING REFORMING CATALYST AND REFORMING OF METHANE
    11.
    发明专利
    PROCESS FOR PRODUCING REFORMING CATALYST AND REFORMING OF METHANE 未知

    公开(公告)号：CA2854863A1

    公开(公告)日：2013-05-16

    申请号：CA2854863

    申请日：2012-11-05

    Applicant: BASF SE

    Inventor： SCHWAB EKKEHARD ,  MILANOV ANDRIAN ,  SCHUNK STEPHAN ,  ROUSSIERE THOMAS ,  WASSERSCHAFF GUIDO ,  STRASSER ANDREAS

    IPC: B01J23/755 ,  B01J23/58 ,  C01B3/38 ,  C01B3/40

    Abstract: A catalyst for the reforming of hydrocarbon-comprising compounds with CO2, water and/or hydrogen, a process for producing the same, and a process using the same for the reforming of the hydrocarbon-comprising compounds are provided. The production of the catalyst is based on contacting, intimately mixing and thermal treating of a hydrotalcite-comprising starting material with a fusible metal salt, which more preferably comprises nickel nitrate hexahydrate, to result in the metal salt melt. After molding and shaping, the compounds are subjected to high-temperature calcination step. In addition, the process using the catalyst for the reforming of the hydrocarbon-comprising compounds is carried out in a temperature range from 500 to 1100 °C at a pressure in the range from 2 to 70 bar. The catalyst is distinguished from the prior art by physicochemical properties.

    HEXAALUMINATE-COMPRISING CATALYST FOR THE REFORMING OF HYDROCARBONS AND A REFORMING PROCESS
    15.
    发明专利
    HEXAALUMINATE-COMPRISING CATALYST FOR THE REFORMING OF HYDROCARBONS AND A REFORMING PROCESS 未知

    公开(公告)号：CA2864063C

    公开(公告)日：2021-06-01

    申请号：CA2864063

    申请日：2013-02-07

    Applicant: BASF SE

    Inventor： SCHUNK STEPHAN ,  MILANOV ANDRIAN ,  STRASSER ANDREAS ,  WASSERSCHAFF GUIDO ,  ROUSSIERE THOMAS

    IPC: B01J23/32 ,  B01J21/04 ,  B01J23/00 ,  C01B32/40

    Abstract: The present invention relates to a hexaaluminate-containing catalyst, which comprises a hexaaluminate-containing phase that includes cobalt and at least one additional element from the group La, Ba, Sr. The Co content of the hexaaluminate-containing catalyst is in the range of 2-15 mol%, preferably 3-10 mol% and further preferably in the range of 4-8 mol%, the content of the at least one additional element from the group La, Ba, Sr is in the range of 2-25 mol%, preferably 3-15 mol%, further preferably 4-10 mol% and the content of Al is in the range of 70-90 mol%. In addition to the hexaaluminate-containing phase, the catalyst can include a 0-50 wt% oxide secondary phase, the portion of oxide secondary phase preferably in the range of 3-40 wt% and further preferably in the range of 5-30 wt%. The method according to the invention for producing the catalyst is based on initially bringing a source of aluminium oxide, preferably, a boehmite, into contact with cobalt species and at least one element from the group La, Ba, Sr. The moulded and dried material is preferably calcined at a temperature greater than or equal to 800°C. The reforming method for converting hydrocarbons, preferably methane, in the presence of CO2 is characterised in that the catalyst is used at a process temperature greater than 700°C, preferably greater than 800°C and further preferably greater than 900°C, the process pressure being greater than 5 bar, preferably greater than 10 bar and further preferably greater than 15 bar.

    HEXAALUMINATE-COMPRISING CATALYST FOR REFORMING OF HYDROCARBONS AND REFORMING PROCESS
    18.
    发明专利
    HEXAALUMINATE-COMPRISING CATALYST FOR REFORMING OF HYDROCARBONS AND REFORMING PROCESS 未知

    公开(公告)号：CA2864063A1

    公开(公告)日：2013-08-15

    申请号：CA2864063

    申请日：2013-02-07

    Applicant: BASF SE

    Inventor： SCHUNK STEPHAN ,  MILANOV ANDRIAN ,  STRASSER ANDREAS ,  WASSERSCHAFF GUIDO ,  ROUSSIERE THOMAS

    IPC: B01J23/32 ,  B01J21/04 ,  B01J23/00 ,  C01B32/40

    Abstract: The present invention relates to a hexaaluminate-containing catalyst, which comprises a hexaaluminate-containing phase that includes cobalt and at least one additional element from the group La, Ba, Sr. The Co content of the hexaaluminate-containing catalyst is in the range of 2-15 mol%, preferably 3-10 mol% and further preferably in the range of 4-8 mol%, the content of the at least one additional element from the group La, Ba, Sr is in the range of 2-25 mol%, preferably 3-15 mol%, further preferably 4-10 mol% and the content of Al is in the range of 70-90 mol%. In addition to the hexaaluminate-containing phase, the catalyst can include a 0-50 wt% oxide secondary phase, the portion of oxide secondary phase preferably in the range of 3-40 wt% and further preferably in the range of 5-30 wt%. The method according to the invention for producing the catalyst is based on initially bringing a source of aluminium oxide, preferably, a boehmite, into contact with cobalt species and at least one element from the group La, Ba, Sr. The moulded and dried material is preferably calcined at a temperature greater than or equal to 800°C. The reforming method for converting hydrocarbons, preferably methane, in the presence of CO2 is characterised in that the catalyst is used at a process temperature greater than 700°C, preferably greater than 800°C and further preferably greater than 900°C, the process pressure being greater than 5 bar, preferably greater than 10 bar and further preferably greater than 15 bar.

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