公开(公告)号：US09076567B2

公开(公告)日：2015-07-07

申请号：US13891581

申请日：2013-05-10

Applicant: CORNING INCORPORATED

Inventor： Monika Backhaus-Ricoult ,  Lisa Anne Moore ,  Charlene Marie Smith ,  Todd Parrish St. Clair

IPC: H01B1/02 ,  H01L35/22 ,  C04B35/64 ,  C04B35/626 ,  C04B35/47 ,  C04B35/645 ,  B82Y30/00

CPC classification number: H01B1/02 ,  B82Y30/00 ,  C04B35/47 ,  C04B35/62685 ,  C04B35/62695 ,  C04B35/64 ,  C04B35/645 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3237 ,  C04B2235/3251 ,  C04B2235/3813 ,  C04B2235/3843 ,  C04B2235/3886 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/5454 ,  C04B2235/652 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/6567 ,  C04B2235/658 ,  C04B2235/6587 ,  C04B2235/666 ,  C04B2235/77 ,  C04B2235/785 ,  C04B2235/79 ,  C04B2235/80 ,  C04B2235/9607 ,  H01L35/22

Abstract: Doped and partially-reduced oxide (e.g., SrTiO3-based) thermoelectric materials. The thermoelectric materials can be single-doped or multi-doped (e.g., co-doped) and display a thermoelectric figure of merit (ZT) of 0.2 or higher at 1050K. Methods of forming the thermoelectric materials involve combining and reacting suitable raw materials and heating them in a graphite environment to at least partially reduce the resulting oxide. Optionally, a reducing agent such as titanium carbide, titanium nitride, or titanium boride can be incorporated into the starting materials prior to the reducing step in graphite. The reaction product can be sintered to form a dense thermoelectric material.

Abstract translation: 掺杂和部分还原的氧化物（例如，基于SrTiO 3的）热电材料。 热电材料可以是单掺杂或多掺杂（例如，共掺杂），并且在1050K下显示出0.2或更高的热电性能（ZT）。 形成热电材料的方法包括组合和反应合适的原料并在石墨环境中加热它们以至少部分地减少所得的氧化物。 任选地，还原剂如碳化钛，氮化钛或硼化钛可以在石墨中的还原步骤之前引入原料中。 反应产物可以烧结以形成致密的热电材料。

公开(公告)号：US20140373571A1

公开(公告)日：2014-12-25

申请号：US14269409

申请日：2014-05-05

Applicant: Corning Incorporated

Inventor： Kenneth Edward Hrdina ,  Changyi Lai ,  Lisa Anne Moore ,  Ulrich Wilhelm Heinz Neukirch ,  William Rogers Rosch

IPC: C03C23/00

CPC classification number: C03C23/0095 ,  C03B19/1453 ,  C03B32/00 ,  C03B2201/07 ,  C03B2201/075 ,  C03B2201/21 ,  C03B2201/22 ,  C03C3/06 ,  C03C4/0085 ,  C03C21/007 ,  C03C2201/21 ,  C03C2201/22 ,  C03C2201/23 ,  C03C2203/54

Abstract: A fused silica glass article having greater resistance to damage induced by exposure to laser radiation such as laser induced wavefront distortion at deep ultraviolet (DUV) wavelengths, and behaviors such as fluence dependent transmission, which are related to intrinsic defects in the glass. The improved resistance to laser damage may be achieved in some embodiments by loading the glass article with molecular hydrogen (H2) at temperatures of about 400° C. or less, or 350° C. or less. The combined OH and deuteroxyl (OD) concentration may be less than 10 ppm by weight. In other embodiments, the improved resistance may be achieved by providing the glass with 10 to 60 ppm deuteroxyl (OD) species by weight. In still other embodiments, improved resistance to such laser damage may be achieved by both loading the glass article with molecular hydrogen at temperatures of about 350° C. or less and providing the glass with less than 10 ppm combined OH and OD, or 10 to 60 ppm OD by weight.

Abstract translation: 一种熔融石英玻璃制品，其具有较强的耐受暴露于激光辐射（例如在深紫外（DUV）波长处的激光诱导波前失真）以及与玻璃中的固有缺陷有关的诸如通量依赖透射的行为的损伤。 在一些实施方案中，可以通过在约400℃或更低或350℃或更低的温度下加载具有分子氢（H 2）的玻璃制品来实现对激光损伤的改进的抗性。 组合的OH和氘氧化（OD）浓度可以小于10ppm重量。 在其它实施方案中，可以通过为玻璃提供10至60ppm的重量的氘氧化（OD）种类来实现改进的电阻。 在另外的其它实施方案中，可以通过在大约350℃或更低的温度下将玻璃制品加载到分子氢中来提供对这种激光损伤的改进的抗性，并且使玻璃具有小于10ppm的组合的OH和OD，或10至 60ppm OD重量。

公开(公告)号：US09444026B2

公开(公告)日：2016-09-13

申请号：US14252131

申请日：2014-04-14

Applicant: Corning Incorporated

Inventor： Monika Backhaus-Ricoult ,  Lisa Anne Moore ,  Charlene Marie Smith ,  Todd Parrish St Clair

IPC: H01L35/18 ,  H01L35/22 ,  C04B35/47 ,  C04B35/645 ,  B82Y30/00

CPC classification number: H01L35/22 ,  B82Y30/00 ,  C04B35/47 ,  C04B35/645 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3237 ,  C04B2235/3251 ,  C04B2235/3813 ,  C04B2235/3843 ,  C04B2235/3886 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/5454 ,  C04B2235/652 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/6567 ,  C04B2235/658 ,  C04B2235/6587 ,  C04B2235/666 ,  C04B2235/77 ,  C04B2235/785 ,  C04B2235/79 ,  C04B2235/80 ,  C04B2235/9607

Abstract: Doped and partially-reduced oxide (e.g., SrTiO3-based) thermoelectric materials. The thermoelectric materials can be single-doped or multi-doped (e.g., co-doped) and display a thermoelectric figure of merit (ZT) of 0.2 or higher at 1050 K. Methods of forming the thermoelectric materials involve combining and reacting suitable raw materials and heating them in a graphite environment to at least partially reduce the resulting oxide. Optionally, a reducing agent such as lanthanum boride, titanium carbide, titanium nitride, or titanium boride can be incorporated into the starting materials prior to the reducing step in graphite. The reaction product can be sintered to form a dense thermoelectric material.

Abstract translation: 掺杂和部分还原的氧化物（例如，基于SrTiO 3的）热电材料。 热电材料可以是单掺杂或多掺杂（例如，共掺杂），并且在1050K处显示0.2或更高的热电性能（ZT）。形成热电材料的方法涉及将合适的原料 并在石墨环境中加热它们以至少部分地减少所得到的氧化物。 任选地，可以在还原步骤之前在石墨中引入硼化镧，碳化钛，氮化钛或硼化钛等还原剂。 反应产物可以烧结以形成致密的热电材料。

公开(公告)号：US09409815B2

公开(公告)日：2016-08-09

申请号：US14672854

申请日：2015-03-30

Applicant: CORNING INCORPORATED

Inventor： Adam James Ellison ,  Lisa Anne Moore ,  Taheisha Linette Werner

IPC: C03C10/10 ,  C03C10/00 ,  C03B32/02 ,  C03C21/00 ,  C03C3/085 ,  C03C4/02

CPC classification number: C03C10/0018 ,  C03B32/02 ,  C03C3/085 ,  C03C4/02 ,  C03C21/002 ,  C03C2204/04

Abstract: Disclosed herein are opaque glass-ceramics comprising at least one nepheline crystal phase and comprising from about 30 mol % to about 65 mol % SiO2, from about 15 mol % to about 40 mol % Al2O3, from about 10 mol % to about 20 mol % (Na2O+K2O), and from about 1 mol % to about 10 mol % (ZnO+MgO). Also disclosed herein are opaque-glass ceramics comprising at least one nepheline crystal phase and at least one spinel-structure phase doped with at least one colorant chosen from transition metals and rare earth elements. Further disclosed herein are methods for making these opaque glass-ceramics.

Abstract translation: 本文公开了包含至少一个霞石结晶相的不透明玻璃陶瓷，其包含约30mol％至约65mol％的SiO 2，约15mol％至约40mol％的Al 2 O 3，约10mol％至约20mol％ （Na 2 O + K 2 O）和约1mol％至约10mol％（ZnO + MgO）。 本文还公开了包含至少一个霞石结晶相和掺杂有选自过渡金属和稀土元素的至少一种着色剂的至少一个尖晶石结构相的不透明玻璃陶瓷。 本文进一步公开了制造这些不透明玻璃陶瓷的方法。

公开(公告)号：US20140225022A1

公开(公告)日：2014-08-14

申请号：US14252131

申请日：2014-04-14

Applicant: Corning Incorporated

Inventor： Monika Backhaus-Ricoult ,  Lisa Anne Moore ,  Charlene Marie Smith ,  Todd Parrish St Clair

IPC: H01L35/22

CPC classification number: H01L35/22 ,  B82Y30/00 ,  C04B35/47 ,  C04B35/645 ,  C04B2235/3224 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3237 ,  C04B2235/3251 ,  C04B2235/3813 ,  C04B2235/3843 ,  C04B2235/3886 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/5454 ,  C04B2235/652 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/6567 ,  C04B2235/658 ,  C04B2235/6587 ,  C04B2235/666 ,  C04B2235/77 ,  C04B2235/785 ,  C04B2235/79 ,  C04B2235/80 ,  C04B2235/9607

Abstract: Doped and partially-reduced oxide (e.g., SrTiO3-based) thermoelectric materials. The thermoelectric materials can be single-doped or multi-doped (e.g., co-doped) and display a thermoelectric figure of merit (ZT) of 0.2 or higher at 1050K. Methods of forming the thermoelectric materials involve combining and reacting suitable raw materials and heating them in a graphite environment to at least partially reduce the resulting oxide. Optionally, a reducing agent such as lanthanum boride, titanium carbide, titanium nitride, or titanium boride can be incorporated into the starting materials prior to the reducing step in graphite. The reaction product can be sintered to form a dense thermoelectric material.

Abstract translation: 掺杂和部分还原的氧化物（例如，基于SrTiO 3的）热电材料。 热电材料可以是单掺杂或多掺杂（例如，共掺杂），并且在1050K下显示出0.2或更高的热电性能（ZT）。 形成热电材料的方法包括组合和反应合适的原料并在石墨环境中加热它们以至少部分地减少所得的氧化物。 任选地，可以在还原步骤之前在石墨中引入硼化镧，碳化钛，氮化钛或硼化钛等还原剂。 反应产物可以烧结以形成致密的热电材料。

公开(公告)号：US10150694B2

公开(公告)日：2018-12-11

申请号：US15659966

申请日：2017-07-26

Applicant: CORNING INCORPORATED

Inventor： Adam James Ellison ,  Lisa Anne Moore ,  Taheisha Linette Werner

IPC: C03C10/10 ,  C03B32/02 ,  C03C21/00 ,  C03C10/00 ,  C03C3/085 ,  C03C4/02

Abstract: Disclosed herein are opaque glass-ceramics comprising at least one nepheline crystal phase and comprising from about 30 mol % to about 65 mol % SiO2, from about 15 mol % to about 40 mol % Al2O3, from about 10 mol % to about 20 mol % (Na2+K2O), and from about 1 mol % to about 10 mol % (ZnO+MgO). Also disclosed herein are opaque-glass ceramics comprising at least one nepheline crystal phase and at least one spinel-structure phase doped with at least one colorant chosen from transition metals and rare earth elements. Further disclosed herein are methods for making these opaque glass-ceramics.

公开(公告)号：US10017413B2

公开(公告)日：2018-07-10

申请号：US14950374

申请日：2015-11-24

Applicant: CORNING INCORPORATED

Inventor： Sezhian Annamalai ,  Carlos Alberto Duran ,  Kenneth Edward Hrdina ,  Lisa Anne Moore

IPC: C03C3/06 ,  C03C3/112 ,  C03C3/089 ,  G03F1/22 ,  C03B25/02 ,  C03B19/02 ,  C03C3/115 ,  C03C21/00 ,  C03C23/00 ,  C03B5/225 ,  C03B25/00

CPC classification number: C03C3/112 ,  C03B5/225 ,  C03B19/02 ,  C03B25/00 ,  C03B25/02 ,  C03B2201/10 ,  C03B2201/12 ,  C03B2201/14 ,  C03B2201/42 ,  C03C3/06 ,  C03C3/089 ,  C03C3/115 ,  C03C21/007 ,  C03C23/007 ,  C03C2201/10 ,  C03C2201/12 ,  C03C2201/14 ,  C03C2201/23 ,  C03C2201/30 ,  C03C2201/42 ,  C03C2203/10 ,  C03C2203/54 ,  G03F1/22

Abstract: A method of forming a doped silica-titania glass is provided. The method includes blending batch materials comprising silica, titania, and at least one dopant. The method also includes heating the batch materials to form a glass melt. The method further includes consolidating the glass melt to form a glass article, and annealing the glass article.

公开(公告)号：US09701573B2

公开(公告)日：2017-07-11

申请号：US14474708

申请日：2014-09-02

Applicant: CORNING INCORPORATED

Inventor： George Halsey Beall ,  Qiang Fu ,  Lisa Anne Moore ,  Linda Ruth Pinckney ,  Charlene Marie Smith

IPC: C03C10/04 ,  C03C10/12 ,  C03C10/00 ,  C03C3/097 ,  C03C3/093

CPC classification number: C03C10/0027 ,  C03C3/093 ,  C03C3/097 ,  C03C10/0054 ,  C03C21/002 ,  C03C2204/00

Abstract: Glass and glass ceramic compositions having a combination of lithium disilicate and β-spodumene crystalline phases along with methods of making the glass and glass ceramic compositions are described. The compositions are compatible with conventional rolling and float processes and have high mechanical strength and fracture resistance. Further, the compositions are able to be chemically tempered to even higher strength glass ceramics that are useful as large substrates in multiple applications.

公开(公告)号：US20170006877A1

公开(公告)日：2017-01-12

申请号：US15202272

申请日：2016-07-05

Applicant: CORNING INCORPORATED

Inventor： Heather Debra Boek ,  John Christopher Mauro ,  Lisa Anne Moore ,  Michael S. Pambianchi ,  Natesan Venkataraman ,  Mark Owen Weller

IPC: A01N59/20 ,  C03B32/00 ,  C03B25/00 ,  C03C14/00 ,  C03C10/00

CPC classification number: A01N59/20 ,  B32B17/06 ,  C03B25/00 ,  C03B32/00 ,  C03C3/093 ,  C03C14/004 ,  C03C17/02 ,  C03C2204/02 ,  C03C2214/08 ,  A01N25/08 ,  A01N25/34

Abstract: A glass laminate for an architectural element has a glass substrate coupled to the architectural element and defines a primary surface facing away from the architectural element. A phase-separable glass cladding is coupled to the primary surface. The cladding has an interconnected matrix with a first phase composition and a second phase that has a second phase composition different than the first phase composition. The second phase is distributed throughout the interconnected matrix. A copper phase is distributed within the interconnected matrix. The glass cladding has an antimicrobial log kill rate greater than about 4 as measured by an EPA Copper Test Protocol.

Abstract translation: 用于建筑元件的玻璃层压板具有联接到建筑元件的玻璃基板，并且限定了远离建筑元件的主表面。 相分离玻璃包层耦合到主表面。 包层具有互连的具有第一相组成的基体和具有不同于第一相组成的第二相组成的第二相。 第二阶段分布在整个互连的矩阵中。 铜相分布在互连的基体内。 通过EPA铜测试方案测量，玻璃包层的抗菌杀菌率大于约4。

公开(公告)号：US20160236969A1

公开(公告)日：2016-08-18

申请号：US15142581

申请日：2016-04-29

Applicant: CORNING INCORPORATED

Inventor： Adam James Ellison ,  Lisa Anne Moore ,  Taheisha Linette Werner

IPC: C03C10/00 ,  C03C21/00 ,  C03B32/02 ,  C03C4/02

CPC classification number: C03C10/0018 ,  C03B32/02 ,  C03C3/085 ,  C03C4/02 ,  C03C21/002 ,  C03C2204/04

Abstract: Disclosed herein are opaque glass-ceramics comprising at least one nepheline crystal phase and comprising from about 30 mol % to about 65 mol % SiO2, from about 15 mol % to about 40 mol % Al2O3, from about 10 mol % to about 20 mol % (Na2O+K2O), and from about 1 mol % to about 10 mol % (ZnO+MgO). Also disclosed herein are opaque-glass ceramics comprising at least one nepheline crystal phase and at least one spinel-structure phase doped with at least one colorant chosen from transition metals and rare earth elements. Further disclosed herein are methods for making these opaque glass-ceramics.

Abstract translation: 本文公开了包含至少一个霞石结晶相的不透明玻璃陶瓷，其包含约30mol％至约65mol％的SiO 2，约15mol％至约40mol％的Al 2 O 3，约10mol％至约20mol％ （Na 2 O + K 2 O）和约1mol％至约10mol％（ZnO + MgO）。 本文还公开了包含至少一个霞石结晶相和掺杂有选自过渡金属和稀土元素的至少一种着色剂的至少一个尖晶石结构相的不透明玻璃陶瓷。 本文进一步公开了制造这些不透明玻璃陶瓷的方法。