Abstract:
A PROCESS FOR PRODUCING AN EPOXIDIZED DIENE POLYMER INCLUDES: DISPERSING OR SUSPENDING A DIENE POLYMER (C) HAVING A BALL-REDUCED PARTICLE SIZE OF 0.05 - - 20 MM IN A MEDIUM (A) IN THE PRESENCE OF POWDER PARTICLES (B) INSOLUBLE IN THE MEDIUM (A) , OR IN AN AQUEOUS MEDIUM IN THE PRESENCE OF A PHENOL-BASED STABILIZER AND/OR A PHOSPHORUS-BASED STABILIZER; AND EPOXIDIZING THE DIENE POLYMER (C) BY AN EPOXIDIZING AGENT, THEREFORE, PROBLEMS ASSOCIATED WITH EPOXIDATICN PERFORMED BY DISSOLVING DIENE POLYMER IN A SOLVENT ARE ELIMINATED; AN ECONOMICAL METHOD FOR EPOXIDIZING, PRODUCING, AND PURIFYING A DIENE POLYMER (C) IN A SOLID FORM IS PROVIDED; EPOXIDIZED DIENE POLYMER HAVING AN EXCELLENT HEAT STABILITY CAN BE OBTAINED.
Abstract:
A metal/synthetic resin laminate comprising a metal substrate layer, an epoxy resin-based adhesive layer (a "1st adhesive layer"), an adhesive layer (a "2nd adhesive layer") comprising an epoxidized styrenic thermoplastic elastomer D prepared through epoxidation of a double bond derived from a conjugated diene compound of a block copolymer C comprising a polymer block A composed mainly of a styrenic compound and a polymer block B composed mainly of a conjugated diene compound or a partial hydrogenation product thereof, and a synthetic resin layer; and a synthetic resin-clad metallic pipe wherein the above metal substrate layer is tubular.
Abstract:
A blended composition consisting of a thermoplastic olefin resin (Comp. A) with an acrylonitrile-styrene-alkyl acrylate copolymer (Comp. B) was attempted to create substitution for vinyl chloride compound prepared from vinyl chloride resin proper and a plasticizer, but resulted in inferior interdispersibility. Incorporation of a thermoplastic epoxy resin (Comp. C) has brought definite improvement in the interdispersibility. A resinous composition including the components A, B, and C has the utility of substitution for vinyl chloride compounds as well as its products.
Abstract:
A blended composition consisting of a thermoplastic olefin resin (Comp. A) with an acrylonitrile-styrene-alkyl acrylate copolymer (Comp. B) was attempted to create substitution for vinyl chloride compound prepared from vinyl chloride resin proper and a plasticizer, but resulted in inferior interdispersibility. Incorporation of a thermoplastic epoxy resin (Comp. C) has brought definite improvement in the interdispersibility. A resinous composition including the components A, B, and C has the utility of substitution for vinyl chloride compounds as well as its products.
Abstract:
An epoxidized block copolymer (E) produced by epoxidizing a block copolymer (C) comprising a polymer block (A) mainly made from an aromatic vinyl compound and a polymer block (B) mainly made from a conjugated diene compound or a product (D) of hydrogenation of the copolymer (C) and satisfying at least one of the following requirements (1), (2) and (3): (1) the molar ratio R is 0.001 to 0.1, R being defined by the formula: R = [hydroxyl]/[epoxy] (wherein [hydroxyl] is the number of moles of hydroxyl groups contained per unit weight of the epoxidized block copolymer and [epoxy] is that of epoxy groups); (2) the gel content is 5 wt.% or below; and (3) the chloride ion content is 7 ppm or below. The above copolymer (E) can be produced by epoxidizing the block copolymer (C) or (D) in an organic solvent and removing the solvent by evaporation. Compositions comprising the copolymer (E) and other compounds and/or resins are useful.
Abstract:
AN EPOXIDIZED GRANULAR THERMOPLASTIC POLYMER WHICH COMPRISES A SHELL LIKE SURFACE LAYER INSOLUBLE IN TOLUENE AT 25°C IS FORMED ON THE POLYMER, AND A PROCESS FOR THE PRODUCTION OF THE EPOXIDIZED GRANULAR THERMOPLASTIC POLYMER CHARACTERIZED IN THAT THE PROCESS COMPRISES: THE FIRST STEP OF EPOXIDIZING A GRANULAR THERMOPLASTIC POLYMER IN A WATER MEDIUM IN THE PRESENCE OF AN ACCELERATING AN EPOXIDATION AGENT OR THE EPOXIDIZING AGENT AND A SOLVENT FOR ACCELERATING AN EPOXIDATION AGENT AND A SOLVENT FOR ACCELERATING AN EPOXIDATION REACTION AND A PHOSPHORIC ACID SERIES COMPOUND: THE SECOND COMPOUND STEP OF THE WASHING WITH WATER, OR THE NEUTRALIZATION AND WASHING WITH WATER OF THE EPOXIDIZED GRANULAR THERMOPLASTIC POLYMER; AND THE THIRD STEP, IF NECESSARY, OF REMOVING THE SOLVENT FOR ACCELERATING EPOXIDATION REACTION WHICH MAY BY USED IN THE FIRST STEP, AS WELL AS A PROCESS FOR THE PRODUCTION OF AN EPOXIDIZED THERMOPLASTIC POLYMER, CHARACTERIZED IN THAT UNDER CONDITION IN WHICH THERMOPLASTIC POLYMER (A) IN THE SOLID-STATE IS DISPERSED OR SUSPENDED IN WATER (B), THE THERMOPLASTIC POLYMER (A) IS EPOXIDIZED BY A PEROXIDE (C) WITH THE DISPERSED OR SUSPENDED STATE MAINTAINED.
Abstract:
A photosensitive hardenable composition comprising as major components a thermoplastic high molecular binder obtained from specific addition polymerizable monomers, an acrylate (or methacryliate) derivative or mixture thereof and a photopolymerization initiator, which possesses improved properties in softness, stripping properties, stripping time, etc of hardened layers formed.
Abstract:
Epoxidized granular thermoplastic polymers characterized by having a shelly surface layer insoluble in toluene at 25 DEG C; a process for the production of the epoxidized granular thermoplastic polymers, characterized by comprising the first step of epoxidizing a granular thermoplastic polymer in an aqueous medium in the presence of both an epoxidizing agent optionally combined with an epoxidation-accelerating solvent, and a phosphoric acid compound, the second step of subjecting the obtained epoxidized granular thermoplastic polymer to water washing which may be accompanied by neutralization, and, if necessary, the third step of removing the solvent used at need in the first step; and a process for the production of epoxidized thermoplastic polymers, characterized by dispersing a solid thermoplastic polymer (A) in water (B) and epoxidizing the polymer with a peroxide (C) while keeping the polymer in the dispersed or suspended state.