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公开(公告)号:GB2178047A
公开(公告)日:1987-02-04
申请号:GB8517863
申请日:1985-07-16
Applicant: DAICEL CHEM
Inventor: ITOH MASANORI , TAKENAKA FUMIO , TOHYA KOUZI
Abstract: The initiator composition is effectively used for a photopolymerizable resin composition which comprises a photopolymerizable compound having a double bond for polymerization and a polymer binder and comprises (A) thioxanthone or a substituted thioxanthone and (B) an oxime ester of the formula: wherein R1 and R2 may be the same or different and represent each an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted phenyl, naphthyl, anthryl, pyridyl or quinolyl group or R1 and R2 may be bonded together to form a ring, and R3 represents an alkyl group having 1 to 5 carbon atoms or a substituted or unsubstituted aryl group.
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公开(公告)号:DE3784246T2
公开(公告)日:1993-05-27
申请号:DE3784246
申请日:1987-12-22
Applicant: DAICEL CHEM
Inventor: TAKENAKA FUMIO , TOHYA KOUZI , OHTSUKA YOSHIHIRO
Abstract: A photosensitive hardenable composition comprising as major components a thermoplastic high molecular binder obtained from specific addition polymerizable monomers, an acrylate (or methacryliate) derivative or mixture thereof and a photopolymerization initiator, which possesses improved properties in softness, stripping properties, stripping time, etc of hardened layers formed.
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公开(公告)号:DE3523803C2
公开(公告)日:1994-03-31
申请号:DE3523803
申请日:1985-07-03
Applicant: DAICEL CHEM
Inventor: ITOH MASANORI , TAKENAKA FUMIO , TOHYA KOUZI
Abstract: The initiator composition is effectively used for a photopolymerizable resin composition which comprises a photopolymerizable compound having a double bond for polymerization and a polymer binder and comprises (A) thioxanthone or a substituted thioxanthone and (B) an oxime ester of the formula: wherein R1 and R2 may be the same or different and represent each an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted phenyl, naphthyl, anthryl, pyridyl or quinolyl group or R1 and R2 may be bonded together to form a ring, and R3 represents an alkyl group having 1 to 5 carbon atoms or a substituted or unsubstituted aryl group.
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公开(公告)号:DE3784246D1
公开(公告)日:1993-03-25
申请号:DE3784246
申请日:1987-12-22
Applicant: DAICEL CHEM
Inventor: TAKENAKA FUMIO , TOHYA KOUZI , OHTSUKA YOSHIHIRO
Abstract: A photosensitive hardenable composition comprising as major components a thermoplastic high molecular binder obtained from specific addition polymerizable monomers, an acrylate (or methacryliate) derivative or mixture thereof and a photopolymerization initiator, which possesses improved properties in softness, stripping properties, stripping time, etc of hardened layers formed.
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公开(公告)号:GB2178047B
公开(公告)日:1989-07-19
申请号:GB8517863
申请日:1985-07-16
Applicant: DAICEL CHEM
Inventor: ITOH MASANORI , TAKENAKA FUMIO , TOHYA KOUZI
Abstract: The initiator composition is effectively used for a photopolymerizable resin composition which comprises a photopolymerizable compound having a double bond for polymerization and a polymer binder and comprises (A) thioxanthone or a substituted thioxanthone and (B) an oxime ester of the formula: wherein R1 and R2 may be the same or different and represent each an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted phenyl, naphthyl, anthryl, pyridyl or quinolyl group or R1 and R2 may be bonded together to form a ring, and R3 represents an alkyl group having 1 to 5 carbon atoms or a substituted or unsubstituted aryl group.
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公开(公告)号:DE3523803A1
公开(公告)日:1987-01-08
申请号:DE3523803
申请日:1985-07-03
Applicant: DAICEL CHEM
Inventor: ITOH MASANORI , TAKENAKA FUMIO , TOHYA KOUZI
Abstract: The initiator composition is effectively used for a photopolymerizable resin composition which comprises a photopolymerizable compound having a double bond for polymerization and a polymer binder and comprises (A) thioxanthone or a substituted thioxanthone and (B) an oxime ester of the formula: wherein R1 and R2 may be the same or different and represent each an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted phenyl, naphthyl, anthryl, pyridyl or quinolyl group or R1 and R2 may be bonded together to form a ring, and R3 represents an alkyl group having 1 to 5 carbon atoms or a substituted or unsubstituted aryl group.
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公开(公告)号:JP2001018941A
公开(公告)日:2001-01-23
申请号:JP19260199
申请日:1999-07-07
Applicant: DAICEL CHEM
Inventor: TAKENAKA FUMIO
Abstract: PROBLEM TO BE SOLVED: To provide a composite volume-reducible container which is sufficient in mechanical strength in service and easily torn in disposal to reduce its volume by providing an easily-tearable layer having a specified tearing strength and consisting of specified resin components and a synthetic resin layer laminated thereon, and setting the peeling strength of the synthetic resin layer to be within a specified range. SOLUTION: A synthetic resin layer laminated on an easily-tearable layer is partly or wholly laminated on one or both surfaces of the easily-tearable layer. The easily-tearable layer is obtained by forming the resin components containing, by weight, 60-95% styrene resin and 40-5% olefin resin. The peeling strength of the synthetic resin layer is preferably 0.5-1.5 kg/15 mm, and the synthetic resin layer can prevent a flange part of a container from being curled up, and can be easily peeled when the container is disposed. The Elmendorf tearing strength of the easily-tearable layer is preferably 10-100f, the mechanical strength of the container can be increased, the easy tearability can be maintained, and the volume of the container can be easily reduced when it is disposed.
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公开(公告)号:JPH03200804A
公开(公告)日:1991-09-02
申请号:JP34233289
申请日:1989-12-28
Applicant: DAICEL CHEM
Inventor: TAKENAKA FUMIO , TOYA KOJI
Abstract: PURPOSE:To obtain a photopolymerizable composition of excellent photopolymerizability by forming a photopolymerizable composition comprising a photopolymerization initiator, a thermoplastic polymer and a normally liquid or solid addition-polymerizable substance, wherein a specified photopolymerization initiator is used as said photopolymerization initiator. CONSTITUTION:A photopolymerization initiator comprising a sulfide compound (a) of formula I (wherein R , R and R which may be the same or different are each a hydrogen atom, an alkyl or aryl group which may be substituted, an alkoxy group or the like; l and n are each an integer of 1-5; and m is an integer of 1-4), a benzophenone compound (b) which may be substituted with a group selected from among a halogen atom, an alkyl group, an alkoxy group, etc., an alkylaminobenzophenone compound (c) which may be substituted with a group similar to that in component (b), a 2,4,5-triarylimidazolyl dimer (d) which may be substituted, and a triarylmethane leuco dye (e) is mixed with a thermoplastic polymer and a normally liquid or solid addition-polymerizable substance.
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公开(公告)号:JPS62290702A
公开(公告)日:1987-12-17
申请号:JP13315586
申请日:1986-06-09
Applicant: DAICEL CHEM
Inventor: ENDO TOSHIRO , FUNAHIKI TAKESHI , TAKENAKA FUMIO
Abstract: PURPOSE:To obtain the photopolymerizable composition improved in adhesion to metal, etc., by adding 2-benzimidazolylacetonitrile to a photopolymerizable composition mainly consisting of a thermoplastic organic polymer, an addition- polymerizable unsaturated compound, a photopolymerization initiator, etc. CONSTITUTION:The purpose photopolymerizable composition is obtained by mixing a thermoplastic organic polymer binder (e.g., polymethyl methacrylate) with an addition-polymerizable unsaturated compound having at least two ethylenically unsaturated double bonds in the molecule (e.g., polyethylene glycol polyacrylate), a photopolymerization initiator (e.g., anthraquinone) and 2- benzimidazolylacetonitrile (derivative) of the formula (wherein R1, R2, R3 and R4 are each H, a halogen, an alkyl, an alkyl ester or an amino, R5 is H, a halogen, an alkyl, allyl, an aryl, an alkoxy or an acyl) as principal components.
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公开(公告)号:JPS6249315B2
公开(公告)日:1987-10-19
申请号:JP15497577
申请日:1977-12-21
Applicant: DAICEL CHEM
Inventor: HASHIZUME YOSHIO , ITO MASANORI , TAKENAKA FUMIO , SAKAI YASUMASA
IPC: C08F12/00 , C08F20/26 , C08F212/14 , C08F220/00 , C08F220/10 , C08F220/12 , C08F220/34 , C08J7/04 , C09D5/00 , C09D133/02 , C09D133/04
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