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公开(公告)号:ES2096615T3
公开(公告)日:1997-03-16
申请号:ES91121937
申请日:1991-12-20
Applicant: HOECHST AG
Inventor: AZ RAINER DR , SCHWAB WOLFGANG DR , SCHNAITMANN DIETER DR , DIETZ ERWIN DR
IPC: C07D251/34 , C07D251/38 , C07D251/46 , C07D251/52 , C07D251/70 , C07D403/12 , C07D403/14 , C08G73/06 , C09K23/00 , C09K23/32 , C09K23/52 , B01F17/32
Abstract: Polymeric, water-soluble triazine compounds which contain both basic and acidic groups in the molecule have out-standing surfactant properties and are suitable for the preparation of dispersions of solids, preferably of dispersions of inorganic and/or organic pigments, in an aqueous or water-dilutable medium. Since these triazine compounds are colorless or only slightly colored, they do not influence the shade of the medium used.
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公开(公告)号:ES2088070T3
公开(公告)日:1996-08-01
申请号:ES92117907
申请日:1992-10-20
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , URBAN MANFRED
Abstract: A pigment preparation consists essentially of a) at least one pigment of the azo, anthrapyrimidine, anthanthrone, quinacridone, perinone, diketopyrrolopyrrole, dioxazine, flavanthrone, indanthrone, isoindolinone, isoviolanthrone, perylene, phthalocyanine, pyranthrone or thioindigo pigments class or of a mixture of pigments of various classes and b) at least one dispersant of the general formula (I) in which P, independently of the pigments mentioned in a), represents a radical of an anthanthrone, azo, quinacridone, perinone, diketopyrrolopyrrole, dioxazine, indanthrone, perylene, phthalocyanine or thioindigo pigment, R and R independently of one another denote hydrogen, halogen, C1-C4-alkyl, C1-X4-alkoxy or nitro, and n is a number from 1 to 4, and their use for the pigmentation of high molecular weight materials in the form of plastic masses, melts, spinning solutions, lacquers, in particular of aqueous lacquers based on polyurethane or low-solvent acrylic resin lacquers having a high solids content, paints and printing inks, in particular those based on nitrocellulose.
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公开(公告)号:DE59204219D1
公开(公告)日:1995-12-14
申请号:DE59204219
申请日:1992-03-19
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , URBAN MANFRED
Abstract: Perylenetetracarboxylic diimides which contain a radical in the same molecule on one imide nitrogen which acts as an anion but contain a radical on the other imide nitrogen which acts as a cation, and on this basis form inner salts, are available by reaction of sulfo-containing alkylamines with perylenetetracarboxylic monoanhydride monoalkylaminoalkylimides or by reaction of alkylaminoalkylamines with perylenetetracarboxylic monoanhydride monosulfoalkylimides. As a result of their characteristic structural principle, these novel perylene compounds have excellent dispersing properties, in particular for pigments of the same chemical classes of compounds and can even be used themselves as pigments (colorants) depending on the substituent.
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公开(公告)号:DE58909330D1
公开(公告)日:1995-08-10
申请号:DE58909330
申请日:1989-04-25
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , PROKSCHY FRANK DR
IPC: C07D239/90 , C07D239/70 , C07D239/92 , C07D487/04 , C07D487/14 , C09B26/02 , C09B57/00 , C09B67/22
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公开(公告)号:DE4305714A1
公开(公告)日:1994-09-01
申请号:DE4305714
申请日:1993-02-25
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , KAPAUN GUSTAV DR
IPC: C07D235/16
Abstract: A process for the preparation of substituted or unsubstituted 2-(cyanomethyl)benzimidazole of the formula (I) is characterised in that an o-phenylenediamine of the formula (II) in which R is C1-C4-alkyl or C1-C4-alkoxy, preferably methyl or methoxy, and n is an integer from 0 to 2, preferably 0 or 1, in particular 0, is reacted with a cyanoacetic ester of the formula (III> NC-CH2-COOR (III> in which R is unsubstituted or substituted, linear, branched or cyclic C2-C12-alkyl and in which 1 to 3 CH2 groups of the alkyl radical can be replaced in each case by oxygen, at a temperature of 150 - 175@C in a halogen-free inert solvent whose boiling point is equal to or greater than 150@C, or in a mixture of two or more such solvents, without an addition of an aromatic sulphonic acid as catalyst. Using the process according to the invention, 2-(cyanomethyl)benzimidazoles are prepared in good yields and high purity without the use of a catalyst.
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公开(公告)号:DE3887744D1
公开(公告)日:1994-03-24
申请号:DE3887744
申请日:1988-12-20
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , KAPAUN GUSTAV DR , KAPPERT MICHAEL DR , PROKSCHY FRANK DR , KROH ADOLF , URBAN MANFRED
IPC: C09B1/00 , C08K5/03 , C09B3/14 , C09B3/22 , C09B3/40 , C09B5/16 , C09B5/20 , C09B5/48 , C09B5/62 , C09B19/02 , C09B47/04 , C09B47/12 , C09B57/04 , C09B67/20 , C09B69/00
Abstract: Pigments of the formula I (I) where A is a five- or six-membered aromatic fused or unfused heterocycle which contains one to three hetero atoms from the series consisting of nitrogen and/or oxygen and/or sulfur and which is bonded to the methylene group via a carbon atom, R1 and R2 are each hydrogen, alkyl C1-C4, alkylene C2 or aryl, and together R1 and R2 may also be an aliphatic or aromatic ring, R3 is hydrogen, alkyl C1-C4+L, hydroxylkyl C1-C3 or alkylene C2, P is the radical of a polycyclic pigment or a radical of a mix-crystal of polycyclic pigments, and n is a number from 0.0001 to 0.2, are useful for pigmenting high molecular weight materials in the form of plastic materials, melts, spinning solutions, surface coatings, paints, printing inks, baking finishes of the class of the alkyd melamine resin or acrylic melamine resin finishes, two-component coatings based on polyisocyanate-crosslinkable acrylic resins and printing inks based on nitrocellulose.
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公开(公告)号:DE58906693D1
公开(公告)日:1994-02-24
申请号:DE58906693
申请日:1989-09-18
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , URBAN MANFRED , SCHIESSLER SIEGFRIED DR
IPC: C09B3/60 , C09B57/00 , C09B57/04 , C09B57/08 , C09B57/12 , C09B67/02 , C09B67/10 , C09B67/20 , C09B67/22 , C09K23/16 , C09K23/32
Abstract: Process for the manufacture of pigment preparations of the anthanthrone series by subjecting anthanthrone crude pigments to an aqueous bead milling in the presence of dispersants of the formulae and/or where in formula (I) Q1 is the residue of an anthanthrone, azo, isoindolinone, diketopyrrolopyrrole or perinone compound, A1 is a direct bond or -O-, -S-, -NR3-, -CO-, -SO2-, -CR4R5- or arylene, X is a group or a heterocyclic radical with at least one nitrogen atom, and R3, R4, R5, R6 and R7 are hydrogen atoms or saturated or unsaturated alkyl groups and n is 1 to 4, and in formula (II) Q2 is a radical of the formula in which R1 is hydrogen, halogen, alkyl, alkoxy or cyano, or in the case where m1>1 can be a combination of these substituents, R2 is hydrogen, halogen, alkyl, alkoxy or cyano, or in the case where m2>1 can be a combination of these substituents, m1 and m2 are 1 to 4, A2 is -(CH2)p-, CR8R9-, arylene, -O-, -NR10-, -CO- or -SO2-, where p is 1 to 6, R8, R9 and R10 are hydrogen or alkyl, Y is dimethylamino or diethylamino or an imidazole or piperazine residue, and z is 1 or 2, and subjecting the resulting prepigment preparation suspensions to a thermal treatment at 20 to 200 DEG C.
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公开(公告)号:DE3785502D1
公开(公告)日:1993-05-27
申请号:DE3785502
申请日:1987-07-07
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , PROKSCHY FRANK DR
Abstract: New gold and maroon quinacridone quinone pigments comprise 98-20 mol.% of a quinacridonequinone of formula (I); 1-65 mol.% of a quinacridone of formula (II); and 1-15 mol.% of one or both acridone derivs. of formula (III) and/or (IV) in which R = H, Cl, CH3 or carbonamide gp., m and n = 1 or 2 and X = O or NH, the added cpds. (II), (III) and/or (IV) being predominantly built into the crystal lattice of the (I).
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公开(公告)号:DE3781842D1
公开(公告)日:1992-10-29
申请号:DE3781842
申请日:1987-07-07
Applicant: HOECHST AG
Inventor: DIETZ ERWIN DR , SOMMER ANDREAS DR , KROH ADOLF , HOHN JUERGEN DR , HAFNER OTMAR , RIEPER WOLFGANG DR
IPC: C08G59/14 , C08G59/06 , C08G59/24 , C08G59/32 , C08G59/50 , C08L63/00 , C09B67/46 , C09C3/08 , C09D17/00 , C09K23/00
Abstract: Addn. cpds. and their salts (I) are claimed, and their prodn. by reaction of polyepoxide(s) of formula (II) with amine(s) (H2NR2)pNH2-pR1 (III) and at least one amine (IV) of formula (IV), R3NHR4, H2N-A-R4, or H2N-Aasterisk-NR3-Aq-R4, in amts. such that 1-99% of the epoxy gps. react with (III) and 99-1% with (IV); opt., the prod. is treated with acid. n = 2-10; R, R3 = H or 1-24C alkyl; X = 2,3-epoxypropyl residue; p = 0-2; R1 = opt. unsatd. 8-24C alkyl; R2 = 1-12C alkylene; Rasterisk forms a heterocyclic ring; R4 = 2-22C opt. unsatd. (poly)nuclear carbo- or hetero-cyclic system(s) (with CH2, O, S, CO, SO, SO2, or NH links), opt. substd. with R5, Hal, OR5, NR5R6 COOR5, CONR5R6, NR5COR6, CN, CF3, or NO2 (R5, R6 = H or 1-24C alkyl), or -R7-NR8R9 (R7 = 2-200C alkylene, opt. O-interrupted, and R8, R9 = H or 1-24C alkyl), or ((CHR10)yNR11)m(CHR10)yNR8R9 (IV) or (CHR10)yN((CHR10)yNR8R9)2 (y = 2-6; m = 1-6; R8, R9, R10, R11 = H or 1-24C alkyl), or R12OR13 (R12 = 2-30C alkylene, opt. interrupted by O or NR13; R13 = H or 1-24C alkyl); A = 1-30C alkylene; Aasterisk = 1-12C alkylene; q = 0 or 1.
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公开(公告)号:DE4040469A1
公开(公告)日:1991-07-04
申请号:DE4040469
申请日:1990-12-17
Applicant: HOECHST AG
Inventor: MACHOLDT HANS-TOBIAS DR , SCHIESSLER SIEGFRIED DR , GITZEL JOERG DR , DIETZ ERWIN DR
IPC: C07C233/36 , C07C233/38 , C07C233/56 , C07C233/62 , C07C233/78 , C07C235/10 , C07D209/48 , C07D241/08 , C07D295/13 , C07D471/06 , C07D487/04 , C07F5/02 , C09D5/03 , G03G9/097
Abstract: New bis-cationic acid amide and imide derivs. of formulae (I) to (III) and their mixts. and mix crystals with mixed anions and/or cations are claimed: R1-8 independently = H or a hydrocarbon gp., opt. contg. a hetero-atom; KR1R2 and K'R4R5 may = a ring system; if R1R2, R4 or R5 is connected to K or K' by a double bond, R3 or R6 is absent and/or one of R1-3 with R7 or R4-6 with or R8 = a 2-5C aliphatic bridge; A, A' and W1 = divalent, W2 = a tetravalent and W3 = a trivalent bridge based on a hydrocarbon, opt. contg. hetero-atoms, and W1 may also = a direct bond; K and K' independently = N, P, As or Sb; X(-) = R9R10R11-R12B-; R9-12 independently = (cyclo)aliphatic, iso- or heterocyclic, aromatic or araliphatic gps. (opt. substd. by 1-4C alkyl, 1-4C alkoxy, aryl or halogen) or F. USE/ADVANTAGE - (I), (II) and (III) are useful as colourless charge transfer agents in electrophotographic toners and developers and to improve changing of powders and lacquers for surface coating, esp. in triboelectric or electrokinetic spraying of powder paints.
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