公开(公告)号：DE4419849A1

公开(公告)日：1995-12-14

申请号：DE4419849

申请日：1994-06-07

Applicant: HOECHST AG

Inventor： ALFTER FRANK DR ,  DIETZ ERWIN DR ,  KAPAUN GUSTAV DR ,  SCHIESLER SIEGFRIED DR

IPC: C07D209/44 ,  C08K5/3417 ,  C09B57/04 ,  C09D7/12 ,  D06P5/00 ,  G03G5/06 ,  C09B67/20 ,  C09D17/00 ,  C09D11/02 ,  C07D403/12 ,  C07D403/14 ,  C07D417/12 ,  C08L23/02

Abstract: Novel isoindoline pigments of formula (I) are claimed, as are also (i) prepn. of (I) by reacting an isoindoline of formula (II) having nucleophilically-exchangeable gps. X and Y in the 1- and 3-positions with a cpd. of formula (III) in which the H atoms of the -CH2- gp. are CH acids so as to give an intermediate of formula (IV) which is then reacted with a benzimidazolone of formula (V); and (ii) the use of (I) in pigmenting high mol. wt. organic materials. R = CN; R = (a) CN; (b) an (un)satd. (non)aromatic 5-7 membered N, O and/or S heterocyclic ring opt. modified by condensation or bridging to further heterocyclic or isocyclic ring systems; (c) -CONR R where R and R = H or 1-4C alkyl; or (d) -CONR R where R = unsubstd. or with at least 5 1-4C alkyl, halogen, CF3, 1-4C alkoxy, carbo(m)ethoxy or carbonamide- or with one 1-4C alkyl or phenyl gp.-substd. carbonamide, NO2, 1-4C alkylamino or OH-substd. (un)satd., (non)aromatic, iso- or hetero-cyclic (N, O and/or S) 5-7-membered ring opt. modified as per the ring of (b) above; or R and R together = ring as per (b) above opt. substd. as per (d) but excluding NO2; R = H, 1-4C alkyl, phenyl, 1-4C alkoxy, halogen or 1-4C acylamino; R = H, 1-4C alkyl, halogen, CF3, MeO, EtO or NO2; m = 1, 2, 3 or 4; n = 1, 2 or 3; and R = H or 1-4C alkyl.

公开(公告)号：DE58908732D1

公开(公告)日：1995-01-19

申请号：DE58908732

申请日：1989-09-28

Applicant: HOECHST AG

Inventor： MACHOLDT HANS-TOBIAS DR ,  KROH ADOLF ,  SIEBER ALEXANDER DR ,  DIETZ ERWIN DR

IPC: G03G9/097 ,  C09B48/00 ,  C09B67/00 ,  C09B67/20 ,  C09B67/22 ,  C09B67/52 ,  G03G9/09

Abstract: Quinacridones having selectively adjusted triboelectric effects, which quinacridones contain about 0.05% to 100 percent by weight of triboelectrically active compounds of the general formula I Q-A-Y]n (I), in which Q is a quinacridone radical which is unsubstituted or substituted by halogen atoms, alkyl, alkoxy H2N-CO-, alkyl-NH-CO- or (alkyl)2N-CO groups, A is a direct bond or -O-, -S-, -NR1-, -CO-, -SO2-, -CR2R3- or arylene and Y is an -NR4R5 group or a five-, six- or seven-membered heterocycle which contains one to three heteroatoms from the series comprising nitrogen and/or oxygen and/or sulfur and which can be substituted by alkyl, alkoxy, hydroxyphenyl, halogen, -CN, -COOH, -CO- NRR', -SO2-NRR', hydroxyalkyl or alkylaminoalkyl, in which R and R' together with the nitrogen atom can be a heterocycle, R and R' are hydrogen atoms or alkyl and R1 to R5, independently of one another, are each hydrogen and/or alkyl or alkenyl of 1 to 22 carbon atoms and n is a number from 1 to 4, and their use for the preparation of toners or developers which are used for electrophotographic copying or reproduction of originals and for printing electronically, optionally or magnetically stored information or are used in color proofing.

公开(公告)号：DE58907103D1

公开(公告)日：1994-04-07

申请号：DE58907103

申请日：1989-12-21

Applicant: HOECHST AG

Inventor： DIETZ ERWIN DR ,  URBAN MANFRED

IPC: C08K5/02 ,  C08K5/03 ,  C08K5/04 ,  C08K5/08 ,  C08K5/16 ,  C08K5/41 ,  C09B3/60 ,  C09B67/22

Abstract: Mixed-crystal pigments of the anthanthrone series consisting of two or more compounds of the formula I in which R1 and R2 denote hydrogen, chlorine, bromine, iodine or the groups nitro, cyano, amino, hydroxyl, C1-C4-alkyl, C1-C4-alkoxy, aryloxy, C1-C4-alkylsulphonyl, benzylsulphonyl, acetoxy, anilino, naphthindonylamino or phthalimido, each component being present in an amount of 1 to 99%, processes for their preparation by redyeing by the vat-dyeing method, milling in a bead mill, dry milling, dissolution in an inorganic acid and precipitation by pouring into water, and their use for pigmenting high molecular weight natural or synthetic organic materials.

公开(公告)号：ES2044876T3

公开(公告)日：1994-01-16

申请号：ES87109752

申请日：1987-07-07

Applicant: HOECHST AG

Inventor： DIETZ ERWIN DR ,  SOMMER ANDREAS DR ,  KROH ADOLF ,  HOHN JURGEN DR ,  HAFNER OTMAR ,  RIEPER WOLFGANG DR

IPC: C08G59/06 ,  C08G59/24 ,  C08G59/32 ,  C08G59/14 ,  C08G59/50 ,  C08L63/00 ,  C09B67/46 ,  C09C3/08 ,  C09D17/00 ,  C09K23/00

Abstract: Polyepoxides based on novolaks having 3 to 11 rings and a mixture of aliphatic, aromatic and/or heterocyclic amines are used to give addition compounds which are suitable as dispersants for solids in organic media.

公开(公告)号：DE4040468A1

公开(公告)日：1991-07-04

申请号：DE4040468

申请日：1990-12-17

Applicant: HOECHST AG

Inventor： MACHOLDT HANS-TOBIAS DR ,  SCHIESSLER SIEGFRIED DR ,  GITZEL JOERG DR ,  DIETZ ERWIN DR

IPC: C07C233/36 ,  C07C233/38 ,  C07C233/62 ,  C07C233/78 ,  C07C235/10 ,  C07D209/48 ,  C07D241/08 ,  C07D295/13 ,  C07D471/06 ,  C07D487/04 ,  C09D5/03 ,  C09D5/46 ,  G03F3/10 ,  G03G9/097

Abstract: Charge transfer agents for toners and developers used in electrophotographic copying and printing of data stored in an electronic, optical or magnetic system or in colour proofing and charge control agents for powder and powder paints are bis-cationic acid amide and imide derivs. of formula (I), (II) and/or (III): R1-8 independently = H or a hydrocarbon gp., opt. contg. a hetero-atom; KR1R2 and K'R4R5 may = a ring system; if R1R2, R4 or R5 is connected to K or K' by a double bond, R3 or R6 is absent and/or one of R1-3 with R7 or R4-6 with or R8 = a 2-5C aliphatic bridge; A, A' and W1 = divalent, W2 = a tetravalent and W3 = a trivalent bridge based on a hydrocarbon, opt. contg. hetero-atoms, and W1 may also = a direct bond; K and K' independently = N, P, As or Sb; X(-) the stoichiometric equiv. of (in)organic or (un)mixed anion(s). USE/ADVANTAGE - (I), (II) and (III) are colourless. The claims include their use in powders and paints for coating metals, wood, plastics, glass, ceramics, cement concrete, textiles, paper or rubber, esp. in triboelectric or electrokinetic spray powder paints. They have high and constant charge control properties, excellent temp. stability and very good dispersibility. They can be synthesised more economically than the usual charge control agents.

公开(公告)号：DE3926564A1

公开(公告)日：1991-02-14

申请号：DE3926564

申请日：1989-08-11

Applicant: HOECHST AG

Inventor： DIETZ ERWIN DR ,  URBAN MANFRED DIPL ING

IPC: C09B5/62 ,  C08K13/06 ,  C09B67/20 ,  C09B67/22 ,  C09D7/12 ,  C09D11/02 ,  C09D11/10 ,  C09D161/20 ,  C09D161/28

Abstract: PCT No. PCT/EP90/01311 Sec. 371 Date Mar. 6, 1992 Sec. 102(e) Date Mar. 6, 1992 PCT Filed Aug. 9, 1990 PCT Pub. No. WO91/02034 PCT Pub. Date Feb. 21, 1991.Pigment preparations consisting essentially of (a) at least one pigment based on perylene-3,4,9,10-tetracarboxylic dianhydride or on corresponding monoimides or diimides of tetracarboxylic acid monoanhydride, or a halogenation product thereof, (b) at least one pigment dispergent based on perylene-3,4,9,10-monoimide substituted on one or both imide nitrogen atoms by alkylene or arylene sulphonic or carboxylic acid groups or on corresponding diimides of tetracarboxylic acid monoanhydride, or a halogenation product thereof. The dispergents used appreciably enhance the key properties of perylene pigments, such as dispersibility, coloring power, stability to flocculation, transparency, rheological behavior and surface properties of the application medium. These new preparations are suitable for the pigmentation of high-quality lacquers and synthetic resins.

公开(公告)号：DE3931052A1

公开(公告)日：1990-03-22

申请号：DE3931052

申请日：1989-09-16

Applicant: HOECHST AG

Inventor： DIETZ ERWIN DR ,  SCHIESSLER SIEGFRIED DR ,  URBAN MANFRED DIPL ING

IPC: C09B57/12 ,  C09B67/22 ,  C09K23/32

Abstract: Pigment prepn. contains organic pigments (I) and basic additives, which are 1,3,6-trioxo- 1,3,6-trihydro- benzimidazo(2,1-b)benzo (1mn)(3,8)phenanthrolin-2-yl cpds. of formula (Q-A)xY (II), where Q = a gp. of formula (III), R1 = halogen, 1-4C alkyl, 1-4C alkoxy or CN; R2 = halogen; m and n = 0, 1, 2, 3 or 4; A = a chemical bond or a divalent -(CH2)p-, -CR3R4-, arylene, -S-, -O-or -NR5- gp. or a combination of these; p = 1-12; R3 and R5 = H or 1-6C alkyl; R4 = 1-6C alkyl; Y = a tert. N atom, -NR6R7, =NR8 or a satd. or unsatd. heterocyclic gp. and contains at least one tert. N atom; R6-8 = 1-20C alk(en)yl (opt. with hetero-atoms in the chain and/or terminal OH, prim. amino or acylamino gps.), a 5-6C cycloaliphatic or araliphatic gp. or an alkylene-heteroaryl gp.; x = 1-6. USE/ADVANTAGE - The prepn. is claimed for pigmenting high mol. organic materials and lacquer systems. It has much better dispersibility, flocculation stability, rheology, gloss and strength of colour than usual and is useful in plastic compsns., melts, spinning solns., lacquers, paints and printing inks.

公开(公告)号：DE3740280A1

公开(公告)日：1989-06-01

申请号：DE3740280

申请日：1987-11-27

Applicant: HOECHST AG

Inventor： DIETZ ERWIN DR ,  URBAN MANFRED DR

IPC: C07D487/06 ,  C07C231/02 ,  C07C235/84 ,  C09B3/18 ,  C09B67/00 ,  C09B67/04 ,  C09B67/10 ,  C09D7/00 ,  C09D7/12

Abstract: According to the invention, the pigment is prepared in a high-hiding pigmentary form using the known reaction of perylene-3,4,9,10-tetracarboxylic dianhydride with methylamine by using per mole of perylene-3,4,9,10-tetracarboxylic dianhydride at least 3 times the molar amount of methylamine in at least 5 times the weight of water, based on the weight of the dianhydride, carrying out the reaction at a temperature of from 40 to 200 DEG C and distilling off excess methylamine no earlier than after the perylene-3,4,9,10-tetracarboxylic dianhydride used has reacted to form methylammonium salts of the corresponding N,N'-dimethyldicarbamoylperylenedicarboxylic acids, the temperature being set after and optionally even in the course of the formation of the N,N'-dimethylperylene-3,4,9,10-tetracarboxylic diimide to 140 - 200 DEG C for some time to form a highly crystalline pigmentary form, then grinding the resulting aqueous suspension of the highly crystalline crude pigment, which has a median particle size D50% (weight distribution) of from 0.15 to 0.4 mu m and a median ratio q50% (weight distribution) of length to width of the pigment particles between 10:1 and 3:1, with or without intermediate isolation, until the median particle size is from 0.1 to 0.2 mu m and the median ratio of length to width of the pigment particles is less than 5:1, and treating the resulting prepigment in an aqueous suspension or following addition of an organic solvent in an aqueous-organic medium with heat until the pigment has a median particle size of from 0.125 to 0.4 mu m and a median ratio of length to width of pigment particles of 4:1 or less. … The pigment produced according to the invention is suitable for pigmenting macromolecular organic materials, more particularly for pigmenting automotive coatings of the type of the alkyd-melamine resin or acrylic-melamine resin baking finishes or of the type of the two-part lacquers based on polyisocyanate-crosslinkable acrylic resins.

公开(公告)号：DE3623336A1

公开(公告)日：1988-01-21

申请号：DE3623336

申请日：1986-07-11

Applicant: HOECHST AG

Inventor： DIETZ ERWIN DR ,  PROKSCHY FRANK DR

IPC: C09B67/20 ,  C09B67/14 ,  C09B67/22 ,  C09D5/44 ,  C09D7/12 ,  C09B67/52 ,  C09B48/00 ,  C09B15/00 ,  C09D17/00 ,  C09D5/38 ,  C08K5/34

Abstract: Pigments of the quinacridonequinone series consisting of 98-20 mol percent of a quinacridonequinone of the general formula (1) (1) in which R denotes a hydrogen or chlorine atom or a methyl or carbonamide group and m and n are 1 or 2, and 1-65 mol percent of a quinacridone of the general formula (2) (2) in which R, m and n have the abovementioned meaning, and 1-15 mol percent of one or two acridone derivatives of the general formulae (3) and/or (4) (3) (4) in which X denotes O or NH and R can be identical or different and, like m and n, has the abovementioned meaning, the added compounds of the general formulae (2), (3) and/or (4) being predominantly incorporated into the crystal lattice if the quinacridonequinone of the general formula (1), processes for their preparation and their use for coloring synthetic and naturally occurring materials.

公开(公告)号：DE3162115D1

公开(公告)日：1984-03-08

申请号：DE3162115

申请日：1981-07-08

Applicant: HOECHST AG

Inventor： DIETZ ERWIN DR ,  HOFFMANN ERICH DR ,  WEIDE JOACHIM

IPC: C08G65/00 ,  C07C67/00 ,  C07C213/00 ,  C07C213/04 ,  C07C217/08 ,  C07C217/32 ,  C07C217/50 ,  C08G59/14 ,  C08G59/50 ,  C08G59/64 ,  C08G65/08 ,  C08G65/26 ,  C08G65/28 ,  C09B67/20 ,  C09B67/46 ,  C09D5/00 ,  C09D5/02 ,  C09D11/02 ,  C09D17/00 ,  C07C93/06 ,  B01F17/46

Abstract: 1. A compound of the general formula X-Y-O-(-A-O-Y-O)m -A-O-Y-X wherein X represents a radical of the general formula [R**1-Gp -(O-CHR**2-CHR**3-)n ]2 N- in which R**1 is a saturated aliphatic radical having 6 to 30 carbon atoms or an unsaturated aliphatic radical having one or several ethylenic bonds and 6 to 30 carbon atoms, G is phenylene or naphthylene, p is zero or 1, R**2 and R**3 are hydrogen or methyl, but are not both methyl, and n is a number from 0 to 25, Y represents a radical of the formula see diagramm : EP0044025,P9,F1 in which R**2 and R**3 have the indicated meanings and q represents identical or different numbers from 0 to about 200, A denotes a radical of the general formula see diagramm : EP0044025,P9,F2 in which R**4 and R**5 are hydrogen or alkyl having 1 to 3 carbon atoms, and m is a number from zero to 5, n and q not both being zero.