公开(公告)号：ES2122101T3

公开(公告)日：1998-12-16

申请号：ES94111031

申请日：1994-07-15

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  BRINDOPKE GERHARD DR ,  DOSSEL KARL-FRIEDRICH DR

IPC: C08F4/28 ,  C08F4/34 ,  C08F20/10 ,  C08F20/26 ,  C08F212/08 ,  C08F220/04 ,  C08F220/12 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/32 ,  C09D5/00 ,  C09D5/03 ,  C09D133/00 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D175/04

Abstract: Copolymers comprising from 5 to 50 % by weight of one or more glycidyl esters of saturated aliphatic C4-C30-monocarboxylic acids containing a tertiary or quaternary alpha -carbon atom and from 95 to 5 % by weight of at least two olefinically unsaturated, copolymerisable monomers, of which at least one contains at least one carboxyl group. The copolymers are characterised by an OH number of from 50 to 250 mg of KOH/g, a solution viscosity of from 15 to 2000 mPa s (50 % strength solution at 23 DEG C), a mean molecular weight (weight average Mw) of less than 8600 g/mol and a nonuniformity of less than 3.4. The copolymers according to the invention are particularly suitable as binder components for high-solids coating compositions.

公开(公告)号：DK0638591T3

公开(公告)日：1998-03-16

申请号：DK94112082

申请日：1994-08-03

Applicant: HOECHST AG

Inventor： KUBILLUS UWE DR ,  SCHMIDT HOLGER DR ,  EPPLE ULRICH DR

IPC: C08F220/32 ,  C08F2/02 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F222/02 ,  C08G18/62 ,  C09D133/02 ,  C09D133/06 ,  C09D133/14 ,  C09D135/00 ,  C09D175/04

Abstract: Copolymers of particularly low viscosity which can be prepared by bulk polymerisation in which component (A) is introduced at the beginning of the polymerisation and at least two olefinically unsaturated, copolymerisable monomers (B), of which at least one contains at least one COOH group and at least one is sterically hindered, are added during the further course of the polymerisation.

公开(公告)号：DE4442769A1

公开(公告)日：1996-06-05

申请号：DE4442769

申请日：1994-12-01

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  BITTNER ANNEGRET

IPC: C08F2/00 ,  C08F2/02 ,  C08F2/06 ,  C08F220/00 ,  C08F291/00 ,  C08G63/91 ,  C08G65/32 ,  C08G69/48 ,  C08G81/02 ,  C09D133/00 ,  C09D151/00 ,  C09D153/00 ,  C09D157/00 ,  C09D161/20 ,  C09D161/28 ,  C09D163/00 ,  C09D175/04 ,  C09J157/00

Abstract: Prepn. of low mol. wt. functional polymers comprises: (1) preparing a first quantity of a mixt. (M1) from at least one component chosen from olefinic unsatd. monomers (B) and cpds. (A) which do not copolymerise with (B) but can react to form a copolymerisable addn. reaction cpd.; (2) starting polymerisation by the addn. of initiators and opt. regulators; and (3) adding an additional quantity (M2) of the (A)/(B) mixt. during polymerisation, the compsn. of (M2) being the same as or different to (M1), with the provision that an oligomer or polymer (C) is dissolved in at least one of (M1) or (M2), and at least one of (M1) or (M2) contains a component (B). Also claimed are: (i) copolymers prepd. by the process, and (ii) binders for lacquers which contain these copolymers, as well as cross-linking agents chosen from isocyanates, melamine resins or epoxy cpds.

公开(公告)号：DE4111197A1

公开(公告)日：1992-10-08

申请号：DE4111197

申请日：1991-04-06

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  SCHNELLER ARNOLD DR ,  CHERDRON HARALD PROF DR

IPC: C08L45/00 ,  C08L65/00 ,  C08L71/00 ,  C08L71/08 ,  C08L71/10

Abstract: Polymer alloys contain (A) at least one cycloolefin polymer and (B) at least one polyarylether ketone, the quantity of (A) amounting to 1 to 99 wt% and the quantity of (B) amounting to 99 to 1 wt%, whereas both quantities added together form 100 wt% of the whole alloy. Such polymer alloys are useful as matrices for composite materials or for producting mouldings.

公开(公告)号：ES2135814T3

公开(公告)日：1999-11-01

申请号：ES96106523

申请日：1996-04-25

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  OSWALD HARALD

IPC: C08F220/32 ,  C08F20/32 ,  C08F220/04 ,  C08F222/02 ,  C08F222/16 ,  C08G18/62 ,  C09D133/02 ,  C09D133/04 ,  C09D133/14 ,  C09D135/00 ,  C09J133/02 ,  C09J133/04 ,  C09J133/14 ,  C09J135/00 ,  C09K3/10

Abstract: Low-mol. wt. copolymers (I) with a wt.-average mol. wt. (Mw) of less than 3500 contain at least 20 wt.% of components with branched side chains, obtd. by the reaction of (aa) glycidyl ester(s) of satd. aliphatic monocarboxylic acids with a tert. or quat. alpha -C atom; and (ab) at least two unsatd. comonomers, at least one of which contains at least one COOH gp., under radical copolymerisation conditions. Also claimed are (i) prepn. of (I) by heating component (aa) to 210-260 degrees C and reacting with component (ab) (which contains at least 2.0 wt.% of a COOH gp.-contg. monomer) in the presence of radical initiator(s), to a degree of conversion of at least 95 (pref. at least 97.5) %; (ii) polymer mixts. contg. (I), obtd. by reaction of (aa) and (ab) as above in at least two time intervals with a constant temp. in each interval, using at least two different reaction temps., at least one of which is in the range 210-260 degrees C; (iii) polymer mixts. contg. (I) and other polymers etc.; (iv) binders for coating materials contg. (I) or the above polymer mixts.; (v) coating materials contg. binders as above and hardeners such as amino resins, capped or uncapped polyisocyanates or organic cpds. with acid and/or anhydride gps.

公开(公告)号：DE59406655D1

公开(公告)日：1998-09-17

申请号：DE59406655

申请日：1994-07-15

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  BRINDOEPKE GERHARD DR ,  DOESSEL KARL-FRIEDRICH DR

IPC: C08F4/28 ,  C08F4/34 ,  C08F20/10 ,  C08F20/26 ,  C08F212/08 ,  C08F220/04 ,  C08F220/12 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/32 ,  C09D5/00 ,  C09D5/03 ,  C09D133/00 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D175/04

Abstract: Copolymers comprising from 5 to 50 % by weight of one or more glycidyl esters of saturated aliphatic C4-C30-monocarboxylic acids containing a tertiary or quaternary alpha -carbon atom and from 95 to 5 % by weight of at least two olefinically unsaturated, copolymerisable monomers, of which at least one contains at least one carboxyl group. The copolymers are characterised by an OH number of from 50 to 250 mg of KOH/g, a solution viscosity of from 15 to 2000 mPa s (50 % strength solution at 23 DEG C), a mean molecular weight (weight average Mw) of less than 8600 g/mol and a nonuniformity of less than 3.4. The copolymers according to the invention are particularly suitable as binder components for high-solids coating compositions.

公开(公告)号：ES2114637T3

公开(公告)日：1998-06-01

申请号：ES94112082

申请日：1994-08-03

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  SCHMIDT HOLGER DR

IPC: C08F220/32 ,  C08F2/02 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F222/02 ,  C08G18/62 ,  C09D133/02 ,  C09D133/06 ,  C09D133/14 ,  C09D135/00 ,  C09D175/04

Abstract: Copolymers of particularly low viscosity which can be prepared by bulk polymerisation in which component (A) is introduced at the beginning of the polymerisation and at least two olefinically unsaturated, copolymerisable monomers (B), of which at least one contains at least one COOH group and at least one is sterically hindered, are added during the further course of the polymerisation.

公开(公告)号：DE59405158D1

公开(公告)日：1998-03-05

申请号：DE59405158

申请日：1994-08-03

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  SCHMIDT HOLGER DR

IPC: C08F220/32 ,  C08F2/02 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F222/02 ,  C08G18/62 ,  C09D133/02 ,  C09D133/06 ,  C09D133/14 ,  C09D135/00 ,  C09D175/04

Abstract: Copolymers of particularly low viscosity which can be prepared by bulk polymerisation in which component (A) is introduced at the beginning of the polymerisation and at least two olefinically unsaturated, copolymerisable monomers (B), of which at least one contains at least one COOH group and at least one is sterically hindered, are added during the further course of the polymerisation.

公开(公告)号：AT162806T

公开(公告)日：1998-02-15

申请号：AT94112082

申请日：1994-08-03

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  KUBILLUS UWE DR ,  SCHMIDT HOLGER DR

IPC: C08F220/32 ,  C08F2/02 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F222/02 ,  C08G18/62 ,  C09D133/02 ,  C09D133/06 ,  C09D133/14 ,  C09D135/00 ,  C09D175/04

Abstract: Copolymers of particularly low viscosity which can be prepared by bulk polymerisation in which component (A) is introduced at the beginning of the polymerisation and at least two olefinically unsaturated, copolymerisable monomers (B), of which at least one contains at least one COOH group and at least one is sterically hindered, are added during the further course of the polymerisation.

公开(公告)号：DE4435950A1

公开(公告)日：1996-04-11

申请号：DE4435950

申请日：1994-10-07

Applicant: HOECHST AG

Inventor： EPPLE ULRICH DR ,  SCHMIDT HOLGER DR ,  BRINDOEPKE GERHARD DR ,  DOESSEL KARL-FRIEDRICH DR

IPC: C08F220/16 ,  C08F2/02 ,  C08F4/04 ,  C08F4/32 ,  C08F20/10 ,  C08F220/18 ,  C08F220/26 ,  C08G18/62 ,  C09D5/02 ,  C09D5/03 ,  C09D133/04 ,  C09D133/06 ,  C09D135/00 ,  C09J133/04 ,  C09J133/06 ,  C08F6/02 ,  B05D7/16 ,  C09D125/02

Abstract: Copolymers (I) of olefinic monomer(s) comprise an isomeric mixt. of esters of isobornyl alcohol with an alpha , beta -unsatd. acid. The isomeric alcohol mixt. contains: (a) not more than 92% isoborneol, (b) at least 3.5% iso-fenchyl alcohol, and (c) at least 1% pseudo-bornyl alcohol. Also claimed are: (i) a process for the prodn. of (I) by bulk polymerisation in the presence of aliphatic azo cpds., diacyl peroxide, alkyl per-esters, alkyl hydroperoxide, dialkyl peroxide or peroxy-di-carbonate as radical initiators; and (ii) a process for the prodn. of water-dilutable polyacrylate dispersions by: (A) dissolution of (I) in a water-dilutable organic solvent, followed by: (B) partial or complete neutralisation, and (C) dilution by adding water or stirring the soln. into water.