11.
    发明专利
    未知

    公开(公告)号:DE58907760D1

    公开(公告)日:1994-07-07

    申请号:DE58907760

    申请日:1989-09-19

    Applicant: HOECHST AG

    Abstract: Novel optically active esters of 5-ethyl- and 5-vinyl-1,3- dioxolane-4-carboxylic acid, their use as dopes in liquid-crystal mixtures, and liquid-crystal mixtures containing the novel esters. Optically active 1,3-dioxolanyl derivatives of the general formula (I) are suitable as dopes in liquid-crystal mixtures. The symbols in the general formula have the following meanings: R has an analogous structure to the moiety on the right of X in the general formula or is an alkyl or alkylene radical, which may be substituted, R and R are H or alkyl, which may also be substituted [R and R are alternatively, together with the C(2) of the dioxolane ring, a cycloaliphatic radical] R is vinyl or ethyl, with the proviso that at least one radical R is vinyl or ethyl if R is analogous to the moiety on the right of X in the formula (I), -A , -A and -A are aromatic, heterocyclic or aliphatic ring systems, -M and -M are -CO-O, -O-CO, -CH2CH2, -CH=CH, -CH2O,-OCH2 or -C=C, and X is O, S or O-CO-O. The particular advantage of the compound of the general formula (I) is that it is able to induce high twisting power in a cholesteric phase.

    12.
    发明专利
    未知

    公开(公告)号:AT106402T

    公开(公告)日:1994-06-15

    申请号:AT89117265

    申请日:1989-09-19

    Applicant: HOECHST AG

    Abstract: Novel optically active esters of 5-ethyl- and 5-vinyl-1,3- dioxolane-4-carboxylic acid, their use as dopes in liquid-crystal mixtures, and liquid-crystal mixtures containing the novel esters. Optically active 1,3-dioxolanyl derivatives of the general formula (I) are suitable as dopes in liquid-crystal mixtures. The symbols in the general formula have the following meanings: R has an analogous structure to the moiety on the right of X in the general formula or is an alkyl or alkylene radical, which may be substituted, R and R are H or alkyl, which may also be substituted [R and R are alternatively, together with the C(2) of the dioxolane ring, a cycloaliphatic radical] R is vinyl or ethyl, with the proviso that at least one radical R is vinyl or ethyl if R is analogous to the moiety on the right of X in the formula (I), -A , -A and -A are aromatic, heterocyclic or aliphatic ring systems, -M and -M are -CO-O, -O-CO, -CH2CH2, -CH=CH, -CH2O,-OCH2 or -C=C, and X is O, S or O-CO-O. The particular advantage of the compound of the general formula (I) is that it is able to induce high twisting power in a cholesteric phase.

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