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公开(公告)号:DE58907760D1
公开(公告)日:1994-07-07
申请号:DE58907760
申请日:1989-09-19
Applicant: HOECHST AG
Inventor: MUELLER INGRID DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , ILLIAN GERHARD DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: G02F1/13 , C07D317/24 , C07D317/30 , C07D317/32 , C07D405/12 , C07D405/14 , C09K19/34 , C09K19/54 , G09F9/35
Abstract: Novel optically active esters of 5-ethyl- and 5-vinyl-1,3- dioxolane-4-carboxylic acid, their use as dopes in liquid-crystal mixtures, and liquid-crystal mixtures containing the novel esters. Optically active 1,3-dioxolanyl derivatives of the general formula (I) are suitable as dopes in liquid-crystal mixtures. The symbols in the general formula have the following meanings: R has an analogous structure to the moiety on the right of X in the general formula or is an alkyl or alkylene radical, which may be substituted, R and R are H or alkyl, which may also be substituted [R and R are alternatively, together with the C(2) of the dioxolane ring, a cycloaliphatic radical] R is vinyl or ethyl, with the proviso that at least one radical R is vinyl or ethyl if R is analogous to the moiety on the right of X in the formula (I), -A , -A and -A are aromatic, heterocyclic or aliphatic ring systems, -M and -M are -CO-O, -O-CO, -CH2CH2, -CH=CH, -CH2O,-OCH2 or -C=C, and X is O, S or O-CO-O. The particular advantage of the compound of the general formula (I) is that it is able to induce high twisting power in a cholesteric phase.
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公开(公告)号:AT106402T
公开(公告)日:1994-06-15
申请号:AT89117265
申请日:1989-09-19
Applicant: HOECHST AG
Inventor: MUELLER INGRID DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , ILLIAN GERHARD DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: G02F1/13 , C07D317/24 , C07D317/30 , C07D317/32 , C07D405/12 , C07D405/14 , C09K19/34 , C09K19/54 , G09F9/35
Abstract: Novel optically active esters of 5-ethyl- and 5-vinyl-1,3- dioxolane-4-carboxylic acid, their use as dopes in liquid-crystal mixtures, and liquid-crystal mixtures containing the novel esters. Optically active 1,3-dioxolanyl derivatives of the general formula (I) are suitable as dopes in liquid-crystal mixtures. The symbols in the general formula have the following meanings: R has an analogous structure to the moiety on the right of X in the general formula or is an alkyl or alkylene radical, which may be substituted, R and R are H or alkyl, which may also be substituted [R and R are alternatively, together with the C(2) of the dioxolane ring, a cycloaliphatic radical] R is vinyl or ethyl, with the proviso that at least one radical R is vinyl or ethyl if R is analogous to the moiety on the right of X in the formula (I), -A , -A and -A are aromatic, heterocyclic or aliphatic ring systems, -M and -M are -CO-O, -O-CO, -CH2CH2, -CH=CH, -CH2O,-OCH2 or -C=C, and X is O, S or O-CO-O. The particular advantage of the compound of the general formula (I) is that it is able to induce high twisting power in a cholesteric phase.
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公开(公告)号:AT104301T
公开(公告)日:1994-04-15
申请号:AT89114603
申请日:1989-08-08
Applicant: HOECHST AG
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公开(公告)号:AT103905T
公开(公告)日:1994-04-15
申请号:AT88115002
申请日:1988-09-14
Applicant: HOECHST AG
Inventor: WINGEN RAINER DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , MUELLER INGRID DR , OHLENDORF DIETER DR
IPC: C07D239/26 , C07D239/34 , C09K19/34 , C09K19/46 , G02F1/137 , G02F1/141
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公开(公告)号:AT100132T
公开(公告)日:1994-01-15
申请号:AT88115003
申请日:1988-09-14
Applicant: HOECHST AG
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公开(公告)号:AT92921T
公开(公告)日:1993-08-15
申请号:AT88104520
申请日:1988-03-22
Applicant: HOECHST AG
Inventor: MUELLER INGRID DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: G02F1/137 , C07D239/26 , C07D239/34 , C07D239/38 , C09K19/34 , G02F1/141
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公开(公告)号:AT82584T
公开(公告)日:1992-12-15
申请号:AT89114602
申请日:1989-08-08
Applicant: HOECHST AG
Inventor: HEMMERLING WOLFGANG DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , ILLIAN GERHARD DR , INOGUCHI YOSHIO DR , MUELLER INGRID DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: G02F1/13 , C07D307/24 , C07D307/56 , C07D405/12 , C07D405/14 , C07D407/12 , C07D407/14 , C07D409/12 , C07D409/14 , C07D417/12 , C07D417/14 , C09K19/54 , C09K19/58 , G02F1/137 , G02F1/141
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公开(公告)号:AT58394T
公开(公告)日:1990-11-15
申请号:AT88105777
申请日:1988-04-12
Applicant: HOECHST AG
Inventor: WINGEN RAINER DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , MUELLER INGRID DR , OHLENDORF DIETER DR
IPC: C07D317/24 , C07D317/32 , C07D317/72 , C07D405/12 , C07D407/12 , C07D409/12 , C09K19/02 , C09K19/34 , C09K19/54 , C09K19/58 , G02F1/133 , G02F1/137 , G02F1/141
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公开(公告)号:AT57918T
公开(公告)日:1990-11-15
申请号:AT87107658
申请日:1987-05-26
Applicant: HOECHST AG
Inventor: HEPPKE GERD PROF DR , BAHR CHRISTIAN , MUELLER INGRID DR , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: C07D239/26 , C09K19/34
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公开(公告)号:DE3909355A1
公开(公告)日:1990-09-27
申请号:DE3909355
申请日:1989-03-22
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HARADA TAKAMASA , HEMMERLING WOLFGANG DR , ILLIAN GERHARD DR , MUELLER INGRID DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
Abstract: Ferroelectric liquid crystal mixtures are based on at least 2 mixing components of general formula (I) and contain, in addition, at least one optically active dopant from one or more of the following groups: (a) optically active esters of tetrahydrofuran-2-carboxylic acid; (b) optically active aryl-2,3-epoxyalkyl ethers; (c) optically active 1,3-dioxolan-4-yl-ethers. Said mixtures possess high spontaneous polarization and permit substantial compensation of the pitch of the helix in a nematic phase.
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