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公开(公告)号：EP0206311A2
公开(公告)日：1986-12-30
申请号：EP86108576
申请日：1986-06-24
Applicant: HOECHST AG
Inventor： OHLENDORF DIETER DR , INTERTHAL WERNER DR , STOLL FRIEDRICH DR
CPC classification number: C23F11/149 , C23F11/141 , C23F11/147
Abstract: Verwendung der Verbindungen der Formel R1 C12-C26-Alkyl oder C12-C26-Alkenyl, n eine Zahl von 0 bis 5, C1-C3-Alkyl, R3 C1-C3-Alkyl oder eine Gruppe der Formel -(C2H4O)xH, x eine Zahl von 1 bis 3, A ein Anion, R9 eine Gruppe der Formel R1'-(OCH2CH2)n-, C8-C18-Alkylaryl oder Aryl-C8-C18-alkyl, R1' C14-C22-Alkyl oder C14-C22-Alkenyl, n eine Zahl von 0 bis 5 und die Reste R10 gleich sind und C1-C4-Alkyl oder C1-C4-Hydroxialkyl bedeuten, als Korrosionsschutzmittel für metallische Werkstoffe in wässrigen Medien.
Abstract translation: 式
R1 C12-C26烷基或C12-C26链烯基，n的化合物的用途是一个从0到5， C1-C3烷基，R3 C1-C3烷基或下式基团的 - （C2H4O）XH，x是一个从1到3，<（ - ）>是阴离子，R 9为下式基团R1“的 - （OCH 2 CH 2）N - ，C8-C18烷基芳基，或芳基 - 的C8-C18烷基， R1“C14-C22烷基或C14-C22链烯基，n是从0到5的数和基团R 10是相同的并且是C1-C4烷基或C1-C4羟烷基的意思是，作为腐蚀抑制剂金属材料在含水介质中。 -
公开(公告)号：DE59009764D1
公开(公告)日：1995-11-16
申请号：DE59009764
申请日：1990-07-31
Applicant: HOECHST AG
Inventor： ESCHER CLAUS DR , DUEBAL HANS-ROLF DR , FELDHUES MICHAEL DR , HARADA TAKAMASA , ILLIAN GERHARD DR , MECKLENBURG THOMAS DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , PAMPUS KARL DR
IPC: C08G61/12 , G02F1/1337 , G02F1/141 , G09F9/35
Abstract: Switching and display elements based on ferroelectric liquid-crystals often exhibit a pronounced optical hysteresis which results in the appearance of so-called ghost images. This phenomenon can be markedly reduced or even suppressed if at least one of the two orienting layers are in direct contact with the electrodes and is composed of an electrically conductive polymer of the formula (I): (I) in which R1, R2=independently of each other, H, or straight-chain or branched alkyl or alkoxy containing 1-16 carbon atoms, or halogen, X=S, NH, Y-=BF4-, PF6-, PO43-, AsF6-, SbCl6-, SO42-, HSO4-, alkyl-SO3-, perfluoroalkyl-SO3-, aryl-SO3, F- or Cl-, and n is an integer from 4 to 100 and m is an integer from 1 to 30.
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公开(公告)号：DE58907440D1
公开(公告)日：1994-05-19
申请号：DE58907440
申请日：1989-08-08
Applicant: HOECHST AG
Inventor： HEMMERLING WOLFGANG DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , ILLIAN GERHARD DR , INOGUCHI YOSHIO DR , MUELLER INGRID DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
Abstract: The novel silylalkyl or -alkenyl compounds conform to the general formula (I) in which A , A and A are aromatic or heteroaromatic molecular units such as 1,4-phenylene or pyrimidine-2,5-diyl which are linked via a single bond (where k and m are zero) or via functional groups M and M , such as CO-O or CH2-O; j, k, l, m and n are zero or 1 (j + l + n = 2 or 3), the radicals R , R , R and R are H or alkyl/alkenyl or cycloalkyl, the radicals R , R and R have a comparable meaning (H); R is alkyl/alkenyl or a substituent known from LC chemistry, such as an alpha -haloalkanoic acid radical. The compounds have liquid-crystalline phases, which are in some cases broad and polymorphous.
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公开(公告)号：AT99304T
公开(公告)日：1994-01-15
申请号：AT89113045
申请日：1989-07-15
Applicant: HOECHST AG
Inventor： SCHEROWSKY GUENTER PROF , GAY JUERGEN , WINGEN RAINER DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , INOGUCHI YOSHIO DR , MUELLER INGRID DR , OHLENDORF DIETER DR
IPC: G02F1/13 , C07D317/22 , C07D317/24 , C07D317/36 , C07D317/72 , C07D405/12 , C07D405/14 , C07D407/12 , C07D409/12 , C07D409/14 , C07D417/12 , C07D417/14 , C09K19/34 , C09K19/54 , C09K19/58 , G02F1/137 , G02F1/33
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公开(公告)号：AT98381T
公开(公告)日：1993-12-15
申请号：AT88105353
申请日：1988-04-02
Applicant: HOECHST AG
Inventor： BAHR CHRISTIAN , HEPPKE GERD PROF DR , LOETZSCH DETLEF , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , OHLENDORF DIETER DR
IPC: C09K19/02 , C07D303/48 , C07D405/12 , C09K19/58 , G02F1/137 , G02F1/139 , G02F1/141 , G02F1/361 , G02F1/37
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Patent Agency Ranking
公开(公告)号：DE3679597D1
公开(公告)日：1991-07-11
申请号：DE3679597
申请日：1986-06-24
Applicant: HOECHST AG
Inventor： OHLENDORF DIETER DR , INTERTHAL WERNER DR , STOLL FRIEDRICH DR
Abstract: Use of the compounds of the formula in which R1 denotes C12-C26-alkyl or C12-C26alkenyl, n denotes a number from 0 to 5, K(+) denotes a group of the formulae or a group of the formula -(C2H4O)xH, x denotes a number from 1 to 3, A(-denotes an anion, R9 denotes a group of the formula R1'-(OCH2CH2)n-, C8-C18-alkylaryl or aryl-C8-C18-alkyl, R1' denotes C14-C22-alkyl or C14-C22-alkenyl, n denotes a number from 0 to 5 and the radicals R10 are identical and denote C1-C4-alkyl or C1-C4-hydroxyalkyl, as corrosion protection agents for metallic materials in aqueous media.
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公开(公告)号：DE3925971A1
公开(公告)日：1991-02-07
申请号：DE3925971
申请日：1989-08-05
Applicant: HOECHST AG
Inventor： ESCHER CLAUS DR , DUEBAL HANS-ROLF DR , HARADA TAKAMASA , HEMMERLING WOLFGANG DR , ILLIAN GERHARD DR , MUELLER INGRID DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WEGENER PETER DR , WINGEN RAINER DR
Abstract: The novel liquid crystalline mixtures, which additionally contain an optically active compound as a dopant in the case of ferroelectric behaviour are based on at least 2 components of the general formula (I) and at least one carboxylic ester of the general formula (XI) or (XII) in which x is an integer of from 2 to 14 and n is an integer of from 6 to 14 in which a and b independently of one another may denote an integer of from 2 to 14 and -X- may denote an or an -O- group; in which A denotes, for example, pyrimidine-2,5-diyl, -Y- denotes, for example, -O- or -S-, -M- denotes, for example, -O- or -CH2-, -R denotes, for example, CH3 and c, d and e denote, for example, integers such as 2, 3 or 4. The mixtures, which may also contain further components, have advantageous properties for use in electrooptical display elements, such as low melting points and low crystallisation temperatures.
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公开(公告)号：DE3907601A1
公开(公告)日：1990-09-13
申请号：DE3907601
申请日：1989-03-09
Applicant: HOECHST AG
Inventor： MUELLER INGRID DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , HEMMERLING WOLFGANG DR , ILLIAN GERHARD DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: G02F1/13 , C07D317/30 , C07D317/72 , C07D405/12 , C07D409/12 , C09K19/06 , C09K19/34 , C09K19/58
Abstract: Optically active 1,3 dioxolane derivatives containing a mesogenic residue, of the general formula (I), are suitable as doping agents especially in ferro-electrical liquid crystal mixtures. The meanings of the symbols in the general formula are: R is constructed similarly to the part of the general formula to the right of X or an alkyl or alkylene residue which may be substituted; R , R , R = H or alkyl (R may also be alkenyl) which may also be substituted [R , R together with the C(2) of the dioxolane ring may be a cycloaliphate or a keto group]; j, l, n = zero, 1 or 2 and k, m = zero or 1 provided that if k = zero, n = zero also, if n = zero, m = zero also and l , -A , -A = aromatic, heterocyclic or aliphatic ring system; -M ,- M = -CO-O, -O-CO, -CH2CH2, -CH=CH, -CH2O, -OCH2, -C=C and X = CH=CH, CH2-CH2. The special advantage of the compounds with the general formula (I) is that they can induce a high twisting capacity in a cholesteric phase without substantially affecting in the smectic C* phase the value of the spontaneous polarisation already in the mixture. They are therefore suitable for pitch compensation, especially for ferro-electrical liquid crystal mixtures.
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公开(公告)号：DE3827600A1
公开(公告)日：1990-02-15
申请号：DE3827600
申请日：1988-08-13
Applicant: HOECHST AG
Inventor： HEMMERLING WOLFGANG DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , ILLIAN GERHARD DR , INOGUCHI YOSHIO DR , MUELLER INGRID DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
Abstract: The novel silylalkyl or -alkenyl compounds conform to the general formula (I) in which A , A and A are aromatic or heteroaromatic molecular units such as 1,4-phenylene or pyrimidine-2,5-diyl which are linked via a single bond (where k and m are zero) or via functional groups M and M , such as CO-O or CH2-O; j, k, l, m and n are zero or 1 (j + l + n = 2 or 3), the radicals R , R , R and R are H or alkyl/alkenyl or cycloalkyl, the radicals R , R and R have a comparable meaning (H); R is alkyl/alkenyl or a substituent known from LC chemistry, such as an alpha -haloalkanoic acid radical. The compounds have liquid-crystalline phases, which are in some cases broad and polymorphous.
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公开(公告)号：DE3827599A1
公开(公告)日：1990-02-15
申请号：DE3827599
申请日：1988-08-13
Applicant: HOECHST AG
Inventor： HEMMERLING WOLFGANG DR , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , ILLIAN GERHARD DR , INOGUCHI YOSHIO DR , MUELLER INGRID DR , MURAKAMI MIKIO , OHLENDORF DIETER DR , WINGEN RAINER DR
IPC: G02F1/13 , C07D307/24 , C07D307/56 , C07D405/12 , C07D405/14 , C07D407/12 , C07D407/14 , C07D409/12 , C07D409/14 , C07D417/12 , C07D417/14 , C09K19/54 , C09K19/58 , G02F1/137 , G02F1/141
Abstract: Optically active tetrahydrofuran-2-carboxylic acid esters containing a mesogenic molecular building block are suitable as dopes in liquid-crystal mixtures. They result in liquid-crystalline ferroelectric phases having short switching times and in electroclinic phases having high electroclinic coefficients. A further advantage is that they induce a helix of very low pitch, so they are also suitable for helix compensation in LC mixtures. The compounds are symbolised by the general formula in which the symbols and indices essentially have the following meanings: R = alkyl/alkenyl or tetrahydrofurancarbonyloxy or -thio; j, l and n = zero, 1 or 2; k and m = zero or 1; -A , -A and -A = phenylene, cycloalkylene or corresponding N-, O- or S-containing heterocycles; -M and -M = bridges, such as -CO-O-, -OCH2- or -CH=CH-; and X = O or S.
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