公开(公告)号：NO310874B1

公开(公告)日：2001-09-10

申请号：NO955306

申请日：1995-12-27

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  FRITZE CORNELIA ,  HERRMANN HANS-FRIEDRICH ,  KUEBER FRANK ,  SPALECK WALTER ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/622 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C07F7/00

Abstract: Polynuclear metallocene cpds. of formula L X2-L )-ÄB(L -M X2-L )Ük-B-L X2-L ) (I) are new: M = tetravalent metal; L -L = -ligands; B = divalent bridging unit; X = H, halogen, 1-10 C fluorocarbyl or 1-40 C hydrocarbyl; and k = 0-10. Also claimed are (i) catalyst components contg. (a) cpd(s) of formula (I) and (b) cocatalysts(s), and (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of the above catalyst combination.

公开(公告)号：CA2175159A1

公开(公告)日：1996-10-28

申请号：CA2175159

申请日：1996-04-26

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  BREKNER MICHAEL-JOACHIM ,  KUEBER FRANK ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/64 ,  C08F4/642 ,  C08F4/68 ,  C08F4/69 ,  C08F10/00 ,  C08F4/42

Abstract: The present invention relates to a metallocene compound containing at least two metallocene fragments L-MX2-L which are different from one another and having the formula I (I) where B is a bridging unit, m is an integer from 2 to 100,000, M is a metal atom of group IVb, Vb or VIb of the Periodic Table of the Elements, X are identical or different in one metallocene fragment L-MX2-L and are each, independently of one another, hydrogen, a C1-C40-hydrocarbon-containing group, an OH group, a halogen atom or a pseudohalogen, L are identical or different in one metallocene fragment and are each, independently of one another, a n ligand or another electron donor. The metallocene compound can advantageously be used as a catalyst component for olefin polymerization.

公开(公告)号：ZA963337B

公开(公告)日：1996-08-27

申请号：ZA963337

申请日：1996-04-26

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  BREKNER MICHAEL-JOACHIM ,  KUEBER FRANK ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F10/00 ,  C07F ,  C08F

公开(公告)号：ZA9603337B

公开(公告)日：1996-08-27

申请号：ZA9603337

申请日：1996-04-26

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  BREKNER MICHAEL-JOACHIM ,  KUEBER FRANK ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F10/00 ,  C07F ,  C08F

CPC classification number: C07F17/00 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/61927 ,  C08F10/00

公开(公告)号：FI956280A0

公开(公告)日：1995-12-27

申请号：FI956280

申请日：1995-12-27

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  FRITZE CORNELIA ,  HERRMANN HANS-FRIEDRICH ,  KUEBER FRANK ,  SPALECK WALTER ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/622 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C07F ,  C08F

Abstract: Polynuclear metallocene cpds. of formula L X2-L )-ÄB(L -M X2-L )Ük-B-L X2-L ) (I) are new: M = tetravalent metal; L -L = -ligands; B = divalent bridging unit; X = H, halogen, 1-10 C fluorocarbyl or 1-40 C hydrocarbyl; and k = 0-10. Also claimed are (i) catalyst components contg. (a) cpd(s) of formula (I) and (b) cocatalysts(s), and (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of the above catalyst combination.

公开(公告)号：AU718870B2

公开(公告)日：2000-04-20

申请号：AU5080796

申请日：1996-04-22

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  BREKNER MICHAEL-JOACHIM ,  KUBER FRANK ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/64 ,  C08F4/642 ,  C08F4/68 ,  C08F4/69 ,  C08F10/00 ,  C08F4/76 ,  C08F4/78 ,  C08F4/643

Abstract: Metallocene cpds. of formula (I) with at least two different metallocene fragments L-MX2-L are new: (I) B = bridging unit; m = 2-100,000; M = Gp. IVb, Vb or VIb metal; X = H, 1-40C hydrocarbon-contg. gp., OH, halogen or pseudohalogen L = a pi-ligand or other electron donor. Also claimed is (i) a catalyst component contg. cpd(s). (I) and cocatalyst(s); (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of a catalyst as in (i); (iii) polyolefins obtd. by this process.

公开(公告)号：BR9705184A

公开(公告)日：1999-05-11

申请号：BR9705184

申请日：1997-10-30

Applicant: HOECHST AG

Inventor： BINGEL CARSTEN ,  HUEBSCHER ERICH ,  NIESERT CLAUS-PETER ,  ZENK ROLAND

IPC: B01J23/42 ,  B01J23/44 ,  C07B61/00 ,  C07F17/00 ,  C08F4/76

Abstract: A process for the hydrogenation of metallocenes, in which metallocene(s) with at least one double bond and/or at least one aromatic substituent (I) is/are reacted in non-halogenated solvent(s) with hydrogen in presence of hydrogenation catalyst(s).

公开(公告)号：BR9606033A

公开(公告)日：1998-09-01

申请号：BR9606033

申请日：1996-12-17

Applicant: HOECHST AG

Inventor： STREB JOHANN ,  RINK THOMAS ,  ZENK ROLAND ,  RIEDEL MICHAEL ,  CABRERA IVAN ,  KAUFMANN WILHELM ,  WISSER THOMAS

IPC: C07F17/00

Abstract: A method for the depletion of inorganic byproducts from product mixtures produced during the synthesis of metallocenes comprises treating the mixture, which contains one or more metallocenes and at least one inorganic byproduct, with a polar extraction agent. Also claimed is the use of polar extraction agents for removing inorganic byproducts from metallocene synthesis product mixtures. Preferably the mixture is a crude metallocene synthesis reaction product. The extraction agent contains 5 - 100 vol.% one or more polar solvents. The amount of inorganic byproducts is reduced to less than 5 wt.%. The byproducts are inorganic salts and / or covalent metal halides.

公开(公告)号：NO955306L

公开(公告)日：1996-07-01

申请号：NO955306

申请日：1995-12-27

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  FRITZE CORNELIA ,  HERRMANN HANS-FRIEDRICH ,  KUBER FRANK ,  SPALECK WALTER ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/622 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C07F7/00

Abstract: Polynuclear metallocene cpds. of formula L X2-L )-ÄB(L -M X2-L )Ük-B-L X2-L ) (I) are new: M = tetravalent metal; L -L = -ligands; B = divalent bridging unit; X = H, halogen, 1-10 C fluorocarbyl or 1-40 C hydrocarbyl; and k = 0-10. Also claimed are (i) catalyst components contg. (a) cpd(s) of formula (I) and (b) cocatalysts(s), and (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of the above catalyst combination.

公开(公告)号：NO955306D0

公开(公告)日：1995-12-27

申请号：NO955306

申请日：1995-12-27

Applicant: HOECHST AG

Inventor： AULBACH MICHAEL ,  FRITZE CORNELIA ,  HERRMANN HANS-FRIEDRICH ,  KUBER FRANK ,  SPALECK WALTER ,  ZENK ROLAND

IPC: C07F17/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/622 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C07F

Abstract: Polynuclear metallocene cpds. of formula L X2-L )-ÄB(L -M X2-L )Ük-B-L X2-L ) (I) are new: M = tetravalent metal; L -L = -ligands; B = divalent bridging unit; X = H, halogen, 1-10 C fluorocarbyl or 1-40 C hydrocarbyl; and k = 0-10. Also claimed are (i) catalyst components contg. (a) cpd(s) of formula (I) and (b) cocatalysts(s), and (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of the above catalyst combination.