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公开(公告)号：NO310874B1
公开(公告)日：2001-09-10
申请号：NO955306
申请日：1995-12-27
Applicant: HOECHST AG
Inventor： AULBACH MICHAEL , FRITZE CORNELIA , HERRMANN HANS-FRIEDRICH , KUEBER FRANK , SPALECK WALTER , ZENK ROLAND
IPC: C07F17/00 , C08F4/60 , C08F4/62 , C08F4/622 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C07F7/00
Abstract: Polynuclear metallocene cpds. of formula L X2-L )-ÄB(L -M X2-L )Ük-B-L X2-L ) (I) are new: M = tetravalent metal; L -L = -ligands; B = divalent bridging unit; X = H, halogen, 1-10 C fluorocarbyl or 1-40 C hydrocarbyl; and k = 0-10. Also claimed are (i) catalyst components contg. (a) cpd(s) of formula (I) and (b) cocatalysts(s), and (ii) a process for the prodn. of olefin polymers by polymerisation of olefin(s) in presence of the above catalyst combination.
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公开(公告)号：NO307520B1
公开(公告)日：2000-04-17
申请号：NO944949
申请日：1994-12-20
Applicant: HOECHST AG
Inventor： WELLER THOMAS , AULBACH MICHAEL , KUEBER FRANK , ERKER GERHARD , PSIORZ CHRISTIAN , BACHMANN BERND , OSAN FRANK
IPC: B01J31/22 , B01J31/06 , C07C13/15 , C07F5/00 , C07F5/06 , C07F7/00 , C07F7/02 , C07F9/00 , C07F17/00 , C08F4/42 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F210/18
Abstract: The present invention relates to a sterically rigid metallocene compound which, as ligands, contains at least two substituted or unsubstituted cyclopentadienyl groups which are bonded to one another via a mono- or polycyclic ring system, at least one cyclopentadienyl group being fused to the mono- or polycyclic ring system, and to a process for the preparation of a cycloolefin copolymer. The cycloolefin copolymers thus obtained have high tensile strengths and are suitable for the production of extruded parts and injection-moulded articles.
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公开(公告)号：NO307216B1
公开(公告)日：2000-02-28
申请号：NO954012
申请日：1995-10-09
Applicant: HOECHST AG
Inventor： HERRMANN HANS-FRIEDRICH , AULBACH MICHAEL , KUEBER FRANK
IPC: C07C2/34 , C07F17/00 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/6592 , C08F4/68 , C08F10/00
Abstract: A metallocene cpd. of formula (I) is new: In (I), M = Gp. IVb, Vb or VIb metal; R , R = H, 1-10C alkyl or alkoxy, 6-10C aryl or aryloxy, 2-10C alkenyl, 7-40C aralkyl, 8-40C aralkenyl, OH or halogen; R -R = H, halogen, opt. halogenated 1-20C hydrocarbyl, -NR2, -SR, -OR, -OSiR3, -SiR3 or -PR2 (with R = halogen, 1-10C alkyl or 6-10C aryl); or two or more of these gps. may form a ring system with the attached atoms; and R '-R ' = as for R -R . Also claimed are: (i) olefin polymerisation catalysts contg. cpd(s). (I) and a co-catalyst; and (ii) a process for the prodn. of olefin polymers by (co)polymerisation of olefins in the presence of (I) and a co-catalyst.
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公开(公告)号：ZA965141B
公开(公告)日：1997-01-23
申请号：ZA965141
申请日：1996-06-18
Applicant: HOECHST AG
Inventor： AULBACH MICHAEL , KUEBER FRANK , RIEDEL MICHAEL , HELMER-METZMANN FREDDY
IPC: C07F17/00 , C08F4/60 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/622 , C08F4/642 , C08F4/6592 , C08F10/00 , C08F
Abstract: Stereo-rigid metallocene cpds. contain, as ligands: (i) substd. or unsubstituted cyclopentadienyl gps. linked together by a 5-membered ring condensed with the cyclopentadienyl gp(s)., where: (1) the ligand system is other than 4-Ä eta -3'-alkyl-cyclopentadienyl)-4,6,6-trimethyl-( eta -2-alkyl- 4,5-tetrahydro-pentalene)Ü. Also claimed are: (i) a catalyst contg. stereo-rigid metallocene and cocatalyst(s); (ii) a process for the prodn. of polyolefins by polymerisation of olefins in presence of the catalyst; (iii) use of the stereo-rigid metallocene cpd. for olefin polymerisation; and (iv) polyolefin obtd. by the process.
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公开(公告)号：NO962577L
公开(公告)日：1996-12-20
申请号：NO962577
申请日：1996-06-18
Applicant: HOECHST AG
Inventor： AULBACH MICHAEL , KUBER FRANK , RIEDEL MICHAEL , HELMER-METZMANN FREDDY
IPC: C07F17/00 , C08F4/60 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/622 , C08F4/642 , C08F4/6592 , C08F10/00 , C08F4/64
Abstract: Stereo-rigid metallocene cpds. contain, as ligands: (i) substd. or unsubstituted cyclopentadienyl gps. linked together by a 5-membered ring condensed with the cyclopentadienyl gp(s)., where: (1) the ligand system is other than 4-Ä eta -3'-alkyl-cyclopentadienyl)-4,6,6-trimethyl-( eta -2-alkyl- 4,5-tetrahydro-pentalene)Ü. Also claimed are: (i) a catalyst contg. stereo-rigid metallocene and cocatalyst(s); (ii) a process for the prodn. of polyolefins by polymerisation of olefins in presence of the catalyst; (iii) use of the stereo-rigid metallocene cpd. for olefin polymerisation; and (iv) polyolefin obtd. by the process.
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Patent Agency Ranking
公开(公告)号：CA2179354A1
公开(公告)日：1996-12-20
申请号：CA2179354
申请日：1996-06-18
Applicant: HOECHST AG
Inventor： AULBACH MICHAEL , KUEBER FRANK , RIEDEL MICHAEL , HELMER-METZMANN FREDDY
IPC: C07F17/00 , C08F4/60 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/622 , C08F4/642 , C08F4/6592 , C08F10/00 , C08F4/627
Abstract: Stereorigid metallocene compound The present invention relates to a stereorigid metallocene compound having as ligands at least two substituted or unsubstituted cyclopentadienyl groups which are connected to one another via a fivemembered ring where at least one cyclopentadienyl group is fused onto the five-membered ring and the ligand system of the stereorigid metallocene compound is different from 4-¢?5-3'-alkylcyclopentadienyl)-4,6,6-trimethyl-(?5-2-alkyl-4,5-tetrahydropentalenne!. The metallocene compound of the invention is suitable as a catalyst component for olefin polymerization.
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公开(公告)号：CA2175159A1
公开(公告)日：1996-10-28
申请号：CA2175159
申请日：1996-04-26
Applicant: HOECHST AG
Inventor： AULBACH MICHAEL , BREKNER MICHAEL-JOACHIM , KUEBER FRANK , ZENK ROLAND
IPC: C07F17/00 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/68 , C08F4/69 , C08F10/00 , C08F4/42
Abstract: The present invention relates to a metallocene compound containing at least two metallocene fragments L-MX2-L which are different from one another and having the formula I (I) where B is a bridging unit, m is an integer from 2 to 100,000, M is a metal atom of group IVb, Vb or VIb of the Periodic Table of the Elements, X are identical or different in one metallocene fragment L-MX2-L and are each, independently of one another, hydrogen, a C1-C40-hydrocarbon-containing group, an OH group, a halogen atom or a pseudohalogen, L are identical or different in one metallocene fragment and are each, independently of one another, a n ligand or another electron donor. The metallocene compound can advantageously be used as a catalyst component for olefin polymerization.
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公开(公告)号：BR9504330A
公开(公告)日：1996-10-08
申请号：BR9504330
申请日：1995-10-09
Applicant: HOECHST AG
Inventor： HERMANN HANS-FRIEDRICH , AULBACH MICHAEL , KUEBER FRANK
IPC: C07C2/34 , C07F17/00 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/6592 , C08F4/68 , C08F10/00
Abstract: A metallocene cpd. of formula (I) is new: In (I), M = Gp. IVb, Vb or VIb metal; R , R = H, 1-10C alkyl or alkoxy, 6-10C aryl or aryloxy, 2-10C alkenyl, 7-40C aralkyl, 8-40C aralkenyl, OH or halogen; R -R = H, halogen, opt. halogenated 1-20C hydrocarbyl, -NR2, -SR, -OR, -OSiR3, -SiR3 or -PR2 (with R = halogen, 1-10C alkyl or 6-10C aryl); or two or more of these gps. may form a ring system with the attached atoms; and R '-R ' = as for R -R . Also claimed are: (i) olefin polymerisation catalysts contg. cpd(s). (I) and a co-catalyst; and (ii) a process for the prodn. of olefin polymers by (co)polymerisation of olefins in the presence of (I) and a co-catalyst.
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公开(公告)号：ZA963337B
公开(公告)日：1996-08-27
申请号：ZA963337
申请日：1996-04-26
Applicant: HOECHST AG
Inventor： AULBACH MICHAEL , BREKNER MICHAEL-JOACHIM , KUEBER FRANK , ZENK ROLAND
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公开(公告)号：ZA9603337B
公开(公告)日：1996-08-27
申请号：ZA9603337
申请日：1996-04-26
Applicant: HOECHST AG
Inventor： AULBACH MICHAEL , BREKNER MICHAEL-JOACHIM , KUEBER FRANK , ZENK ROLAND
CPC classification number: C07F17/00 , C08F4/61912 , C08F4/61916 , C08F4/61927 , C08F10/00
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