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公开(公告)号:DE3825584A1
公开(公告)日:1990-02-01
申请号:DE3825584
申请日:1988-07-28
Applicant: HOECHST AG
Inventor: HOENEL MICHAEL DR , ZIEGLER PETER DR , SPRENGER WALTER , WENDT WOLFGANG
Abstract: The invention relates to paste resins based on epoxide compounds, containing (a) specific quaternary ammonium groups, (b) OH groups and (c) isocyanate radicals bonded to the epoxide compound, of which at least 10 mol% are derived from a long-chain, monofunctional isocyanate having at least 8 carbon atoms, the mean molecular weight (Mn) of these paste resins being 500 to 10000. … In addition, the invention relates to the preparation of these paste resins, to their use for pigment pastes and to these pigment pastes. Water-thinnable paints, in particular electrodeposition paints, which contain the pigment pastes according to the invention give defect-free surfaces and comparable coating thicknesses even on different substrates.
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公开(公告)号:DE3809695A1
公开(公告)日:1989-10-12
申请号:DE3809695
申请日:1988-03-23
Applicant: HOECHST AG
Inventor: HOENEL MICHAEL DR , FINKE MANFRED DR , WALZ GERD DR , ZIEGLER PETER DR
IPC: C08G18/32 , C08G18/38 , C08G18/64 , C08G18/80 , C09D5/44 , C09D175/00 , C09D175/04
Abstract: Curing agents (A) for isocyanate-curable resins (B) which have an amine number of from 20 to 150 mg of KOH/g, a maximum OH number of 20 mg KOH/g and contain, per molecule, at least two capped isocyanate groups which are reactive under the curing conditions, are obtained by reacting A) an amine which contains at least one ss-hydroxyalkyl group per molecule, as an OH number of from 100 to 1200 mg KOH/g and an amine number of from 100 to 1200 mg of KOH/g and optionally also contains NHCO groups, optionally blended with another OH- and/or NH-functional compound, with B) a partially capped polyisocyanate, optionally blended with an at least bifunctional, OH- and/or NH-reactive compound. These curing agents, if necessary after neutralisation, are readily dispersible in aqueous systems and frequently have a stability-increasing action in water-borne paint formulations.
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公开(公告)号:AT207946T
公开(公告)日:2001-11-15
申请号:AT94113888
申请日:1994-09-05
Applicant: HOECHST AG
Inventor: HOENEL MICHAEL DR , SCHAFHEUTLE MARKUS A DR , VOELKER ACHIM DR , WALZ GERD DR , WEHNER SUSANNE , ZIEGLER PETER DR
IPC: C08F2/16 , C08F2/24 , C08F2/44 , C08G18/00 , C08G18/08 , C08G18/58 , C08G18/64 , C08G18/72 , C08G18/80 , C08L63/00 , C08L63/10 , C09D5/02 , C09D5/44 , C09D163/00 , C09D175/04
Abstract: Solvent-free, aqueous synthetic resin dispersions containing a polymer A) obtained by polymerisation of A1) masked polyisocyanates, where some of the masking groups contain an ethylenically unsaturated group, and A2) ethylenically unsaturated monomers, in the presence of an ionic resin B).
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公开(公告)号:AT185160T
公开(公告)日:1999-10-15
申请号:AT95109598
申请日:1995-06-21
Applicant: HOECHST AG
Inventor: NEUMANN UWE DR , HOENEL MICHAEL DR , VOELKER ACHIM DR , WALZ GERD DR , WEHNER SUSANNE , ZIEGLER PETER DR
IPC: C08L75/04 , C08F283/10 , C08F290/06 , C08F290/14 , C08G18/08 , C08G18/58 , C08G18/64 , C08G18/67 , C08G18/80 , C08G59/06 , C08G59/14 , C08G59/24 , C08G59/40 , C08G59/50 , C08G59/56 , C08J3/03 , C08L51/08 , C08L63/00 , C08L75/00 , C09D5/44 , C09D175/00 , C09D175/04
Abstract: The aq. synthetic resin dispersions (I) contain: (a) an ionic epoxy resin derived from bisphenol A substd. with aralkyl gp(s)., (b) a capped polyisocyanate, and (c) a polymer of radically polymerisable olefinic monomer(s). Also claimed are: (i) a process for the prodn. of (I) from a mixt. of vinyl monomer (c), resin (a) and blocked di or poly-isocyanate (b), by converting the mixt. into an aq. dispersion and polymerising with a radical initiator; and (ii) articles coated with the dispersion (I).
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公开(公告)号:AT176677T
公开(公告)日:1999-02-15
申请号:AT94106322
申请日:1994-04-22
Applicant: HOECHST AG
Inventor: HOENEL MICHAEL DR , VOELKER ACHIM DR , WALZ GERD DR , ZIEGLER PETER DR
IPC: C08G18/08 , C08F2/16 , C08F2/18 , C08F2/44 , C08F283/00 , C08G18/00 , C08G18/63 , C08G18/64 , C08G18/70 , C08G18/80 , C08L63/00 , C08L75/00 , C08L75/04 , C09D5/44 , C09D163/00 , C09D175/00 , C09D175/04 , C25D15/02
Abstract: Aqueous synthetic resin dispersions containing A) an ionic resin, preferably a cationic resin, B) a masked polyisocyanate and C) a polymer comprising at least one free-radical-polymerizable ethylenically unsaturated monomer. These synthetic resin dispersions are used as binders in electrodeposition coating baths.
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公开(公告)号:DE59010628D1
公开(公告)日:1997-02-20
申请号:DE59010628
申请日:1990-09-25
Applicant: HOECHST AG
Inventor: HOENEL MICHAEL DR , WALZ GERD DR , ZIEGLER PETER DR , KUBILLUS UWE DR
IPC: C08G59/50 , C08L63/00 , C08L101/00 , C09D5/02 , C09D7/12 , C09D5/44 , C09D163/00 , C09D201/00
Abstract: The invention relates to the use of crosslinked polymer microparticles having an average particle size of at most 5 mu m and a glass transition temperature (Tg) of at least +30 DEG C. in aqueous paint preparations as filler and/or as partial substitute of white pigments, in particular of titanium dioxide. Among other things, the corresponding paints show increased spreading power, less tendency for sedimentation and reduced crater formation.
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公开(公告)号:ES2094726T3
公开(公告)日:1997-02-01
申请号:ES89113521
申请日:1989-07-22
Applicant: HOECHST AG
Inventor: HONEL MICHAEL DR , ZIEGLER PETER DR , SPRENGER WALTER , WENDT WOLFGANG
Abstract: The invention relates to paste resins based on epoxide compounds, containing (a) specific quaternary ammonium groups, (b) OH groups and (c) isocyanate radicals bonded to the epoxide compound, of which at least 10 mol% are derived from a long-chain, monofunctional isocyanate having at least 8 carbon atoms, the mean molecular weight (Mn) of these paste resins being 500 to 10000. … In addition, the invention relates to the preparation of these paste resins, to their use for pigment pastes and to these pigment pastes. Water-thinnable paints, in particular electrodeposition paints, which contain the pigment pastes according to the invention give defect-free surfaces and comparable coating thicknesses even on different substrates.
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公开(公告)号:DE59301142D1
公开(公告)日:1996-01-25
申请号:DE59301142
申请日:1993-05-05
Applicant: HOECHST AG
Inventor: WEHNER SUSANNE , KLIMA HEINZ , HOENEL MICHAEL DR , ZIEGLER PETER DR , WALZ GERD DR
IPC: C08L63/00 , C08G59/28 , C09D5/44 , C09D175/00 , C09D175/04 , C25D13/06
Abstract: Electrocoating bath containing a urethane of the formula R1-NHCOO-R2 where R1 is alkyl or a group of the formula B1-NH-B2-[X-B3]n-, R2 is a group of the formulae -(C2H4O)y-R1 and -(C3H7O) y-R or of the formula R is C1-C18-alkyl, Y is from zero to 4, B1 is hydrogen, alkyl or a group of the formula -COOR2, B2 and B3 can be identical or different and each is C2-C14-alkylene, n is an integer from 0 to 5, preferably from 0 to 2, X is -O-, -S-, -NH- or @N-(C1-C4)-alkyl, R3 is hydrogen or alkyl, alkenyl, hydroxyalkyl, phenyl or alkylphenyl, R4 and R5 can be identical or different and each is hydrogen or C1-C4-alkyl, and A is a direct bond or one of the groups -O-, -CH2O- or -CH2OCO-. The presence of these urethanes in the electrocoating bath reduces the number of surface defects in galvanised surfaces.
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公开(公告)号:DE4314297A1
公开(公告)日:1994-11-03
申请号:DE4314297
申请日:1993-04-30
Applicant: HOECHST AG
Inventor: HOENEL MICHAEL DR , VOELKER ACHIM DR , WALZ GERD DR , ZIEGLER PETER DR
IPC: C08G18/08 , C08F2/16 , C08F2/18 , C08F2/44 , C08F283/00 , C08G18/00 , C08G18/63 , C08G18/64 , C08G18/70 , C08G18/80 , C08L63/00 , C08L75/00 , C08L75/04 , C09D5/44 , C09D163/00 , C09D175/00 , C09D175/04 , C25D15/02 , C08J3/03 , C08L57/00 , C08G18/58 , C09D157/00
Abstract: Aqueous synthetic resin dispersions containing A) an ionic resin, preferably a cationic resin, B) a masked polyisocyanate and C) a polymer comprising at least one free-radical-polymerizable ethylenically unsaturated monomer. These synthetic resin dispersions are used as binders in electrodeposition coating baths.
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公开(公告)号:DE58908087D1
公开(公告)日:1994-09-01
申请号:DE58908087
申请日:1989-03-21
Applicant: HOECHST AG
Inventor: HOENEL MICHAEL DR , FINKE MANFRED DR , WALZ GERD DR , ZIEGLER PETER DR
IPC: C08G18/32 , C08G18/38 , C08G18/64 , C08G18/80 , C09D5/44 , C09D175/00 , C09D175/04
Abstract: Curing agents (A) for isocyanate-curable resins (B) which have an amine number of from 20 to 150 mg of KOH/g, a maximum OH number of 20 mg KOH/g and contain, per molecule, at least two capped isocyanate groups which are reactive under the curing conditions, are obtained by reacting A) an amine which contains at least one ss-hydroxyalkyl group per molecule, as an OH number of from 100 to 1200 mg KOH/g and an amine number of from 100 to 1200 mg of KOH/g and optionally also contains NHCO groups, optionally blended with another OH- and/or NH-functional compound, with B) a partially capped polyisocyanate, optionally blended with an at least bifunctional, OH- and/or NH-reactive compound. These curing agents, if necessary after neutralisation, are readily dispersible in aqueous systems and frequently have a stability-increasing action in water-borne paint formulations.
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