公开(公告)号：CA1341623C

公开(公告)日：2011-10-11

申请号：CA558109

申请日：1988-02-04

Applicant: IBM

Inventor： BEYERS ROBERT B ,  ENGLER EDWARD M ,  GRANT PAUL M ,  LIM GRACE S ,  PARKIN STUART S P

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24

Abstract: Compositions having the formula A1 x m 2 x Cu3Oy, wherein A is Y, or a combination of Y, La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77°K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800°C and about 1100°C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.

公开(公告)号：CA1333977C

公开(公告)日：1995-01-17

申请号：CA600087

申请日：1989-05-18

Applicant: IBM

Inventor： ENGLER EDWARD M ,  KODAS TOIVO T ,  LEE VICTOR Y-W

IPC: C04B35/00 ,  C01G1/00 ,  C04B35/45 ,  H01B12/12 ,  H01B13/00 ,  H01L39/24

Abstract: A process for forming a composite high temperature superconductor copper wire, said process comprising the steps of (1) directing a submicron sized powder of a superconducting ceramic material through a length of copper tubing to coat the interior surface of said tubing with a uniform compact film of said powder, and (2) sintering said powder while passing oxygen through said tube and while maintaining the outside of said tube in an inert atmosphere. In a preferred embodiment an aerosol process is used to generate the submicron sized powder of the superconductor.

公开(公告)号：AU1278388A

公开(公告)日：1988-09-15

申请号：AU1278388

申请日：1988-03-08

Applicant: IBM

Inventor： BEYERS ROBERT B ,  ENGLER EDWARD M ,  GRANT PAUL M ,  LIM GRACE S ,  PARKIN STUART S P

IPC: C01G1/00 ,  C01G3/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/00 ,  H01B13/00 ,  H01L39/12 ,  H01L39/24 ,  C01G3/02 ,  C01G57/00

Abstract: Compositions having the formula A1+/-xM2+/-xCu3Oy, wherein A is Y, or a combination of Y La, Lu, Sc or Yb; M is Ba, or a combination of Ba, Sr or Ca and y is sufficient to satisfy the valence demands, have been found to be bulk electrical superconductors at a temperature above 77K. The compositions are single phase perovskite-like crystalline structures. They are made by a process involving intimately mixing the metal oxides or their precursors in the proper molar ratios, heating the mixture in the presence of oxygen to a temperature between about 800 DEG C and about 1100 DEG C and slowly cooling the mixture to room temperature in the presence of oxygen over a period of at least four hours.

公开(公告)号：FR2393388A1

公开(公告)日：1978-12-29

申请号：FR7813283

申请日：1978-04-27

Applicant: IBM

Inventor： ENGLER EDWARD M ,  KAUFMAN FRANK B

IPC: C09B69/10 ,  C09K9/02 ,  G02F1/15 ,  C09K9/00 ,  G02F1/153 ,  G02F1/17 ,  G09F9/30 ,  G09X ,  C09B57/00

Abstract: This invention is concerned with a reversible electrochromic display device wherein its electrochromic activity is derived from an electrochromic active molecules which are attached to a porous polymeric resin.

公开(公告)号：CA1341499C

公开(公告)日：2006-02-28

申请号：CA588409

申请日：1989-01-17

Applicant: IBM

Inventor： PARKIN STUART S P ,  NAZZAL ADEL I ,  LEE VICTOR Y-W ,  ENGLER EDWARD M

IPC: H01B12/00 ,  B22D23/06 ,  B22D41/00 ,  C01G1/00 ,  C01G15/00 ,  C04B35/45 ,  C22C1/02 ,  H01L39/12

Abstract: Stable, bulk electrical superconductors are prepared by heating mixed metal oxides in the presence of oxygen in a closed vessel in a preheated oven for 1-5 hours at 850-900 DEG C. The final oxides are in the molar ratio Tl0.6-1.1Ca2-3Ba0.75-1.25Cu2-3O(5+ delta )-(9+ delta ), where delta is less than one.

公开(公告)号：CA1116174A

公开(公告)日：1982-01-12

申请号：CA299917

申请日：1978-03-29

Applicant: IBM

Inventor： ENGLER EDWARD M ,  NICHOLS KENNETH H ,  PATEL VISHNUBHAI V ,  RIVERA NILDA M ,  SCHUMAKER ROBERT R

IPC: C09K3/16 ,  C07F1/00 ,  C07F1/08 ,  C07F3/06 ,  C07F15/00 ,  C08G75/00 ,  C08G79/00 ,  C09D5/24 ,  C09D185/00 ,  C07D341/00

Abstract: HIGHLY CODUCTING ORGANOMETALLIC POLYMERS This specification discloses highly conducting organometallic polymers having units chosen from the following recurring units and where each M is same or different and is a multivalent metal, and method for preparing the above polymers.

公开(公告)号：CA1096020A

公开(公告)日：1981-02-17

申请号：CA299558

申请日：1978-03-22

Applicant: IBM

Inventor： ENGLER EDWARD M ,  KAUFMAN FRANK B

IPC: C09K9/00 ,  C09B69/10 ,  C09K9/02 ,  G02F1/15 ,  G02F1/153 ,  G02F1/17 ,  G09F9/30 ,  G02F1/00

Abstract: A REVERSIBLE ELECTROCHROMIC DISPLAY DEVICE HAVING MEMORY This invention is concerned with a reversible electrochromic display device wherein its electrochromic activity is derived from electrochromic active molecules which are attached to a porous polymeric resin. YO9-77-002

公开(公告)号：CA1068150A

公开(公告)日：1979-12-18

申请号：CA256032

申请日：1976-06-30

Applicant: IBM

Inventor： ENGLER EDWARD M ,  KAUFMAN FRANK B ,  SCOTT BRUCE A

IPC: G03C1/73 ,  G03C1/675 ,  G03C1/72 ,  G03C5/56 ,  G03G5/026 ,  H05K1/09 ,  H05K3/10 ,  G03G5/00

Abstract: Optical printing of highly conductive lines or characters is described, wherein an organic .pi. -electron donor compound, dissolved in a halocarbon, is deposited onto a substrate. The coated substrate is exposed to actinic radiation in a predetermined pattern, and then the halocarbon is removed. The compositions used are of the type (Donor)xn where the donor is typically selected from TTF, TSeF, DSeDTF, and their substituted derivations where x may be selected from F, Br, Cl and I, and n

公开(公告)号：CA1064043A

公开(公告)日：1979-10-09

申请号：CA292334

申请日：1977-12-05

Applicant: IBM

Inventor： ENGLER EDWARD M ,  SCHUMAKER ROBERT R

IPC: C07D339/04 ,  C07D295/16 ,  C07D295/21 ,  C07D339/06 ,  C07D495/02 ,  C07D495/04 ,  C07D517/04 ,  C07D519/00

Abstract: TETRATHIAPENTALENE AND TETRASELENAPENTTALENE COMPOUNDS This application is concerned with tetrathiapentalene and tetrasalenapentalene compounds. Specifically, it is concerned with 1, 3, 4, 6-tetrathia-2, 5-dihetexo-pentalene and 1, 3, 4, 6 tetraselena-2, 5-dihetero-pentalene compounds having the formula or wherein X is S or Se; each of Y1 and Y2 is O, S, or Se; each or Z1 and Z2 is -SR, SeR ox = N? wherein R and Rr are H, alkyl, aryl, or together form a ring of carbon atoms; and An is the anion of a strong acid. These compounds are key synthetic intermediates for the preparation of tetrathiafulvalene and tetraselenafulvalene materials, in the art of producing organic conductors.

公开(公告)号：FR2316628A1

公开(公告)日：1977-01-28

申请号：FR7615015

申请日：1976-05-13

Applicant: IBM

Inventor： ENGLER EDWARD M ,  KAUFMAN FRANK B ,  SCOTT BRUCE A

IPC: G03C1/73 ,  G03C1/675 ,  G03C1/72 ,  G03C5/56 ,  G03G5/026 ,  H05K1/09 ,  H05K3/10 ,  H05K3/02

Abstract: A method of optically printing conductive characters using charge transfer compounds is provided. The method is characterized by depositing an organic pi electron donor compound dissolved in a halogenated hydrocarbon (halocarbon) on a suitable substrate and selectively exposing the so coated substrate to actinic radiation to obtain a permanent, highly conductive, image.