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公开(公告)号:SG102636A1
公开(公告)日:2004-03-26
申请号:SG200105472
申请日:2001-09-07
Applicant: MITSUI CHEMICALS INC
Inventor: IMUTA JUNICHI , KASHIWA NORIO , OTA SEIJI , MORIYA SATORU , NOBORI TADAHITO , MIZUTANI KAZUMI
IPC: C08F4/659 , C08F4/6592 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/14 , C08F210/16 , C08F210/04 , C08F216/02 , C08F216/12 , C08F220/64
Abstract: The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (4), and optionally a constituent unit represented by the following formula (5), having a molecular weight distribution (Mw/Mn) of not more than 3, and having an intensity ratio of T±² to T±± (T±²/T±±), as determined from a 13 C-NMR spectrum of said copolymer, of not more than 1.0: wherein R 1 is a hydrogen atom or a straight-chain or branched aliphatic hydrocarbon group of 1 to 18 carbon atoms; R 5 is a hydrocarbon group; R 6 is a hetero atom or a group containing a hetero atom; r is 0 or 1; Z is a polymer segment obtained by any one of anionic polymerization, ring-opening polymerization and polycondensation; W is a hydroxyl group or an epoxy group; p is an integer of 1 to 3, q is 0, 1 or 2, and p+q ‰ 3; when p is 2 or 3, each -O-Z may be the same or different, and in this case, if r is 0, -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, -O-Z may be bonded to the same or different atom of R 6 ; when q is 2, each W may be the same or different, and in this case, if r is 0, W may be bonded to the same or different atom of R 5 , and if r is 1, W may be bonded to the same or different atom of R 6 ; in case of p‰¥1 and q‰¥1, if r is 0, W and -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, W and -O-Z may be bonded to the same or different atom of R 6 ; m is 0 or 1; n is an integer of 1 to 3; and when n is 2 or 3, each W may be the same or different, and in this case, if m is 0, W may be bonded to the same or different atom of R 6 , and if m is 1, W may be bonded to the same or different atom of R 7 . The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
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公开(公告)号:DE60141777D1
公开(公告)日:2010-05-20
申请号:DE60141777
申请日:2001-09-07
Applicant: MITSUI CHEMICALS INC
Inventor: IMUTA JUNICHI , KASHIWA NORIO , OTA SEIJI , MORIYA SATORU , NOBORI TADAHITO , MIZUTANI KAZUMI
IPC: C08F210/02 , C08F4/659 , C08F4/6592 , C08F210/00 , C08F210/06 , C08F210/08 , C08F210/14 , C08F210/16 , C08F290/00 , C08L23/00
Abstract: The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (4), and optionally a constituent unit represented by the following formula (5), having a molecular weight distribution (Mw/Mn) of not more than 3, and having an intensity ratio of T±² to T±± (T±²/T±±), as determined from a 13 C-NMR spectrum of said copolymer, of not more than 1.0: wherein R 1 is a hydrogen atom or a straight-chain or branched aliphatic hydrocarbon group of 1 to 18 carbon atoms; R 5 is a hydrocarbon group; R 6 is a hetero atom or a group containing a hetero atom; r is 0 or 1; Z is a polymer segment obtained by any one of anionic polymerization, ring-opening polymerization and polycondensation; W is a hydroxyl group or an epoxy group; p is an integer of 1 to 3, q is 0, 1 or 2, and p+q ‰ 3; when p is 2 or 3, each -O-Z may be the same or different, and in this case, if r is 0, -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, -O-Z may be bonded to the same or different atom of R 6 ; when q is 2, each W may be the same or different, and in this case, if r is 0, W may be bonded to the same or different atom of R 5 , and if r is 1, W may be bonded to the same or different atom of R 6 ; in case of p‰¥1 and q‰¥1, if r is 0, W and -O-Z may be bonded to the same or different atom of R 5 , and if r is 1, W and -O-Z may be bonded to the same or different atom of R 6 ; m is 0 or 1; n is an integer of 1 to 3; and when n is 2 or 3, each W may be the same or different, and in this case, if m is 0, W may be bonded to the same or different atom of R 6 , and if m is 1, W may be bonded to the same or different atom of R 7 . The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
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公开(公告)号:DE60112565D1
公开(公告)日:2005-09-15
申请号:DE60112565
申请日:2001-01-18
Applicant: MITSUI CHEMICALS INC
Inventor: OTA SEIJI , MORIYA SATORU , MORI RYOJI , KODA TAKU , TAN JUNJI , KOJOH SHINICHI , KANEKO HIDEYUKI , HAMA SHUNICHI , NOBORI TADAHITO , MATSUGI TOMOAKI , KASHIWA NORIO
IPC: C08F293/00 , C08G81/00 , C08L53/00 , C08L101/00
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公开(公告)号:AU2003292690A1
公开(公告)日:2004-10-25
申请号:AU2003292690
申请日:2003-12-26
Applicant: MITSUI CHEMICALS INC
Inventor: INOUE NORIHIDE , HIROTA NARITOSHI , KANEYOSHI HIROMU , FUNAYA MUNEHITO , KAWAI KOJI , KAWAHARA NOBUO , KOJOH SHINICHI , KASHIWA NORIO , MORI RYOJI , IKENAGA SHIGENOBU , OKADA KEIJI , TAKAYASU HIROSHI
IPC: C08F4/64 , C08F4/6592 , C08F210/06 , C08L23/14 , C08L23/10 , C08J5/18 , C07C17/00 , B32B27/32 , C07F7/00
Abstract: The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol% of propylene units and 10 to 40 mol% of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5 %, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120°C, and satisfies the following relation wherein Tm represents a melting point and M (mol%) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R 1 and R 3 is hydrogen, R 2 and R 4 are selected from a hydrocarbon group and silicon-containing group, R 5 to R 13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R 5 to R 12 may be linked to form a ring. R 14 is an aryl group, and R 13 and R 14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.
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公开(公告)号:SG169235A1
公开(公告)日:2011-03-30
申请号:SG2008064453
申请日:2001-01-26
Applicant: MITSUI CHEMICALS INC
Inventor: MITANI MAKOTO , YOSHIDA YASUNORI , MOHRI JUNICHI , TSURU KAZUTAKA , ISHII SEIICHI , KOJOH SHINICHI , MATSUGI TOMOAKI , SAITO JUNJI , MATSUKAWA NAOTO , MATSUI SHIGEKAZU , NAKANO TAKASHI , TANAKA HIDETSUGU , KASHIWA NORIO , FUJITA TERUNORI
IPC: C08F4/60 , C08F4/659 , C08F10/00 , C08F110/02 , C08F210/16 , C08F297/08 , C08L53/00
Abstract: An olefin polymer which is a copolymer of ethylene and at least one olefin is disclosed. The olefin is selected from olefins of 3 to 8 carbon atoms, and has a commoner content of not less than 10% by mol., and has a number-average molecular weight of 1,000- 5,000,000 and Mw/Mn of not more than 1.5. (FIG. 1)
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公开(公告)号:AT478900T
公开(公告)日:2010-09-15
申请号:AT06768098
申请日:2006-07-11
Applicant: MITSUI CHEMICALS INC
Inventor: KANEKO HIDEYUKI , KOJOH SHINICHI , KAWAHARA NOBUO , MATSUO SHINGO , MATSUGI TOMOAKI , KASHIWA NORIO
IPC: C08F255/00 , C08F293/00 , C08L51/06
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公开(公告)号:DE60331612D1
公开(公告)日:2010-04-15
申请号:DE60331612
申请日:2003-12-26
Applicant: MITSUI CHEMICALS INC
Inventor: IKENAGA SHIGENOBU , OKADA KEIJI , TAKAYASU HIROSHI , INOUE NORIHIDE , HIROTA NARITOSHI , KANEYOSHI HIROMU , FUNAYA MUNEHITO , KAWAI KOJI , KAWAHARA NOBUO , KOJOH SHINICHI , KASHIWA NORIO , MORI RYOJI
IPC: C08F210/06 , C08F4/64 , C08F4/6592 , C08J5/18 , C08L23/10 , C08L23/14
Abstract: The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol% of propylene units and 10 to 40 mol% of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5 %, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120°C, and satisfies the following relation wherein Tm represents a melting point and M (mol%) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R 1 and R 3 is hydrogen, R 2 and R 4 are selected from a hydrocarbon group and silicon-containing group, R 5 to R 13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R 5 to R 12 may be linked to form a ring. R 14 is an aryl group, and R 13 and R 14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.
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公开(公告)号:AU2003292690B2
公开(公告)日:2008-11-20
申请号:AU2003292690
申请日:2003-12-26
Applicant: MITSUI CHEMICALS INC
Inventor: OKADA KEIJI , KOJOH SHINICHI , HIROTA NARITOSHI , KAWAHARA NOBUO , INOUE NORIHIDE , KASHIWA NORIO , TAKAYASU HIROSHI , KAWAI KOJI , MORI RYOJI , IKENAGA SHIGENOBU , KANEYOSHI HIROMU , FUNAYA MUNEHITO
IPC: C08F210/06 , C08F4/64 , C08F4/6592 , C08L23/14
Abstract: The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol% of propylene units and 10 to 40 mol% of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5 %, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120°C, and satisfies the following relation wherein Tm represents a melting point and M (mol%) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R 1 and R 3 is hydrogen, R 2 and R 4 are selected from a hydrocarbon group and silicon-containing group, R 5 to R 13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R 5 to R 12 may be linked to form a ring. R 14 is an aryl group, and R 13 and R 14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.
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公开(公告)号:DE602004013479D1
公开(公告)日:2008-06-19
申请号:DE602004013479
申请日:2004-03-12
Applicant: MITSUI CHEMICALS INC
Inventor: KANEKO HIDEYUKI , MATSUGI TOMOAKI , KOJOH SHINICHI , MATSUO SHINGO , KAWAHARA NOBUO , KASHIWA NORIO
IPC: C08F8/14 , C08G81/02 , C08F290/04
Abstract: A group of polymers comprising a plurality of polyolefin chains and polar polymer chains and having a multi-branched structure such as a block structure, a graft structure and a star-shaped structure is produced efficiently by polymerizing or reacting a combination of various polar monomers and their polymers i.e. polar polymer chains by using a functional group-containing polyolefin as a macroinitiator, a macromonomer or a reactive polymer. The resulting multi-branched polymer has a specific shape such as a block structure, a graft structure or a star-shaped structure, and has properties of both the polyolefin and polar polymer,thusexhibiting usefulperformance in various uses in films and compatibilizing agents as a novel polyolefin-based polymer.
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公开(公告)号:DE3752359D1
公开(公告)日:2002-12-19
申请号:DE3752359
申请日:1987-09-24
Applicant: MITSUI CHEMICALS INC
Inventor: TSUTUI TOSHIYUKI , TOYOTA AKINORI , KASHIWA NORIO
IPC: C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16 , C08F210/18
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