公开(公告)号：DD298261A5

公开(公告)日：1992-02-13

申请号：DD34427290

申请日：1990-09-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： MIZUI KINYA ,  KISO YOSHIHISA ,  HAYASHI TETSUO ,  TANAKA MASAHIDE

IPC: C10M107/20 ,  C07C67/00 ,  C08G64/18 ,  C09K5/04 ,  C10M105/48 ,  C10M107/32 ,  C10M171/00 ,  F02B75/02 ,  C10M145/26 ,  C10M107/30 ,  C08L69/00

Abstract: The present invention provides lubricant oil compositions comprising a polyalkylene glycol polycarbonate. The lubricant oil compositions are useful for industrial gear oil, automotive gear oil, and lubricant oil for refrigerators, rolling installations and fibers, which are excellent in lubricating properties and detergency. The present invention also relates to lubricant oil compositions which comprise a polyalkylene glycol polycarbonate having mutual solubility with an ozone layer-nondestructive Freon such as Freon R-134a, and which are accordingly especially suited for refrigerators using hydrogenated fluorocarbon as a refrigerant. A polyalkylene glycol polycarbonate according to the invention comprises a polyoxypropylene group in the molecular chain and an alkyl group and an alkyloxyalkylene group at the molecular terminals. This invention provides a process for preparing said polyalkylene glycol polycarbonate wherein a polypropylene glycol and a carbonate are allowed to react, said reaction including condensation polymerization. The invention also provides a process without condensation polymerization for preparing a polyalkylene glycol polyol wherein a polyol and a carbonate is allowed to react in the presence of a basic catalyst while a produced alcohol is being distilled off, the catalyst is removed then, and the unreacted carbonate is eliminated.

公开(公告)号：CA2026504C

公开(公告)日：1998-04-28

申请号：CA2026504

申请日：1990-09-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  HAYASHI TETSUO ,  TANAKA MASAHIDE ,  MIZUI KINYA

IPC: C10M107/20 ,  C07C67/00 ,  C08G64/18 ,  C09K5/04 ,  C10M105/48 ,  C10M107/32 ,  C10M171/00 ,  F02B75/02 ,  C10M105/38 ,  C10M107/34 ,  C10M105/36

Abstract: The present invention provides lubricant oil compositions comprising a polyalkylene glycol polycarbonate. The lubricant oil compositions are useful for industrial gear oil, automotive gear oil, and lubricant oil for refrigerators, rolling installations and fibers, which are excellent in lubricating properties and detergency. The present invention also relates to lubricant oil compositions which comprise a polyalkylene glycol polycarbonate having mutual solubility with an ozone layer-nondestructive Freon such as Freon R-134a, and which are accordingly especially suited for refrigerators using hydrogenated fluorocarbon as a refrigerant. A polyalkylene glycol polycarbonate according to the invention comprises a polyoxypropylene group in the molecular chain and an alkyl group and an alkyloxyalkylene group at the molecular terminals. This invention provides a process for preparing said polyalkylene glycol polycarbonate wherein a polypropylene glycol and a carbonate are allowed to react, said reaction including condensation polymerization. The invention also provides a process without condensation polymerization for preparing a polyalkylene glycol polyol wherein a polyol and a carbonate is allowed to react in the presence of a basic catalyst while a produced alcohol is being distilled off, the catalyst is removed then, and the unreacted carbonate is eliminated.

公开(公告)号：DE69031966D1

公开(公告)日：1998-02-26

申请号：DE69031966

申请日：1990-09-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： MIZUI KINYA ,  KISO YOSHIHISA ,  HAYASHI TETSUO ,  TANAKA MASAHIDE

IPC: C10M107/20 ,  C07C67/00 ,  C08G64/18 ,  C09K5/04 ,  C10M105/48 ,  C10M107/32 ,  C10M171/00 ,  F02B75/02 ,  C10M107/34

Abstract: The present invention provides lubricant oil compositions comprising a polyalkylene glycol polycarbonate. The lubricant oil compositions are useful for industrial gear oil, automotive gear oil, and lubricant oil for refrigerators, rolling installations and fibers, which are excellent in lubricating properties and detergency. The present invention also relates to lubricant oil compositions which comprise a polyalkylene glycol polycarbonate having mutual solubility with an ozone layer-nondestructive Freon such as Freon R-134a, and which are accordingly especially suited for refrigerators using hydrogenated fluorocarbon as a refrigerant. A polyalkylene glycol polycarbonate according to the invention comprises a polyoxypropylene group in the molecular chain and an alkyl group and an alkyloxyalkylene group at the molecular terminals. This invention provides a process for preparing said polyalkylene glycol polycarbonate wherein a polypropylene glycol and a carbonate are allowed to react, said reaction including condensation polymerization. The invention also provides a process without condensation polymerization for preparing a polyalkylene glycol polyol wherein a polyol and a carbonate is allowed to react in the presence of a basic catalyst while a produced alcohol is being distilled off, the catalyst is removed then, and the unreacted carbonate is eliminated.

公开(公告)号：CZ280200B6

公开(公告)日：1995-11-15

申请号：CS150992

申请日：1990-09-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： MIZUI KINYA ,  KISO YOSHIHISA ,  HAYASHI TETSUO ,  TANAKA MASAHIDE

IPC: C10M107/20 ,  C07C67/00 ,  C07C69/00 ,  C09K5/04

Abstract: (1) A lubricant oil compsn. comprising a polyalkylene glycol polycarbonate of formula (I): R1-OCOO-(((R2)1-O-)m-COO-)n-R1 (I) where each R1 = an HC gp., not more than C20, chosen from aliphatic, alicyclic, aromatic, aromatic-substd. aliphatic and alkoxyalkylene of formula (II): -(-(-R3-)p-O-)q-R4 where R3 = C2-10 alkylene; R4 = aliphatic, alicyclic or aromatic gp. of not more than C20; p, q (integers) = 1-10; R2 = C2-20 alkylene; l, n (integers) = 1-100; m (integer) = 1-10. (2) A polyalkylene glycol polycarbonate of formula (III): (III) R11-OCOO-(-(R12O-)m-1-R12O-COO-)n-R11 where each R11 = C1-6 alkyl or alkoxylene (IV): -(-R13O-)q-R14 where R13 ethylene or propylene gp., R14 = C1-6 alkyl, q (integer) = 1-10; R12 = propylene, m (integer) = 2-10; n (integer) = 1-10 and 10-95 mol% molecular terminal gps. are occupied by (IV). (3) There are also independent claims for the prepn. of R41-OCOO-(-R42-OCOO)n-R41 (V), equiv. to (III) and both for the prepn. and use in a lubricant compsn. of (VI): R15-(-OCOO-R16).

公开(公告)号：CA2125247A1

公开(公告)日：1994-12-08

申请号：CA2125247

申请日：1994-06-06

Applicant: MITSUI PETROCHEMICAL IND

Inventor： FUKUOKA DAISUKE ,  TASHIRO TAKASHI ,  KAWAAI KOJI ,  SAITO JUNJI ,  UEDA TAKASHI ,  KISO YOSHIHISA ,  MIZUNO AKIRA ,  KAWASAKI MASAAKI ,  ITOH MASAAKI ,  IMUTA JUNICHI ,  FUJITA TERUNORI ,  NITABARU MASATOSHI ,  YOSHIDA MASAYASU ,  HASHIMOTO MIKIO

IPC: C07C45/46 ,  C07C49/67 ,  C07C49/697 ,  C07F17/00 ,  C08F4/60 ,  C08F4/602 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C07F7/00 ,  C07F9/00 ,  C07F11/00 ,  C08F4/42

Abstract: The novel transition metal compound of the invention is represented by the following formula (I): (see formula I) wherein M is a transition metal; R1 is a hydrocarbon group of 2 to 6 carbon atoms, R2 is an aryl group of 6 to 16 carbon atoms; X1 and X2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. An olefin polymerization catalyst component of the present invention comprises the aforementioned transition metal compound. An olefin polymerization catalyst of the present invention comprises the aforementioned olefin polymerization catalyst component. The propylene homopolymer, the propylene copolymer and the propylene elastomer according to the present invention have such properties that the triad tacticity of propylene units chain is high, a proportion of the inversely units based on the 2,1-insertion of propylene monomer is in the specific range, and the intrinsic viscosity [.pi.], as measured in decahydronaphthalene at 135.degree.C, is in the specific range.

公开(公告)号：CA1330093C

公开(公告)日：1994-06-07

申请号：CA596842

申请日：1989-04-17

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  MATSUNAGA YUUICHI

IPC: C07C68/06 ,  C07C69/96

Abstract: Disclosed is a process for producing an aromatic carbonate which comprises reacting a phenolic compound with a di-aliphatic carbonate or an aliphatic-aromatic carbonate in the presence of a catalyst. The catalyst is either SnO and/or a tin compound represented by the following formula wherein X and Y are identical or different and each represents OH, SCN, OR1, OCOR1 or a halogen atom, R1 represents an alkyl or aryl group, X and Y are not alkoxy groups at the same time, and R represents an alkyl or aryl group; or at least one compound of an element selected from the group consisting of Sc, Cr, Mo, W, Mn, Au, Ga, In, Bi, Te and lantanoids. The use of these specific catalysts enables the product to be obtained in high yields and selectivities and makes it easy to purify the product.

公开(公告)号：AT102938T

公开(公告)日：1994-04-15

申请号：AT88306712

申请日：1988-07-21

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  MATSUNAGA YUUICHI ,  IMAGAWA MASAO

IPC: C07D317/12 ,  B01J23/02 ,  B01J27/232 ,  B01J31/02 ,  B01J31/08 ,  C07B61/00 ,  C07D317/36 ,  C07D319/04 ,  C07D319/06 ,  C07D325/00

Abstract: A process for preparing a cyclic carbonate, which comprises reacting at least one 1,3-diol or 1,2-diol with a dialkylcarbonate in the presence of a basic catalyst.

公开(公告)号：CA1303618C

公开(公告)日：1992-06-16

申请号：CA572680

申请日：1988-07-21

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  MATSUNAGA YUUICHI ,  IMAGAWA MASAO

IPC: C07D317/12 ,  B01J23/02 ,  B01J27/232 ,  B01J31/02 ,  B01J31/08 ,  C07B61/00 ,  C07D317/36 ,  C07D319/04 ,  C07D319/06 ,  C07D325/00 ,  C07D317/26

Abstract: Cyclic carbonates are prepared by reacting a 1,3diol or 1,2-diol with a dialkylcarbonate in the presence of a basic catalyst. They are obtained in higher yields with higher purity by subjecting the reaction mixture to heat aging under vacuum in the presence of the basic catalyst, and recovering the cyclic carbonate from the mixture.

公开(公告)号：BR9004888A

公开(公告)日：1991-09-10

申请号：BR9004888

申请日：1990-09-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： MIZUI KINYA ,  KISO YOSHIHISA ,  HAYASHI TETSUO ,  TANAKA MASAHIDE

IPC: C10M107/20 ,  C07C67/00 ,  C08G64/18 ,  C09K5/04 ,  C10M105/48 ,  C10M107/32 ,  C10M171/00 ,  F02B75/02 ,  C10L1/18 ,  C07C59/125

Abstract: The present invention provides lubricant oil compositions comprising a polyalkylene glycol polycarbonate. The lubricant oil compositions are useful for industrial gear oil, automotive gear oil, and lubricant oil for refrigerators, rolling installations and fibers, which are excellent in lubricating properties and detergency. The present invention also relates to lubricant oil compositions which comprise a polyalkylene glycol polycarbonate having mutual solubility with an ozone layer-nondestructive Freon such as Freon R-134a, and which are accordingly especially suited for refrigerators using hydrogenated fluorocarbon as a refrigerant. A polyalkylene glycol polycarbonate according to the invention comprises a polyoxypropylene group in the molecular chain and an alkyl group and an alkyloxyalkylene group at the molecular terminals. This invention provides a process for preparing said polyalkylene glycol polycarbonate wherein a polypropylene glycol and a carbonate are allowed to react, said reaction including condensation polymerization. The invention also provides a process without condensation polymerization for preparing a polyalkylene glycol polyol wherein a polyol and a carbonate is allowed to react in the presence of a basic catalyst while a produced alcohol is being distilled off, the catalyst is removed then, and the unreacted carbonate is eliminated.

公开(公告)号：AT162536T

公开(公告)日：1998-02-15

申请号：AT90118684

申请日：1990-09-28

Applicant: MITSUI PETROCHEMICAL IND

Inventor： MIZUI KINYA ,  KISO YOSHIHISA ,  HAYASHI TETSUO ,  TANAKA MASAHIDE

IPC: C10M107/20 ,  C07C67/00 ,  C08G64/18 ,  C09K5/04 ,  C10M105/48 ,  C10M107/32 ,  C10M171/00 ,  F02B75/02 ,  C10M107/34

Abstract: The present invention provides lubricant oil compositions comprising a polyalkylene glycol polycarbonate. The lubricant oil compositions are useful for industrial gear oil, automotive gear oil, and lubricant oil for refrigerators, rolling installations and fibers, which are excellent in lubricating properties and detergency. The present invention also relates to lubricant oil compositions which comprise a polyalkylene glycol polycarbonate having mutual solubility with an ozone layer-nondestructive Freon such as Freon R-134a, and which are accordingly especially suited for refrigerators using hydrogenated fluorocarbon as a refrigerant. A polyalkylene glycol polycarbonate according to the invention comprises a polyoxypropylene group in the molecular chain and an alkyl group and an alkyloxyalkylene group at the molecular terminals. This invention provides a process for preparing said polyalkylene glycol polycarbonate wherein a polypropylene glycol and a carbonate are allowed to react, said reaction including condensation polymerization. The invention also provides a process without condensation polymerization for preparing a polyalkylene glycol polyol wherein a polyol and a carbonate is allowed to react in the presence of a basic catalyst while a produced alcohol is being distilled off, the catalyst is removed then, and the unreacted carbonate is eliminated.