公开(公告)号：CA2119540C

公开(公告)日：1996-10-08

申请号：CA2119540

申请日：1994-03-21

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  KAWAAI KOJI ,  NITABARU MASATOSHI

IPC: B01J31/02 ,  C07B61/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/30 ,  C07F17/00 ,  C07H17/00

Abstract: Disclosed is a process for preparing a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, comprising reacting (i) a lithium, sodium or potassium salt of a cyclopentadiene derivative with (ii) a silicon halide compound or a germanium halide compound in the presence of a cyanide or a thiocyanate. The cyanide or the thiocyanate is preferably a copper salt. According to the process of the invention, a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, which is very useful for the preparation of a metallocene complex catalyst component, can be prepared in a high yield for a short period of time.

公开(公告)号：DE3867877D1

公开(公告)日：1992-03-05

申请号：DE3867877

申请日：1988-03-25

Applicant: MITSUI PETROCHEMICAL IND

Inventor： MIKI HISAYA ,  ARAKI SHINTAROU ,  NITABARU MASATOSHI

IPC: B01J27/02 ,  B01J27/06 ,  B01J27/16 ,  C07B61/00 ,  C07C27/00 ,  C07C37/08 ,  C07C37/50 ,  C07C39/08 ,  C07C39/10 ,  C07C67/00

Abstract: Hydroxybenzenes can be produced in high yield through a one-step reaction by subjecting (a) an alpha , alpha -dialkyl- alpha -hydroxymethyl group containing benzene and/or (b) a benzene containing both alpha , alpha -dialkyl- alpha -hydroxymethyl and alpha , alpha -dialkyl- alpha -hydroperoxymethyl groups to reaction in the presence of a nitrile, an acid and hydrogen peroxide. In a preferred mode, the reaction system further contains (c) an alpha , alpha -dialkyl- alpha -hydroperoxymethyl group containing benzene.

公开(公告)号：CA2119540A1

公开(公告)日：1994-09-23

申请号：CA2119540

申请日：1994-03-21

Applicant: MITSUI PETROCHEMICAL IND

Inventor： KISO YOSHIHISA ,  KAWAAI KOJI ,  NITABARU MASATOSHI

IPC: B01J31/02 ,  C07B61/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/30 ,  C07F17/00 ,  C07H17/00

Abstract: A process for preparing a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, comprises reacting (i) a lithium, sodium or potassium salt of a cyclopentadiene derivative with (ii) a silicon halide compound or a germanium halide compound in the presence of a cyanide or a thiocyanate. The cyanide or the thiocyanate is preferably a copper salt. According to the process of the invention, a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, which is very useful for the preparation of a metallocene complex catalyst component, can be prepared in a high yield for a short period of time.

公开(公告)号：CA1308122C

公开(公告)日：1992-09-29

申请号：CA562470

申请日：1988-03-25

Applicant: MITSUI PETROCHEMICAL IND

Inventor： MIKI HISAYA ,  ARAKI SHINTAROU ,  NITABARU MASATOSHI

IPC: B01J27/02 ,  B01J27/06 ,  B01J27/16 ,  C07B61/00 ,  C07C27/00 ,  C07C37/08 ,  C07C37/50 ,  C07C39/08 ,  C07C39/10 ,  C07C67/00 ,  C07C39/02

Abstract: Hydroxybenzenes can be produced in high yield through a one-step reaction by subjecting (a) an .alpha., .alpha.-dialkyl-.alpha.-hydroxymethyl group containing benzene and/or (b) a benzene containing both .alpha., .alpha.-dialkyl-.alpha.-hydroxymethyl and .alpha., .alpha.-dialkyl-.alpha.-hydroperoxymethyl groups to reaction in the presence of a nitrile, an acid and hydrogen peroxide. In a preferred mode, the reaction system further contains (c) an .alpha., .alpha.-dialkyl-.alpha.-hydroperoxymethyl group containing benzene.

公开(公告)号：CA2052738A1

公开(公告)日：1992-04-05

申请号：CA2052738

申请日：1991-10-03

Applicant: MITSUI PETROCHEMICAL IND

Inventor： TANAKA MICHIO ,  KAWAAI KOJI ,  TARUMOTO HIROYOSHI ,  MIKI HISAYA ,  KISHIKAWA KEIKI ,  KAWAMURA MASATO ,  NITABARU MASATOSHI ,  FUJITA TERUNORI

IPC: B41M5/30 ,  B41M5/323

Abstract: A color-forming recording material containing: (a) an aromatic diamine, (b) an oxidizing agent such as a quinoid type electron-accepting compound, and (c) an acidic substance such as an aromatic carboxylic acid. The araomatic diamine (a) has preferably the formula (1), .........(1) wherein each o-f R1 and R4 Is, independently of the other, a substituted or unsubstituted aryl group, each of R2 and R3 is, independently of the other, a hydrogen atom, a lower alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group, and X is a substituted or unsubstituted arylene group, or the formula (2), .............(2) wherein R1, R2, R3 and X are as defined in the -formula (1), and R is an alkyl group, an aryl group or an aralkyl group. The color-forming recording material is useful for use in a data reading apparatus using visible light and/or near infrared light.

公开(公告)号：CA1278314C

公开(公告)日：1990-12-27

申请号：CA546695

申请日：1987-09-11

Applicant: MITSUI PETROCHEMICAL IND

Inventor： HANEDA YUTAKA ,  YOSHIMOTO SADAO ,  MIKI HISAYA ,  YASUDA MASAAKI ,  ARAKI SHINTAROU ,  NITABARU MASATOSHI

IPC: C07C37/055 ,  C07C37/08 ,  C07C39/14 ,  C07C67/055 ,  C07C409/08

Abstract: Disclosed in accordance with the present invention are processes for the preparation of hydroperoxides and/or carbinols by liquid phase oxidation of secondary alkylsubstituted naphthalenes with molecular oxygen, wherein the oxidation reaction is carried out by dissolving in the reaction mixture containing the secondary alkylsubstituted naphthalenes at least 0.5 ppm in terms of metal, based on the starting secondary alkyl-substituted naphthalenes, of at least one compound of metal selected from the group consisting of palladium and gold, said metal compound being soluble in the reaction mixture of the secondary alkyl-substituted naphthalenes. When compared with the prior art processes using catalysts of non homogeneous system, therefore, not only the amount of catalyst used can be minimized but also the rate of oxidation can be enhanced, and hence there can be obtained in a short period of time hydroperoxides and/or carbinols in high yields which are the oxidation products in accordance with the present invention. According to the present invention, the desired hydroperoxide can be obtained in high yields as well as in high purity from the hydroperoxides and/or carbinols obtained in the manner as mentioned above.

公开(公告)号：CA2125247A1

公开(公告)日：1994-12-08

申请号：CA2125247

申请日：1994-06-06

Applicant: MITSUI PETROCHEMICAL IND

Inventor： FUKUOKA DAISUKE ,  TASHIRO TAKASHI ,  KAWAAI KOJI ,  SAITO JUNJI ,  UEDA TAKASHI ,  KISO YOSHIHISA ,  MIZUNO AKIRA ,  KAWASAKI MASAAKI ,  ITOH MASAAKI ,  IMUTA JUNICHI ,  FUJITA TERUNORI ,  NITABARU MASATOSHI ,  YOSHIDA MASAYASU ,  HASHIMOTO MIKIO

IPC: C07C45/46 ,  C07C49/67 ,  C07C49/697 ,  C07F17/00 ,  C08F4/60 ,  C08F4/602 ,  C08F4/619 ,  C08F4/6192 ,  C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C07F7/00 ,  C07F9/00 ,  C07F11/00 ,  C08F4/42

Abstract: The novel transition metal compound of the invention is represented by the following formula (I): (see formula I) wherein M is a transition metal; R1 is a hydrocarbon group of 2 to 6 carbon atoms, R2 is an aryl group of 6 to 16 carbon atoms; X1 and X2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. An olefin polymerization catalyst component of the present invention comprises the aforementioned transition metal compound. An olefin polymerization catalyst of the present invention comprises the aforementioned olefin polymerization catalyst component. The propylene homopolymer, the propylene copolymer and the propylene elastomer according to the present invention have such properties that the triad tacticity of propylene units chain is high, a proportion of the inversely units based on the 2,1-insertion of propylene monomer is in the specific range, and the intrinsic viscosity [.pi.], as measured in decahydronaphthalene at 135.degree.C, is in the specific range.