公开(公告)号：ES2178350T3

公开(公告)日：2002-12-16

申请号：ES99302315

申请日：1999-03-25

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  TOFT MARK ANTHONY

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/28 ,  B01J23/887 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08

Abstract: A process of manufacturing acrylonitrile or methacrylonitrile by the catalytic reaction in the vapor phase of a paraffin selected from propane and isobutane with molecular oxygen and ammonia by catalytic contact of the reactants in a reaction zone with a catalyst, the feed composition having a mole ratio of the paraffin to ammonia in the range of from about 2.5 to 16 and a mole ratio of paraffin to oxygen in the range of from about 1.0 to 10, wherein said catalyst has the elements in the proportions indicated by the empirical formula: VSbmAaMobDdOx where A is one or more of Ti, Sn, Fe, Cr and Ga; D is one or more of Li, Mg, Ca, Sr, Ba, Co, Ni, Zn, Ge, Nb, Zr, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B and Mn; m equals 0.8 to 4; a equals 0.01 to 2; 0

公开(公告)号：RO116253B1

公开(公告)日：2000-12-29

申请号：RO9800065

申请日：1998-01-15

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84

Abstract: The invention relates to a process for preparing a catalyst having the elements and the proportions indicated by the following empirical formula: VsbmAaDdOx where A is selected from the elements Ti, Sn, where Sn is always present, D is selected from the elements Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and Mn, m ranges between 0.5 and 10, a ranges between 0 and 10, d ranges between 0 and 10, x is determined by the oxidation state of the cations present. The process consists of the preparation of an aqueous slurry of a mixture of the source batch materials comprising the compounds of said elements, followed by drying and heat calcining the mixture. The source batch material for tin is a solution comprising SnO2xH2O, wherein x is greater than or equal to 0, dispersed in tetraalkyl ammonium hydroxide defined by the formula (CnH2n+1)4NOH, wherein n is less than or equal to 5 and greater than or equal to 1. The slurry is dried and calcined up to a temperature of over 500°C.

公开(公告)号：BR9602629A

公开(公告)日：1998-04-22

申请号：BR9602629

申请日：1996-06-04

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK JR ,  CAVALCANTI FERNANDO A P

IPC: B01J23/18 ,  B01J23/22 ,  B01J23/847 ,  B01J27/057 ,  C07B61/00 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

Abstract: The process for the ammoxidation of a C3 to C5 paraffinic hydrocarbon to its corresponding alpha , beta -unsaturated hydrocarbon comprising reacting the C3 to C5 paraffinic hydrocarbon with ammonia and oxygen in a fluid bed reactor at a temperature of between 250 DEG C to 600 DEG C in the presence of a catalyst having the empirical formula as follows: VvSbmAaDdOx wherein A when present is Sn and/or Ti D when present is one or more of Li, Mg, Na, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al, P and Mn; and wherein v is 1, m is 0.5-75, a is 0 to 25, d is 0 to 25, and x is determined by the oxidation state of the cations present, and a minor quantity of an halogen-containing component, preferably characterized by the following formula: R-X or X2 where R=Hydrogen, C1-C20 alkyl and X=F, Cl, Br, I or mixtures thereof.arbo

公开(公告)号：MX165294B

公开(公告)日：1992-11-04

申请号：MX1402988

申请日：1988-12-02

Applicant: STANDARD OIL CO OHIO

Inventor： TOFT MARK ANTHONY ,  BRAZDIL JAMES FRANK JR ,  GLAESER LINDA C

IPC: B01J23/18 ,  B01J23/22 ,  C07C253/00 ,  C07C253/24 ,  C07C255/00

Abstract: Disclosed is a method of making a catalyst precursor by reacting the ion VO(O2) in aqueous solution with an antimony compound that contains Sb having a valence of 3. In one embodiment, the VO(O2) ion is made by reacting H2O2 with a vanadium compound. Also disclosed is making a catalyst by drying and calcining such precursor. When the drying is effected by spray drying a new microspheroidal catalyst is produced. The catalysts useful for ammoxidation of propane are more attrition resistant than catalysts of the same empirical formula made by prior art methods.

公开(公告)号：BG64351B1

公开(公告)日：2004-11-30

申请号：BG10219498

申请日：1998-01-16

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84

Abstract: The invention relates to method for the production of catalyst containing the elements and the proportions designed by formula VsbmAaDdOx wherein A is one or more Ti, Sn, and Sn is always present, D is one or more Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and Mn, m having the value of 0.5 to 10, a is bigger that 0 to 10, d has the value of from 0 to 10 and x is determined by the degree of oxidation of the present cations. The method includes the preparation of aqueous suspension of a mixture of burden of initial materials containing compounds of the said elements, which must be included in the final composition of the catalyst. There follows drying and tempering of the mixture to active catalyst. The initial raw material for tin is a solution containing SnO2 x H2O, having a value bigger or equal to 0, and dispersed in tetraalkylammonium hydroxide with the formula (CnH2n+1)4NOH wherein 5 ? n ?1. The suspension produced is driedand the mixture is tempered at maximum tempering temperature of 500 degrees C.

公开(公告)号：DE69818718T2

公开(公告)日：2004-09-23

申请号：DE69818718

申请日：1998-01-14

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84

Abstract: A catalyst (I) containing vanadium, antimony and tin in the oxide state is prepared by making an aqueous slurry of a mixture (II) of compounds of the desired elements followed by drying and calcining the mixture to form active catalyst (I). (II) is a solution comprising SnO2.xH2O (where x >= 0) dispersed in a tetraalkyl ammonium hydroxide of formula (CnH2n+14NOH (1). Also claimed is a process for making an alpha , beta -unsaturated mononitrile, preferably acrylonitrile or methacrylonitrile by the catalytic reaction in the vapour phase of propane or isobutane with oxygen and ammonia in the presence of a catalyst (I) of formula VSbmAaDdOx (2). The mole ratio of paraffin to NH3 is 2.5-16 and the mole ratio of paraffin to O2 is 1-10. n = 1-5; A = Ti and/or Sn where Sn is always present D = Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and/or Mn. m = 0.5 - 10; a = 0 - 10; d = 0-10; and x is determined by the oxidation state of the cations present.

公开(公告)号：RU2195999C2

公开(公告)日：2003-01-10

申请号：RU98101417

申请日：1998-01-16

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84

Abstract: FIELD: chemical technology, catalysts. SUBSTANCE: invention relates to method of synthesis of tin-containing vanadium-antimony catalysts useful for catalytic ammoxidation of C3-C5-paraffins or olefins, particularly, to synthesis of catalysts used for ammoxidation of propane or isobutene or propylene or isobutylene to yield corresponding alpha,beta- unsaturated mononitrile, acrylonitrile or methacrylonitrile. Invention describes method of synthesis of catalyst containing vanadium, antimony, tin and titanium in oxidized state that involves preparing aqueous suspension of parent substances as a charge containing compounds of elements to be incorporation in final catalyst, drying mixture and its calcination to form active catalyst. The source of charging tin is a solution containing SnO2.xH2O where n >= 0 dispersed in tetraalkylammonium hydroxide defined by the following formula: (C2H2n+1)4NOH where 5 >= n >= 1. Invention describes also method of synthesis of catalyst of definite empirical formula and providing drying carrying out and calcinations up to 500 C and also methods of synthesis of alpha,beta-unsaturated mononitrile in the presence of catalysts synthesized by the above described methods. EFFECT: enhanced activity and selectivity of catalyst. 16 cl, 2 ex

公开(公告)号：ZA9902101B

公开(公告)日：1999-10-01

申请号：ZA9902101

申请日：1999-03-16

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  TOFT MARK ANTHONY

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/28 ,  B01J23/887 ,  B01J37/08 ,  C07B61/00 ,  C07C253/24 ,  C07C255/07 ,  C07C255/08 ,  C07C ,  B01J

CPC classification number: C07C253/24 ,  B01J23/002 ,  B01J23/28 ,  B01J23/8876 ,  B01J37/08 ,  B01J2523/00 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/68

公开(公告)号：MX9704617A

公开(公告)日：1998-12-31

申请号：MX9704617

申请日：1997-06-20

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  KECKLER KENNETH PAUL ,  HAUSER RICHARD PAUL

IPC: C01C01/00

Abstract: Un proceso para la recuperacion de amoniaco sin reaccionar el efluente del reactor obtenido a partir de una zona de reaccion utilizando para producir acrilonitrilo o metacrilonitrilo que comprende enfriar el efluente de reactor con una solucion acuosa de fosfato de amonio en donde la proporcion de iones amonio o iones fosfato en la solucion es entre cerca de 0.7 a cerca de 1.3, preferentemente entre cerca de 0.9 a 1.2.

公开(公告)号：BR8806416A

公开(公告)日：1989-08-22

申请号：BR8806416

申请日：1988-12-06

Applicant: STANDARD OIL CO OHIO

Inventor： TOFT MARK ANTHONY ,  BRAZDIL JAMES FRANK JR ,  GLAESER LINDA C

IPC: B01J23/18 ,  B01J23/22 ,  C07C253/00 ,  C07C253/24 ,  C07C255/00

Abstract: Disclosed is a method of making a catalyst precursor by reacting the ion VO(O2) in aqueous solution with an antimony compound that contains Sb having a valence of 3. In one embodiment, the VO(O2) ion is made by reacting H2O2 with a vanadium compound. Also disclosed is making a catalyst by drying and calcining such precursor. When the drying is effected by spray drying a new microspheroidal catalyst is produced. The catalysts useful for ammoxidation of propane are more attrition resistant than catalysts of the same empirical formula made by prior art methods.