公开(公告)号：JPH10225634A

公开(公告)日：1998-08-25

申请号：JP688398

申请日：1998-01-16

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84

Abstract: PROBLEM TO BE SOLVED: To prepare an oxidation (especially ammoxidation) catalyst by producing an aq. slurry of a batch of feed mixture contg. the compds. of vanadium and antimony and the tin shown by formula II to be dispersed in tetraalkylammonium hydroxide of formula I, drying and then calcining the slurry. SOLUTION: The catalyst contg. vanadium, antimony and tin as their oxides is prepared from the optional appropriate org. or inorg. precursor compds. of V and Sb and a compd. (e.g. the salt, oxide, hydroxide or organometallic compd. of such elements) used for introducing other optional elements into the calcined final catalyst. The tin is introduced into the batch of feed mixture to prepare the catalyst as a dispersion of SnO2 .xH2 O (where x>=0) in (Cn H2n+1 )4 NOH (where 5>=n>=1), and the batch of feed mixture is heated and calcined until a final catalyst is obtained to prepare an excellent oxidation (especially ammoxidation) catalyst.

公开(公告)号：ZA9800258B

公开(公告)日：1998-07-13

申请号：ZA9800258

申请日：1998-01-13

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL FRANK JAMES JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84 ,  B01J

CPC classification number: C07D213/84 ,  B01J23/18 ,  B01J23/22 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C255/08 ,  C07C255/51

公开(公告)号：ES2209062T3

公开(公告)日：2004-06-16

申请号：ES98300250

申请日：1998-01-14

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84

Abstract: A catalyst (I) containing vanadium, antimony and tin in the oxide state is prepared by making an aqueous slurry of a mixture (II) of compounds of the desired elements followed by drying and calcining the mixture to form active catalyst (I). (II) is a solution comprising SnO2.xH2O (where x >= 0) dispersed in a tetraalkyl ammonium hydroxide of formula (CnH2n+14NOH (1). Also claimed is a process for making an alpha , beta -unsaturated mononitrile, preferably acrylonitrile or methacrylonitrile by the catalytic reaction in the vapour phase of propane or isobutane with oxygen and ammonia in the presence of a catalyst (I) of formula VSbmAaDdOx (2). The mole ratio of paraffin to NH3 is 2.5-16 and the mole ratio of paraffin to O2 is 1-10. n = 1-5; A = Ti and/or Sn where Sn is always present D = Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and/or Mn. m = 0.5 - 10; a = 0 - 10; d = 0-10; and x is determined by the oxidation state of the cations present.

公开(公告)号：DE69818718D1

公开(公告)日：2003-11-13

申请号：DE69818718

申请日：1998-01-14

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84

Abstract: A catalyst (I) containing vanadium, antimony and tin in the oxide state is prepared by making an aqueous slurry of a mixture (II) of compounds of the desired elements followed by drying and calcining the mixture to form active catalyst (I). (II) is a solution comprising SnO2.xH2O (where x >= 0) dispersed in a tetraalkyl ammonium hydroxide of formula (CnH2n+14NOH (1). Also claimed is a process for making an alpha , beta -unsaturated mononitrile, preferably acrylonitrile or methacrylonitrile by the catalytic reaction in the vapour phase of propane or isobutane with oxygen and ammonia in the presence of a catalyst (I) of formula VSbmAaDdOx (2). The mole ratio of paraffin to NH3 is 2.5-16 and the mole ratio of paraffin to O2 is 1-10. n = 1-5; A = Ti and/or Sn where Sn is always present D = Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and/or Mn. m = 0.5 - 10; a = 0 - 10; d = 0-10; and x is determined by the oxidation state of the cations present.

公开(公告)号：ZA98258B

公开(公告)日：1998-07-13

申请号：ZA98258

申请日：1998-01-13

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL FRANK JAMES JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84 ,  B01J

Abstract: A catalyst (I) containing vanadium, antimony and tin in the oxide state is prepared by making an aqueous slurry of a mixture (II) of compounds of the desired elements followed by drying and calcining the mixture to form active catalyst (I). (II) is a solution comprising SnO2.xH2O (where x >= 0) dispersed in a tetraalkyl ammonium hydroxide of formula (CnH2n+14NOH (1). Also claimed is a process for making an alpha , beta -unsaturated mononitrile, preferably acrylonitrile or methacrylonitrile by the catalytic reaction in the vapour phase of propane or isobutane with oxygen and ammonia in the presence of a catalyst (I) of formula VSbmAaDdOx (2). The mole ratio of paraffin to NH3 is 2.5-16 and the mole ratio of paraffin to O2 is 1-10. n = 1-5; A = Ti and/or Sn where Sn is always present D = Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and/or Mn. m = 0.5 - 10; a = 0 - 10; d = 0-10; and x is determined by the oxidation state of the cations present.

公开(公告)号：DE2860929D1

公开(公告)日：1981-11-12

申请号：DE2860929

申请日：1978-06-22

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  BARTEK JOSEPH PETER

IPC: B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C13/45 ,  C07C13/465 ,  C07C67/00

Abstract: The problem exists of finding a simple, economic and straightforward process for the production of indene monomer. This problem is solved by making indene monomer and substituted indene monomers by a dehydrogenation process in which an indene precursor more saturated than indene is contacted with an oxygen donor with a phosphate catalyst. An oxygen donor is O2. The process is carried out a temperature above 100 DEG C. The phosphate catalyst is represented by the formula MaPxOy in which M is one or more elements selected from Mg, Sr, Ca, Ba, La, Ce, other rare earths, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sn, Pb, Bi, Te, B, Al, Rh, Sb, As, Ge, U, Th and Ru. In a representative Example a mixture of indane, approximately five parts of air and three parts of nitrogen for each part of indane vapour are fed to a reactor containing a phosphate catalyst and maintained at a temperature of 550 DEG C.

公开(公告)号：SG77153A1

公开(公告)日：2000-12-19

申请号：SG1998000060

申请日：1998-01-06

Applicant: STANDARD OIL CO

Inventor： BRAZDIL AJMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84

Abstract: A catalyst (I) containing vanadium, antimony and tin in the oxide state is prepared by making an aqueous slurry of a mixture (II) of compounds of the desired elements followed by drying and calcining the mixture to form active catalyst (I). (II) is a solution comprising SnO2.xH2O (where x >= 0) dispersed in a tetraalkyl ammonium hydroxide of formula (CnH2n+14NOH (1). Also claimed is a process for making an alpha , beta -unsaturated mononitrile, preferably acrylonitrile or methacrylonitrile by the catalytic reaction in the vapour phase of propane or isobutane with oxygen and ammonia in the presence of a catalyst (I) of formula VSbmAaDdOx (2). The mole ratio of paraffin to NH3 is 2.5-16 and the mole ratio of paraffin to O2 is 1-10. n = 1-5; A = Ti and/or Sn where Sn is always present D = Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and/or Mn. m = 0.5 - 10; a = 0 - 10; d = 0-10; and x is determined by the oxidation state of the cations present.

公开(公告)号：BR9800349A

公开(公告)日：1999-05-25

申请号：BR9800349

申请日：1998-01-16

Applicant: STANDARD OIL CO OHIO

Inventor： BRAZDIL JAMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84

Abstract: A catalyst (I) containing vanadium, antimony and tin in the oxide state is prepared by making an aqueous slurry of a mixture (II) of compounds of the desired elements followed by drying and calcining the mixture to form active catalyst (I). (II) is a solution comprising SnO2.xH2O (where x >= 0) dispersed in a tetraalkyl ammonium hydroxide of formula (CnH2n+14NOH (1). Also claimed is a process for making an alpha , beta -unsaturated mononitrile, preferably acrylonitrile or methacrylonitrile by the catalytic reaction in the vapour phase of propane or isobutane with oxygen and ammonia in the presence of a catalyst (I) of formula VSbmAaDdOx (2). The mole ratio of paraffin to NH3 is 2.5-16 and the mole ratio of paraffin to O2 is 1-10. n = 1-5; A = Ti and/or Sn where Sn is always present D = Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al and/or Mn. m = 0.5 - 10; a = 0 - 10; d = 0-10; and x is determined by the oxidation state of the cations present.

公开(公告)号：BG102194A

公开(公告)日：1998-08-31

申请号：BG10219498

申请日：1998-01-16

Applicant: STANDARD OIL CO

Inventor： BRAZDIL JAMES FRANK JR ,  BARTEK JOSEPH PETER

IPC: B01J23/20 ,  B01J23/14 ,  B01J23/16 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/26 ,  B01J23/28 ,  B01J23/30 ,  B01J23/34 ,  B01J23/847 ,  B01J27/057 ,  B01J37/04 ,  C07B61/00 ,  C07C51/265 ,  C07C253/00 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07C255/08 ,  C07C255/51 ,  C07D213/84 ,  B01J23/00

Abstract: The invention relates to a method for the preparation of acatalyst containing the elements and proportions designed by thefollowing formulaVSbmAaDdOxwhere: A is one or more Ti, Sn, Sn being always present, D is oneor more Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr,Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B. Al and Mn and where mhas the value from 0.5 to 10, a is bigger from 0 to 10, d has thevalue of 0 to 10, and x is determined by the degree of oxidationof the present cations. The method includes the preparation ofaqueous suspensiion of a mixture of burden of initial materialscontaining compounds of the above elements which should beincluded in the final catalyst. There follows drying and heatcalcination of the mixture to an active catalyst where the initialraw material for the tin is a solution containing Sn02.xH20, wherex has the value of bigger or equal to 0, and dispersed intetraalkylammonium hydroxide with a formula(CnH2n+1)4NOHwhere 5 n 1. The suspension produced is dried and the mixture iscalcinated at maximum calcination temperature of 500°C.18 claims

公开(公告)号：DE2816946A1

公开(公告)日：1978-11-09

申请号：DE2816946

申请日：1978-04-19

Applicant: STANDARD OIL CO OHIO

Inventor： BARTEK JOSEPH PETER ,  GRASSELLI ROBERT KARL

IPC: B01J23/00 ,  B01J27/186 ,  B01J27/192 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C15/44 ,  C07C15/46 ,  C07C15/58 ,  C07C67/00 ,  C07D213/06 ,  C07D213/127 ,  C07D213/16 ,  C07C15/10 ,  B01J27/18 ,  C07C5/36 ,  C07C15/09 ,  C07D213/02